公开(公告)号：US3839313A

公开(公告)日：1974-10-01

申请号：US21674672

申请日：1972-01-10

Applicant: MONTEDISON SPA

Inventor： GALLI P ,  DI DRUSCO G ,  SUSA E

IPC: C08F4/64 ,  C08F10/00 ,  C08F3/06 ,  C08F1/42

CPC classification number: C08F10/00 ,  C08F4/634

Abstract: There are disclosed new catalysts for the polymerization of olefins and which comprise the products of reaction between organometallic compounds or hydrides of metals of Groups I, II or III of the Mendelyeev Periodic Table and the product obtained by reacting a liquid halogenated compound of titanium or vanadium with a solid carrier containing chemically uncombined water and having the formula Mg O. (Mg(OH)2)x. (H2O)y, WHEREIN X IS A NUMBER GREATER THAN O and may be 100 or higher; y is a number between 0 and 1; (Mg(OH)2)x expresses the number of hydroxyls present in the carrier, however combined; and (H2O)y represents the number of chemically uncombined molecules of water present in the carrier. The catalysts are very active and use thereof in the polymerization of olefins results in high yields of polymers having a low content of foreign substances.

Abstract translation: 公开了用于烯烃聚合的新催化剂，其包括Mendelyeev周期表第I，II或III族金属的有机金属化合物或氢化物之间的反应产物和通过使钛或钒的液体卤化化合物反应而获得的产物 具有含化学未结合水并具有式Mg O [Mg（OH）2] x的固体载体。 （H 2 O）y，其中X是比O更大的并且可以是100或更高; y是0和1之间的数字; [Mg（OH）2] x表示载体中存在的羟基数，然而组合; 和（H 2 O）y表示存在于载体中的化学未结合的水分子的数量。 催化剂是非常活泼的，并且在烯烃聚合中的用途导致高产率的具有低含量异物的聚合物。

公开(公告)号：US3830787A

公开(公告)日：1974-08-20

申请号：US24145072

申请日：1972-04-05

Applicant: MONTEDISON SPA

Inventor： EMILIA R ,  MAYR A ,  SUSA E ,  DAVOLI V

IPC: C08F4/02 ,  C08F4/64 ,  C08F10/00 ,  B01J11/84 ,  C08F1/56

CPC classification number: C08F10/00 ,  C08F4/022 ,  C08F4/6543 ,  C08F4/6574 ,  C08F4/6555

Abstract: NEW CATALYSTS FOR THE POLYMERIZATION OF OLEFINS, MORE PARTICULARLY FOR THE POLYMERIZATION OF ETHYLENE AND MIXTURES THEREOF WITH HIGHER ALPHA-OLEFINS ARE DISCLOSED, AS WELL AS METHODS FOR PREPARING THE SAME, AND FOR POLYMERIZING OLEFINS THEREWITH. THE NEW CATALYSTS ARE PREPARED BY MIXING A HYDRIDE OR ORGANOMETALLIC COMPOUND OF A METAL BELONGING TO GROUP I, II OR III OF THE MENDELYEEV PERIODIC TABLE WITH THE PRODUCT OBTAINED BY CONTACTING A TITANIUM COMPOUND WITH THE SOLID REACTION PRODUCT OF A HYDRATED MAGNESIUM HALIDE AND AN ORGANOMETALLIC COMPOUND OF ONE OF SAID GROUPS I TO III METALS, IN A MOLAR RATIO ORGANOMETALLIC COMPOUND/H2O OF AT LEAST 1.