SUBSTITUTED 4-CYAN-3-(2,6-DIFLUOROPHENYL)-4-PHENYLBUTANOATES, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF AS HERBICIDES AND PLANT GROWTH REGULATORS
    5.
    发明申请
    SUBSTITUTED 4-CYAN-3-(2,6-DIFLUOROPHENYL)-4-PHENYLBUTANOATES, METHOD FOR THE PRODUCTION THEREOF AND USE THEREOF AS HERBICIDES AND PLANT GROWTH REGULATORS 审中-公开
    取代的4-氰基-3-(2,6-二氟苯基)-4-苯基丁酸酯,其生产方法及其作为除草剂和植物生长调节剂的用途

    公开(公告)号:US20140087945A1

    公开(公告)日:2014-03-27

    申请号:US14005759

    申请日:2012-03-12

    摘要: Compounds of the formula (I) or salts thereof, in which R1 is H or a hydrolyzable radical, (R2)n is n substituents R2, where R2 independently of the others is Hal, CN, NO2, (C1-C8)-alkyl, (C1-C8)-alkoxy, (C1-C8)-alkylthio, (C1-C8)-alkylsulfinyl, (C1-C8)-alkylsulfonyl, (C1-C6)-haloalkyl, (C1-C6)-haloalkoxy, (C1-C6)-haloalkylthio, (C1-C6)-haloalkylsulfinyl, (C1-C6)-haloalkylsulfonyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, tri-[(C1-C4)-alkyl]-silyl or tri-[(C1-C4)-alkyl]-silyl-(C1-C4)-alkyl or where in each case two groups R2 located ortho at the ring together are —Z1-A*-Z2, in which A* is (C1-C4)-alkylene, which is optionally substituted by radicals from the group consisting of halogen, (C1-C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-alkoxy and (C1-C4)-haloalkoxy, Z1, Z2 are each a direct bond, O or S and where the group —Z1-A*-Z2 together with the carbon atoms, attached to the group, of the phenyl ring form a fused-on 5- or 6-membered ring, and n is 0, 1, 2, 3, 4 or 5, excluding the compound in which R1 is methyl and (R2)n is 3-fluoro (n=1), are suitable for use as herbicides and plant growth regulators and can be prepared by the process of claim 8.

    摘要翻译: 式(I)化合物或其盐,其中R 1为H或可水解基团,(R2)n为n取代基R2,其中R2独立地为Hal,CN,NO2,(C1-C8) - 烷基 ,(C1-C8) - 烷氧基,(C1-C8) - 烷硫基,(C1-C8)烷基亚磺酰基,(C1-C8) - 烷基磺酰基,(C1-C6) - 卤代烷基,(C1-C6) - 卤代烷氧基,( (C 1 -C 6) - 卤代烷基亚磺酰基,(C 1 -C 6) - 卤代烷基磺酰基,(C 2 -C 6) - 烯基,(C 2 -C 6) - 炔基,三 - [(C 1 -C 4) - 烷基] 甲硅烷基或三 - [(C 1 -C 4) - 烷基] - 甲硅烷基 - (C 1 -C 4) - 烷基或其中在每种情况下两个位于环的环上的两个R一起为-Z1-A * -Z2,其中A (C1-C4) - 烷基,(C1-C4) - 烷氧基,(C1-C4) - 烷氧基,(C1-C4) - 烷氧基,(C1-C4) C 4) - 卤代烷氧基,Z 1,Z 2各自为直接键,O或S,并且其中与基团连接的苯基上的基团-Z1-A * -Z2与碳原子一起形成稠合的5- 或6元环,n为0,1,2,3,4或5,不包括化合物i n,其中R1是甲基,(R2)n是3-氟(n = 1),适合用作除草剂和植物生长调节剂,并且可以通过权利要求8的方法制备。

    PRODUCTION AND USE OF ZINC AMIDES
    6.
    发明申请
    PRODUCTION AND USE OF ZINC AMIDES 有权
    锌的生产和使用

    公开(公告)号:US20110288296A1

    公开(公告)日:2011-11-24

    申请号:US13147339

    申请日:2010-02-11

    摘要: The application relates to a reagent of the general formula R1R2N—ZnY LiY  (I) wherein R1, R2 are, independently, selected from H, substituted or unsubstituted aryl or heteroaryl containing one or more heteroatoms, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or silyl derivatives thereof; and R1 and R2 together can be part of a cyclic or polymeric structure; and wherein at least one of R1 and R2 is other than H; Y is selected from the group consisting of F; Cl; Br; I; CN; SCN; NCO; Halon, wherein n=3 or 4 and Hal is selected from Cl, Br and I; NO3; BF4; PF6; H; a carboxylate of the general formula RXCO2; an alcoholate of the general formula ORX; a thiolate of the general formula SRX; RXP(O)O2; or SCORX; or SCSRX; OnSRx; wherein n=2 or 3; or NOn, wherein n=2 or 3; and a derivative thereof; wherein Rx is a substituted or unsubstituted aryl or heteroaryl containing one or more heteroatoms, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or derivatives thereof, or H; or as adduct with a solvent; as well as to the preparation and use thereof.34

    摘要翻译: 本申请涉及通式为R 1 R 2 N-ZnY LiY(I)的试剂,其中R 1,R 2独立地选自H,具有直链,支链或环状的取代或未取代的一个或多个杂原子的取代或未取代的芳基或杂芳基 烷基,烯基,炔基或甲硅烷基衍生物; R1和R2一起可以是环状或聚合物结构的一部分; 并且其中R 1和R 2中的至少一个不是H; Y选自F; Cl; Br; 一世; CN; SCN; NCO; Halon,其中n = 3或4,Hal选自Cl,Br和I; NO3; BF4; PF6; H; 通式为RXCO2的羧酸酯; 通式ORX的醇化物; 通式SRX的硫醇盐; RXP(O)O2; 或SCORX; 或SCSRX; OnSRx; 其中n = 2或3; 或NO n,其中n = 2或3; 及其衍生物; 其中Rx是取代或未取代的芳基或含有一个或多个杂原子的直链,支链或环状取代或未取代的烷基,烯基,炔基或衍生物,或H; 或作为与溶剂的加合物; 以及其制备和使用。 34

    Production and use of zinc amides
    7.
    发明授权
    Production and use of zinc amides 有权
    生产和使用锌酰胺

    公开(公告)号:US09334237B2

    公开(公告)日:2016-05-10

    申请号:US13147339

    申请日:2010-02-11

    IPC分类号: C07D211/10 C07F3/00

    摘要: A reagent of the formula R1R2N—ZnY LiY  (I) wherein R1 and R2 are independently, selected from H, aryl or heteroaryl, linear, branched or cyclic, substituted or unsubstituted alkyl, alkenyl, alkynyl, or silyl derivatives thereof; and R1 and R2 together form part of a cyclic or polymeric structure; R1 and/or R2 is not H; Y is F, Cl, Br, I, CN, SCN, NCO or HalOn, wherein n=3 or 4 and Hal is Cl, Br or I; NO3; BF4; PF6; H; a carboxylate of formula R5CO2; an alcoholate of formula OR5; a thiolate of formula SR5; R5P(O)O2; or SCOR5; or SCSR5; OnSR5; wherein n=2 or 3; or NOn, wherein n=2 or 3; and a derivative thereof; wherein R5 is an aryl or heteroaryl, linear, branched or cyclic, alkyl, alkenyl, alkynyl, or derivatives thereof, or H; or as adduct with a solvent; and preparation and use thereof.

    摘要翻译: 式R 1 R 2 N-ZnY LiY(I)的试剂,其中R 1和R 2独立地选自H,芳基或杂芳基,直链,支链或环状的取代或未取代的烷基,链烯基,炔基或甲硅烷基衍生物; 并且R1和R2一起形成环状或聚合物结构的一部分; R1和/或R2不是H; Y是F,Cl,Br,I,CN,SCN,NCO或HalOn,其中n = 3或4,Hal是Cl,Br或I; NO3; BF4; PF6; H; 式R5CO2的羧酸酯; 式OR5的醇化物; 式SR5的硫醇盐; R5P(O)O2; 或SCOR5; 或SCSR5; OnSR5; 其中n = 2或3; 或NO n,其中n = 2或3; 及其衍生物; 其中R5是直链,支链或环状的烷基,烯基,炔基或衍生物的芳基或杂芳基,或H; 或作为与溶剂的加合物; 及其制备和使用。