公开(公告)号：US4203723A

公开(公告)日：1980-05-20

申请号：US747674

申请日：1976-12-06

Applicant: James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher ,  Madeline S. Toy ,  Roger S. Stringham

Inventor： James C. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Fletcher ,  Madeline S. Toy ,  Roger S. Stringham

IPC: C08J7/18 ,  C08F8/00

CPC classification number: C08J7/18 ,  C08J2377/10 ,  Y10S8/12 ,  Y10S8/18

Abstract: A process for producing aromatic polyamides having improved nonflammability characteristics in which a polyamide substrate is contacted with a gaseous medium comprising a minor amount of a haloolefinic material and an inert diluent in the presence of light having sufficient energy to effect chemical addition of the haloolefin to said polyamide substrate.

Abstract translation: 一种制备芳族聚酰胺的方法，其具有改进的不燃性特性，其中聚酰胺基材与包含少量卤烯烃材料和惰性稀释剂的气体介质在具有足够能量的光的存在下接触以实现将卤代烯烃化学加成到所述 聚酰胺基材。

公开(公告)号：US4149016A

公开(公告)日：1979-04-10

申请号：US852114

申请日：1977-11-16

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: B01J19/12 ,  C07C409/16 ,  C07C43/18

CPC classification number: B01J19/123

Abstract: A method for synthesizing perfluoropolyethers by effecting addition reactions under low temperature photolysis between perfluoroolefins, perfluorodialkyl peroxides and fluoroxyperfluoroalkanes resulting in the snythesis of new compounds.

Abstract translation: 通过在全氟烯烃，全氟二烷基过氧化物和氟氧全氟烷烃之间的低温光解下进行加成反应合成全氟聚醚的方法，导致新化合物的合成。

公开(公告)号：US4393198A

公开(公告)日：1983-07-12

申请号：US307347

申请日：1981-09-30

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: C07C43/192 ,  C07D317/70 ,  C07D493/08 ,  C07D519/00 ,  C08G61/02 ,  C08G65/00

CPC classification number: C07D493/08 ,  C07C43/192 ,  C07D317/70 ,  C08G61/02 ,  C08G65/007

Abstract: A method for polymerizing octafluoronaphthalene and the resulting perfluorocompounds prepared therefrom. Polymerization is accomplished by reacting the octafluoronaphthalene monomer with a mono or difluoroxyperfluoroalkane.

Abstract translation: 聚合八氟萘的方法及其制备的全氟化合物。 通过使八氟萘单体与单或二氟全氟烷烃反应来实现聚合。

公开(公告)号：US4075073A

公开(公告)日：1978-02-21

申请号：US771858

申请日：1977-02-23

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: C07C409/16 ,  B01J1/10

CPC classification number: C07C409/16 ,  C07C407/00 ,  C07C407/003

Abstract: A method for synthesizing bis(perfluoro-t-butyl) peroxide through the photolysis of perfluoro-t-butyl hypofluorite in the presence of tetrafluorohydrazine.

Abstract translation: 在四氟肼存在下，通过全氟叔丁基次氟化物的光解，合成双（全氟叔丁基）过氧化物的方法。

公开(公告)号：US4430089A

公开(公告)日：1984-02-07

申请号：US368405

申请日：1982-04-14

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: D06M10/06 ,  D06M11/13 ,  D06M11/20 ,  D06M11/56 ,  D06M11/69 ,  D06M11/81 ,  D06M10/00 ,  D06M1/22 ,  D06M9/00

CPC classification number: D06M11/56 ,  D06M10/06 ,  D06M11/13 ,  D06M11/20 ,  D06M11/69 ,  D06M11/81

Abstract: A process for effecting flame retardation of fibrous structures, such as fabrics, particularly fabrics made from mixtures of natural and synthetic fibers, such as cotton and nylon. The process includes the steps of contacting the fabric to be treated with halomonomers and/or inorganic salts, followed by fluorocarbon grafting, and then by photohalogenation. The aforesaid treatment results in fabrics which are not only flame resistant but also have improved hand, manifested by softness, silkiness, and unwettability of the resulting fabric.

Abstract translation: 纤维结构如织物，特别是由天然和合成纤维（如棉和尼龙）的混合物制成的织物的阻燃的方法。 该方法包括以下步骤：使待处理的织物与卤素单体和/或无机盐接触，随后进行氟碳接枝，然后通过光卤化。 上述处理产生的织物不仅具有阻燃性，而且具有改善的手感，表现为所得织物的柔软性，丝质和不耐受性。

公开(公告)号：US4321359A

公开(公告)日：1982-03-23

申请号：US182562

申请日：1980-08-29

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: C07C43/192 ,  C07D317/70 ,  C07D493/08 ,  C07D519/00 ,  C08G61/02 ,  C08G65/00

CPC classification number: C07D493/08 ,  C07C43/192 ,  C07D317/70 ,  C08G61/02 ,  C08G65/007

Abstract: A method for polymerizing octafluoronaphthalene and the resulting perfluorocompounds prepared therefrom. Polymerization is accomplished by reacting the octafluoronaphthalene monomer with a mono or difluoroxyperfluoroalkane.

Abstract translation: 聚合八氟萘的方法及其制备的全氟化合物。 通过使八氟萘单体与单或二氟全氟烷烃反应来实现聚合。

公开(公告)号：US4278703A

公开(公告)日：1981-07-14

申请号：US68110

申请日：1979-08-20

Applicant: Madeline S. Toy ,  Roger S. Stringham ,  Lawrence C. Fogg

Inventor： Madeline S. Toy ,  Roger S. Stringham ,  Lawrence C. Fogg

IPC: D06M14/18 ,  B05D3/06

CPC classification number: D06M14/18

Abstract: An improved process and apparatus is provided for imparting chemically bonded fluorocarbon finishes to textiles. In the process, the textiles are contacted with a gaseous mixture of fluoroolefins in an inert diluent gas in the presence of ultraviolet light under predetermined conditions.

Abstract translation: 提供了一种改进的方法和装置，用于将化学键合的碳氟化合物表面涂布到纺织品上。 在此过程中，在预定条件下，在紫外线的存在下，将纺织品与惰性稀释气体中的氟烯烃的气体混合物接触。

公开(公告)号：US4077857A

公开(公告)日：1978-03-07

申请号：US771853

申请日：1977-02-23

Applicant: Madeline S. Toy ,  Roger S. Stringham

Inventor： Madeline S. Toy ,  Roger S. Stringham

IPC: B01J19/12 ,  C07C409/16 ,  B01J1/10

CPC classification number: B01J19/123

Abstract: A method for synthesizing perfluoropolyethers by effecting addition reactions under low temperature photolysis between perfluoroolefins, perfluorodialkyl peroxides and fluoroxyperfluoroalkanes resulting in the synthesis of new compounds.

Abstract translation: 通过在全氟烯烃，全氟二烷基过氧化物和氟氧全氟烷烃之间的低温光解下进行加成反应合成全氟聚醚的方法，导致新化合物的合成。

公开(公告)号：US3931132A

公开(公告)日：1976-01-06

申请号：US45549

申请日：1970-06-11

Applicant: George M. Deputy Administrator of the National Aernautics and Space Administration, with respect to an invention of Low ,  Madeline S. Toy

Inventor： George M. Deputy Administrator of the National Aernautics and Space Administration, with respect to an invention of Low ,  Madeline S. Toy

IPC: C08C19/32 ,  C08F36/16 ,  C08F114/00 ,  C08L9/00 ,  C08L27/12

CPC classification number: C08C19/32 ,  C08F36/16

Abstract: Oxygen difluoride, OF.sub.2, is reacted with ethylenically unsaturated fluorocarbon compounds. Depending upon the fluorocarbon material and reaction conditions, OF.sub.2 can chain extend fluoropolyenes, convert functional perfluorovinyl groups to acyl fluoride and/or epoxide groups and act as a monomer for an addition type copolymerization with diolefins.

Abstract translation: 氟化二氟化物OF2与烯属不饱和碳氟化合物反应。 根据氟碳材料和反应条件，OF2可以连续扩链氟代多烯，将功能性全氟乙烯基转化为酰基氟化物和/或环氧化物基团，并充当与二烯烃进行加成型共聚合的单体。

公开(公告)号：US4945063A

公开(公告)日：1990-07-31

申请号：US247710

申请日：1988-09-22

Applicant: Madeline S. Toy ,  Melvin K. Carter

Inventor： Madeline S. Toy ,  Melvin K. Carter

IPC: G01N31/00 ,  G01N33/18

CPC classification number: G01N33/1846 ,  G01N31/005 ,  Y10S436/905 ,  Y10T436/171538 ,  Y10T436/18 ,  Y10T436/19 ,  Y10T436/21

Abstract: A method is provided for detecting the presence of organic materials in an aqueous sample. The materials are decomposed by simultaneous exposure to ultraviolet radiation and acoustic energy to decompose the materials to simple decomposition products. The simple decomposition products such as ammonium ion, halogen ion, alkyl ammonium ions, or sulfate ions, are then detected by conventional analytical devices and methods.

Abstract translation: 提供了一种用于检测含水样品中有机材料的存在的方法。 材料通过同时暴露于紫外线和声能而分解，将材料分解成简单的分解产物。 然后通过常规分析装置和方法检测简单的分解产物如铵离子，卤素离子，烷基铵离子或硫酸根离子。