公开(公告)号：US08822746B2

公开(公告)日：2014-09-02

申请号：US13263759

申请日：2010-03-22

申请人： Marc Armbruster ,  Kirill Kovnir ,  Juri Grin ,  Robert Schlogl ,  Peter Gille ,  Marc Heggen ,  Michael Feuerbacher

发明人： Marc Armbruster ,  Kirill Kovnir ,  Juri Grin ,  Robert Schlogl ,  Peter Gille ,  Marc Heggen ,  Michael Feuerbacher

IPC分类号： C07C5/05 ,  C07C5/08 ,  C07C5/09 ,  C07C7/163 ,  B01J23/62 ,  C30B15/00 ,  B01J23/75 ,  C30B29/52 ,  C10G45/32 ,  C22C21/00 ,  C22C1/04 ,  B22F7/08 ,  C30B17/00 ,  C30B11/00 ,  C07C7/167 ,  B01J23/745 ,  B01J35/00

CPC分类号： C10G45/32 ,  B01J23/745 ,  B01J23/75 ,  B01J35/002 ,  B22F7/08 ,  B22F2998/00 ,  C07C7/167 ,  C10G2400/20 ,  C22C1/0491 ,  C22C21/00 ,  C30B11/00 ,  C30B15/00 ,  C30B17/00 ,  C30B29/52 ,  Y02P20/52 ,  C07C11/04 ,  B22F5/106

摘要： The present invention relates to a process for the hydrogenation, in particular the selective hydrogenation of unsaturated hydrocarbon compounds, such as the selective hydrogenation of acetylene to ethylene, using a hydrogenation catalyst comprising an ordered intermetallic compound, namely an ordered cobalt-aluminum or iron-aluminum intermetallic compound. According to another aspect, the present invention relates to a catalyst comprising a support and at least one specific ordered cobalt-aluminum and/or iron-aluminum intermetallic compound supported thereon, as well as to the use of specific ordered intermetallic cobalt-aluminum and iron-aluminum intermetallic compounds as catalysts. The ordered cobalt-aluminum and iron-aluminum intermetallic compounds proved to be highly selective and long-term stable catalysts, e.g. in the selective hydrogenation of acetylene to ethylene in a large excess of ethylene.

摘要翻译： 本发明涉及一种氢化方法，特别是不饱和烃化合物的选择性氢化，例如使用包含有序金属间化合物的氢化催化剂，即有序的钴 - 铝或铁 - 铝金属间化合物。 根据另一方面，本发明涉及一种催化剂，其包含载体和至少一种在其上负载的特定有序的钴 - 铝和/或铁 - 铝金属间化合物，以及使用特定有序的金属间钴 - 铝和铁 - 铝金属间化合物作为催化剂。 有序的钴铝和铁 - 铝金属间化合物被证明是高选择性和长期稳定的催化剂，例如。 在大量过量的乙烯中乙炔选择性氢化成乙烯。

公开(公告)号：US20120029254A1

公开(公告)日：2012-02-02

申请号：US13263759

申请日：2010-03-22

申请人： Marc Armbruster ,  Kirill Kovnir ,  Juri Grin ,  Robert Schlogl ,  Peter Gille ,  Marc Heggen ,  Michael Feuerbacher

发明人： Marc Armbruster ,  Kirill Kovnir ,  Juri Grin ,  Robert Schlogl ,  Peter Gille ,  Marc Heggen ,  Michael Feuerbacher

IPC分类号： C07C5/05 ,  C07C5/02 ,  C07C5/03 ,  B01J21/02

CPC分类号： C10G45/32 ,  B01J23/745 ,  B01J23/75 ,  B01J35/002 ,  B22F7/08 ,  B22F2998/00 ,  C07C7/167 ,  C10G2400/20 ,  C22C1/0491 ,  C22C21/00 ,  C30B11/00 ,  C30B15/00 ,  C30B17/00 ,  C30B29/52 ,  Y02P20/52 ,  C07C11/04 ,  B22F5/106

摘要： The present invention relates to a process for the hydrogenation, in particular the selective hydrogenation of unsaturated hydrocarbon compounds, such as the selective hydrogenation of acetylene to ethylene, using a hydrogenation catalyst comprising an ordered intermetallic compound, namely an ordered cobalt-aluminum or iron-aluminum intermetallic compound. According to another aspect, the present invention relates to a catalyst comprising a support and at least one specific ordered cobalt-aluminum and/or iron-aluminum intermetallic compound supported thereon, as well as to the use of specific ordered intermetallic cobalt-aluminum and iron-aluminum intermetallic compounds as catalysts. The ordered cobalt-aluminum and iron-aluminum intermetallic compounds proved to be highly selective and long-term stable catalysts, e.g. in the selective hydrogenation of acetylene to ethylene in a large excess of ethylene.

摘要翻译： 本发明涉及一种氢化方法，特别是不饱和烃化合物的选择性氢化，例如使用包含有序金属间化合物的氢化催化剂，即有序的钴 - 铝或铁 - 铝金属间化合物。 根据另一方面，本发明涉及一种催化剂，其包含载体和至少一种在其上负载的特定有序的钴 - 铝和/或铁 - 铝金属间化合物，以及使用特定有序的金属间钴 - 铝和铁 - 铝金属间化合物作为催化剂。 有序的钴铝和铁 - 铝金属间化合物被证明是高选择性和长期稳定的催化剂，例如。 在大量过量的乙烯中乙炔选择性氢化成乙烯。