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    METHOD FOR PREPARING ORGANIC PEROXIDES
    1.
    发明申请
    METHOD FOR PREPARING ORGANIC PEROXIDES 有权
    制备有机过氧化物的方法

    公开(公告)号：US20160207882A1

    公开(公告)日：2016-07-21

    申请号：US14910937

    申请日：2014-07-09

    申请人： ARKEMA FRANCE

    发明人： Philippe MAJ ,  Serge HUB

    IPC分类号： C07C409/16 ,  B01J31/02 ,  B01J27/053 ,  C07C407/00

    CPC分类号： C07C409/16 ,  B01J27/053 ,  B01J31/0225 ,  C07C407/00 ,  C07C407/003

    摘要： A method for preparing peroxide, including a step of treating, in a reaction medium, a component having at least one tertiary alcohol grouping with a compound having at least one tertiary hydroperoxide function in the presence of a catalyst, said method being characterised in that the catalyst includes a sulphonic acid and a inorganic acid, the molar ratio between the sulphonic acid and the aforementioned component including at least one tertiary alcohol grouping ranges from 0.05 to 0.8, and the molar ratio between the inorganic acid and the aforementioned component including at least one tertiary alcohol grouping ranges from 0.05 to 0.8. Also, to the peroxide resulting directly from said preparation method.

    摘要翻译： 一种制备过氧化物的方法，包括在催化剂存在下，在反应介质中处理具有至少一个叔醇基的组分与具有至少一个叔氢过氧化物功能的化合物的步骤的方法，其特征在于， 催化剂包括磺酸和无机酸，所述磺酸与包含至少一种叔醇基团的前述组分的摩尔比在0.05至0.8范围内，无机酸与上述组分的摩尔比包括至少一种 叔醇分数范围为0.05至0.8。 而且，直接由所述制备方法得到的过氧化物。

    Oxygen Resistant Organic Peroxides for Reticulation/Cure and Their Use in the Process of Continuous Vulcanization in Hot Air Tunnel
    4.
    发明申请
    Oxygen Resistant Organic Peroxides for Reticulation/Cure and Their Use in the Process of Continuous Vulcanization in Hot Air Tunnel 审中-公开
    用于网状/固化的耐氧有机过氧化物及其在热风隧道连续硫化过程中的应用

    公开(公告)号：US20110147986A1

    公开(公告)日：2011-06-23

    申请号：US13060021

    申请日：2008-08-21

    申请人： Antonio D'Angelo

    发明人： Antonio D'Angelo

    IPC分类号： B29C71/02 ,  C08L23/16 ,  C07C409/16 ,  C07C409/38 ,  C07C409/32

    CPC分类号： C08L23/16 ,  C07C409/00 ,  C07C409/16 ,  C07C409/22 ,  C07C409/34 ,  C08L23/06 ,  C08L2312/00 ,  C08L2666/06

    摘要： This application refers to Organic Peroxides of the Dialcyl, Perester, Perketal, and Dialkyl classes, which were modified to resist to oxygen, destined to be used in the process of production of Power Wires and Cables, Shapes, flocculated, compact and spongeous, used for the assembly of sealing of doors, trunks and windows in the automobile industry and civil construction, and also in the process of continuous vulcanization in hot air tunnel, in presence of oxygen, with the application of modified Organic Peroxides.

    摘要翻译： 本申请涉及经过修改以抵抗氧气的Dialcyl，Perester，Perketal和Dialkyl类的有机过氧化物，注定用于生产功率线和电缆，形状，絮凝，紧凑和海绵状物的过程 用于在汽车工业和民用建筑中的门，树干和窗户的密封组装，以及在热空气隧道中，在存在氧气的情况下连续硫化的过程中，应用改性的有机过氧化物。

    Conjoint production of ditertiary butyl peroxide and tertiary butyl alcohol from tertiary butyl hydroperoxide
    8.
    发明授权
    Conjoint production of ditertiary butyl peroxide and tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
    从叔丁基过氧化氢联合生产二叔丁基过氧化物和叔丁醇

    公开(公告)号：US5345009A

    公开(公告)日：1994-09-06

    申请号：US150913

    申请日：1993-11-12

    申请人： John R. Sanderson ,  John F. Knifton

    发明人： John R. Sanderson ,  John F. Knifton

    IPC分类号： B01J23/44 ,  C07B61/00 ,  C07C27/00 ,  C07C29/132 ,  C07C31/12 ,  C07C409/16

    CPC分类号： C07C409/16 ,  C07C29/132 ,  C07C407/00

    摘要： A method for conjointly preparing tertiary butyl alcohol and ditertiary butyl peroxide wherein a solution of a tertiary butyl hydroperoxide feedstock in tertiary butyl alcohol is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of palladium supported on pelleted carbon, and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol and ditertiary butyl peroxide.

    摘要翻译： 一种联合制备叔丁醇和二叔丁基过氧化物的方法，其中将叔丁基过氧化氢原料在叔丁醇中的溶液加入含有催化有效量的氢过氧化物分解催化剂的氢过氧化物分解反应区，所述氢过氧化物分解催化剂基本上由负载在颗粒 碳，并在氢过氧化物分解反应条件下与液相中的催化剂接触，将叔丁基氢过氧化物转化成分解产物，主要是叔丁醇和二叔丁基过氧化物。

    Preparation of dialkyl peroxides
    9.
    发明授权
    Preparation of dialkyl peroxides 失效
    二烷基过氧化物的制备

    公开(公告)号：US5288919A

    公开(公告)日：1994-02-22

    申请号：US61139

    申请日：1993-05-13

    申请人： Mahmoud K. Faraj

    发明人： Mahmoud K. Faraj

    IPC分类号： C07C409/16

    CPC分类号： C07C409/16 ,  C07C407/00

    摘要： The present invention provides a process for the production of dialkyl peroxides by reaction of an alcohol and/or an olefin with an organic hydroperoxide, using an inorganic heteropoly and/or isopoly acid catalyst.

    摘要翻译： 本发明提供了使用无机杂多和/或异多酸催化剂通过醇和/或烯烃与有机氢过氧化物反应制备二烷基过氧化物的方法。

    Modification of (co)polymers employing organic peroxides
    10.
    发明授权
    Modification of (co)polymers employing organic peroxides 失效
    使用有机过氧化物改性（共）聚合物

    公开(公告)号：US5202386A

    公开(公告)日：1993-04-13

    申请号：US703965

    申请日：1991-05-22

    申请人： Andreas H. Hogt ,  John Meijer ,  Peter Hope ,  Jernej Jelenic

    发明人： Andreas H. Hogt ,  John Meijer ,  Peter Hope ,  Jernej Jelenic

    IPC分类号： C07C409/16 ,  C07C409/18 ,  C08F8/08

    CPC分类号： C07C409/16 ,  C07C407/00 ,  C08F8/08

    摘要： Organic (co)polymers, including saturated (co)polymers, are modified by contacting them with an organic peroxide and decomposing the peroxide. Use is made of an organic peroxide having the general formula R--(O--O--CHR.sup.1 --CR.sup.2 .dbd.CR.sup.3 R.sup.4)N, wherein N is 1, 2 or 3; R.sup.1 is H, C.sub.1 -C.sub.4 alkyl or C.sub.2 -C.sub.4 alkylene; R.sup.2, R.sup.3 and R.sup.4 are, independently, H or C.sub.1 -C.sub.4 alkyl; two of the substituents R.sup.1 -R.sup.4 together may form C.sub.3 -C.sub.12 alkylene; and, when N is 1, R is an optionally hydroxyl substituted C.sub.4 -C.sub.18 T.alkyl, P-menth-8-yl, C.sub.5 -C.sub.18 T.alkenyl, 1-vinylcyclohexyl or a group of the formula: --C(CH.sub.3)2--C.sub.6 HJ(5--M)--R.sup.5 (M), wherein M is 0, 1 or 2 and R.sup.5 is isopropenyl or 2-hydroxyisopropyl; when N is 2, R is a C.sub.8 -C.sub.12 alkylene or alkynylene group having a tertiary structure at both ends, or a group having the formula --(C)CH.sub.3)2)2--C.sub.6 H(4--X)--R.sup.5 (X), wherein X is 0 or 1; and when N is 3, R is 1,2,4- or 1,3,5-triisopropylbenzene-alpha, alpha"-triyl, i.a., 3-allylperoxy-3,3-dimethylpropene according to a preferred embodiment the modification is carried out in the presence of a coagent, whereby the advantageous polymer properties, such as adhesion to polar materials, are further enhanced.

    摘要翻译： 包括饱和（共）聚合物在内的有机（共）聚合物通过与有机过氧化物接触并分解过氧化物而被改性。 使用具有通式R-（O-O-CHR 1 -CR 2 = CR 3 R 4）N的有机过氧化物，其中N为1,2或3; R1是H，C1-C4烷基或C2-C4亚烷基; R2，R3和R4独立地是H或C1-C4烷基; 两个取代基R 1 -R 4一起可以形成C 3 -C 12亚烷基; 当N为1时，R为任选羟基取代的C 4 -C 18烷基，P-menth-8-yl，C 5 -C 18 T链烯基，1-乙烯基环己基或下式的基团-C（CH 3） 2-C6HJ（5-M）-R5（M），其中M是0,1或2，R5是异丙烯基或2-羟基异丙基; 当N为2时，R为在两端具有三级结构的C 8 -C 12亚烷基或亚炔基或具有式（C）CH 3）2）2 -C 6 H（4-X）-R 5（X）的基团， 其中X为0或1; 当N为3时，根据优选实施方案，R为1,2,4-或1,3,5-三异丙基苯-α，α“ - 三基，ia，3-烯丙基过氧-3,3-二甲基丙烯， 在助剂的存在下进行，由此有利的聚合物性质，例如对极性材料的粘附性进一步增强。