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    Hetarylalkenes, their preparation and intermediates for their preparation and their use
    1.
    发明授权
    Hetarylalkenes, their preparation and intermediates for their preparation and their use 失效
    营养素及其制备及其制备及其使用的中间体

    公开(公告)号：US5175167A

    公开(公告)日：1992-12-29

    申请号：US652634

    申请日：1991-02-08

    申请人： Bernhard Zipperer ,  Manfred Lauer ,  Norbert Goetz ,  Thomas Zierke ,  Eberhard Ammermann ,  Gisela Lorenz

    发明人： Bernhard Zipperer ,  Manfred Lauer ,  Norbert Goetz ,  Thomas Zierke ,  Eberhard Ammermann ,  Gisela Lorenz

    IPC分类号： A01N43/40 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  C07D213/30 ,  C07D213/50 ,  C07D401/06 ,  C07D405/06 ,  C07D407/06 ,  C07D409/06

    CPC分类号： C07D213/30 ,  A01N43/40 ,  A01N43/54 ,  A01N43/58 ,  A01N43/60 ,  C07D213/50

    摘要： Hetarylalkenes of the general formula I ##STR1## where Ar is hetaryl,A is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.8 -cycloalkyl-C.sub.1 -C.sub.3 -alkyl or unsubstituted or monosubstituted, disubstituted or trisubstituted aryl or aralkyl, ##STR2## Z is whereR is hydrogen, C.sub.2 -C.sub.4 -acyl, unsubstituted or substituted benzoyl, C.sub.1 -C.sub.4 -alkylsulfonyl, unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted phenylsulfonyl or a radical R.sup.1,R.sup.1 is C.sub.1 -C.sub.4 -alkyl or unsubstituted or substituted phenyl or benzyland Hal is fluorine, chlorine, bromine or iodine,and B is unsubstituted or substituted mononuclear or dinuclear aryl, aralkyl or hetaryl,and their N-oxides and addition salts, the preparation of these substances, intermediates for this purpose and the preparation thereof, fungicides containing hetarylalkenes and a corresponding method for controlling harmful fungi.

    摘要翻译： 其中Ar是杂芳基，A是C 1 -C 6 - 烷基，C 2 -C 6 - 烯基，C 3 -C 8 - 环烷基，C 3 -C 8 - 环烷基-C 1 -C 3 - 烷基或未被取代或单取代的通式I的芳基烯 ，二取代或三取代的芳基或芳烷基，其中R是氢，C 2 -C 4酰基，未取代或取代的苯甲酰基，C 1 -C 4 - 烷基磺酰基，未取代的或C 1 -C 4 - 烷基取代的苯基磺酰基或基团R 1， R1是C1-C4-烷基或未取代或取代的苯基或苄基，Hal是氟，氯，溴或碘，B是未取代或取代的单核或双核芳基，芳烷基或杂芳基及其N-氧化物和加成盐， 这些物质的制备，用于该目的的中间体及其制备方法，含有杂芳基烯的杀真菌剂和用于控制有害真菌的相应方法。

    Azolylnitriles, and fungicides containing these compounds
    4.
    发明授权
    Azolylnitriles, and fungicides containing these compounds 失效
    腈基腈和含有这些化合物的杀真菌剂

    公开(公告)号：US4639447A

    公开(公告)日：1987-01-27

    申请号：US741112

    申请日：1985-06-04

    申请人： Karl Roeser ,  Manfred Lauer ,  Hubert Sauter ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

    发明人： Karl Roeser ,  Manfred Lauer ,  Hubert Sauter ,  Eberhard Ammermann ,  Ernst-Heinrich Pommer

    IPC分类号： A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D213/57 ,  C07D233/61 ,  C07D249/08 ,  C07D333/00 ,  C07D401/06 ,  C07D409/06 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/40 ,  A01N43/50 ,  A01N43/653 ,  C07D213/57 ,  C07D233/56 ,  C07D249/08

    摘要： Compounds of the formula ##STR1## where R.sup.2 is a 5-membered or 6-membered heterocyclic structure possessing one or two hetero atoms or is phenyl which is unsubstituted or substituted by R.sub.n, R is hydrogen, alkyl, alkoxy, alkylthio, alkylsulfonyl, halogen, haloalkyl, nitro, cyano, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy or unsubstituted or substituted amino, R.sup.1 is alkyl, cycloalkyl, cycloalkylalkyl, unsubstituted or substituted aryl, unsubstituted or substituted aralkyl, unsubstituted or substituted aryloxyalkyl, unsubstituted or substituted benzyloxyalkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl or (CH.sub.2 --CH.sub.2 O).sub.m --R.sup.4, where R.sup.4 is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted aryl or unsubstituted or substituted benzyl and m is 1, 2, 3 or 4, Het is 1,2,4-triazol-1-yl, imidazol-1-yl or pyrid-3-yl, n is 1, 2, 3, 4 or 5, Z is CH.sub.2, oxygen, SO.sub.t or (R.sup.3 N), where t is 0, 1 or 2 and R.sup.3 has the same meanings as R.sup.1 and is identical to or different from R.sup.1 or together with R.sup.1 forms a diradical of the formula --(CH.sub.2).sub.k -- X--(CH.sub.2).sub.1 --, where k and 1 independently of one another are each 1, 2, 3, 4 or 5, and X is O, S or NH, or Z--R.sup.1 is unsubstituted or substituted phenyl, and their plant-tolerated acid addition salts, and fungicides containing them.

    摘要翻译： 式（I）的化合物，其中R 2是具有一个或两个杂原子的5元或6元杂环结构，或者是未被取代或被R n取代的苯基，R是氢，烷基，烷氧基，烷硫基， 烷基磺酰基，卤素，卤代烷基，硝基，氰基，未取代或取代的苯基，未取代或取代的苯氧基或未取代或取代的氨基，R1是烷基，环烷基，环烷基烷基，未取代或取代的芳基，未取代或取代的芳烷基，未取代或取代的芳氧基烷基， 取代的苄氧基烷基，未取代或取代的烯基，未取代或取代的炔基或（CH 2 -CH 2 O）m -R 4，其中R 4是C 1 -C 4烷基，未取代或取代的芳基或未取代或取代的苄基，m是1,2,3或4 ，Het为1,2,4-三唑-1-基，咪唑-1-基或吡啶-3-基，n为1,2,3,4或5，Z为CH 2，氧，SOt或（R 3 N） 其中t是0,1或2，R3与R1具有相同的含义，与o相同 r不同于R 1或与R 1一起形成式 - （CH 2）k -X-（CH 2）1的双基，其中k和1彼此独立地各自为1,2,3,4或5，并且X 是O，S或NH，或Z-R 1是未取代或取代的苯基，以及它们的植物耐受酸加成盐和含有它们的杀真菌剂。

    Triazole compounds and methods for regulating plant growth
    5.
    发明授权
    Triazole compounds and methods for regulating plant growth 失效
    三唑化合物和调节植物生长的方法

    公开(公告)号：US4969950A

    公开(公告)日：1990-11-13

    申请号：US195132

    申请日：1988-05-17

    申请人： Manfred Lauer ,  Hubert Sauter ,  Karl Roeser ,  Johann Jung ,  Wilhelm Rademacher ,  Wolfgang Will

    发明人： Manfred Lauer ,  Hubert Sauter ,  Karl Roeser ,  Johann Jung ,  Wilhelm Rademacher ,  Wolfgang Will

    IPC分类号： A01N43/653 ,  A01N49/00 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/653 ,  A01N49/00 ,  C07D233/56 ,  C07D249/08

    摘要： Triazole compounds of the formulae Ia and Ib ##STR1## where R.sup.1 is hydrogen or cyclopropyl, or is C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.2 -C.sub.4 -alkynyl, each of which is unsubstituted or substituted by methyl, ethyl, ethenyl, ethynyl, hydroxyl, fluorine, chlorine, bromine or C.sub.1 -C.sub.4 -alkoxy, or is C.sub.1 -C.sub.4 -alkoxy, C.sub.2 -C.sub.4 -alkenyloxy or C.sub.2 -C.sub.4 -alkynyloxy,R.sup.2 and R.sup.3 independently of one another are each hydrogen, straight-chain or branched C.sub.1 -C.sub.3 -alkyl, and R.sup.2 and R.sup.3 together may furthermore form a carbocyclic ring which has up to six members in each ring system and may possess bridge members, with the proviso that, in formula Ia, two or more of the radicals R.sup.1 -R.sup.3 are not hydrogen, and is hydrogen, an acyl radical CO-R.sup.5 or a sulfonyl radical SO.sub.2 R.sup.5, R.sup.5 being straight-chain or branched C.sub.1 -C.sub.8 -alkyl or unsubstituted or substituted phenyl, or is a metal cation or ammonium,are used as plant growth regulators.

    摘要翻译： 式Ia和Ib的三唑化合物其中R 1是氢或环丙基，或是C 1 -C 4 - 烷基，C 2 -C 4 - 烯基或C 2 -C 4 - 炔基，其各自是未取代的或被甲基，乙基， 乙烯基，乙炔基，羟基，氟，氯，溴或C 1 -C 4 - 烷氧基，或者C 1 -C 4 - 烷氧基，C 2 -C 4 - 烯氧基或C 2 -C 4 - 炔氧基，R 2和R 3彼此独立地各自为氢，直链 链或支链C 1 -C 3 - 烷基，并且R 2和R 3一起可以形成碳环，其在每个环系中具有至多六个成员，并且可以具有桥连构件，条件是在式Ia中，两个或更多个 基团R 1 -R 3不是氢，并且是氢，酰基-CO-R 5或磺酰基SO 2 R 5，R 5是直链或支链C 1 -C 8 - 烷基或未取代或取代的苯基，或者是金属阳离子或铵 ，被用作植物生长调节剂。

    Synergistic triazole compounds
    6.
    发明授权
    Synergistic triazole compounds 失效
    协同三唑化合物

    公开(公告)号：US4988818A

    公开(公告)日：1991-01-29

    申请号：US418225

    申请日：1989-10-06

    申请人： Manfred Lauer ,  Matthias Zipplies ,  Hubert Sauter ,  Barbara A. Moore ,  Dale R. Carlson ,  Paul S. Zorner ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    发明人： Manfred Lauer ,  Matthias Zipplies ,  Hubert Sauter ,  Barbara A. Moore ,  Dale R. Carlson ,  Paul S. Zorner ,  Karl-Otto Westphalen ,  Bruno Wuerzer

    IPC分类号： A01N43/653 ,  A01N43/88 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/653 ,  A01N43/88 ,  C07D233/56 ,  C07D249/08

    摘要： Triazole compounds I ##STR1## where A is C.sub.7 -C.sub.20 -alkyl or unsubstituted or substituted phenyl, naphthyl or pyridyl, and R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl or is --COR.sup.x or --SO.sub.2 R.sup.x, where R.sup.x is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.8 -alkyl or phenyl, and their environmentally compatible salts, and herbicides containing one or more triazole compounds I, IA or IB ##STR2## where R.sup.1 is hydrogen, cyclopropyl or unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl or is C.sub.1 -C.sub.4 -alkoxy, C.sub.2 -C.sub.4 -alkenyloxy or C.sub.2 -C.sub.4 -alkynyloxy, and R.sup.2 and R.sup.3 are each hydrogen, adamantyl or C.sub.1 -C.sub.3 -alkyl or, together with the carbon atom to which they are bonded, form unsubstituted or substituted C.sub.3 -C.sub.7 -cycloalkyl, C.sub.6 -C.sub.10 -bicycloalkyl, C.sub.6 -C.sub.10 -bicycloalkenyl, or their environmentally compatible salts and a benzothiadiazone.

    摘要翻译： 三唑化合物其中A为C 7 -C 20烷基或未取代或取代的苯基，萘基或吡啶基，R为氢或未取代或取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基 或者是-COR x或-SO 2 R x，其中R x是氢或未取代或取代的C 1 -C 8 - 烷基或苯基，以及它们的环境相容的盐和含有一种或多种三唑化合物I，IA或IB的除草剂。 其中R1是氢，环丙基或未取代的或取代的C1-C6-烷基，C2-C6-烯基或C2-C6-炔基或是C1-C4-烷氧基，C2-C4-烯氧基或C2-C4-炔氧基，R2 C 3 -C 7 - 环烷基，C 6 -C 10 - 双环烯基或它们的连接基团的碳原子一起形成未取代或取代的C 3 -C 7 - 环烷基，C 6 -C 10 - 双环烷基，C 6 -C 10 - 环境相容的盐和苯并噻二唑。