Reservoir feed method of making ceramic composite structures and
structures made thereby
    1.
    发明授权
    Reservoir feed method of making ceramic composite structures and structures made thereby 失效
    由此制作陶瓷复合结构和结构的储层进料方法

    公开(公告)号:US4918034A

    公开(公告)日:1990-04-17

    申请号:US168358

    申请日:1988-03-15

    IPC分类号: B28B7/34 C04B35/65

    摘要: A method for producing a self-supporting ceramic composite structure comprising a ceramic matrix embedding a filler, includes oxidizing a parent metal to form a polycrystalline material comprising the oxidation reaction product of the parent metal and, optionally, one or more metallic constituents. The method includes heating the parent metal to provide a source of molten parent metal and a reservoir of molten metal which is in communication with the parent metal having a chemical composition which is different from the parent metal and contacting the molten parent metal with a permeable bedding of filler. The molten parent metal reacts with the oxidant to form the oxidation reaction product and is replenished by the reservoir as the reacting continues for a time sufficient to grow the oxidation reaction product to a desired extent and thereby embed at least a portion of the bedding of filler within the oxidation reaction product to form the ceramic composite structure. The bedding of filler may have any suitable shape, including that of a hollow body, the interior of which is contacted by the molten parent metal to grow the oxidation reaction product through the shaped, hollow body of filler.

    摘要翻译: 一种生产包含填充填料的陶瓷基体的自支撑陶瓷复合结构体的方法包括氧化母体金属以形成包含母体金属和任选的一种或多种金属成分的氧化反应产物的多晶材料。 该方法包括加热母体金属以提供熔融母体金属源和熔融金属储存器,其与母体金属连通,其母体金属具有不同于母体金属的化学组成并使熔融母体金属与可渗透层压板接触 的填料。 熔融母体金属与氧化剂反应形成氧化反应产物,并由储存器补充,因为反应继续进行足以将氧化反应产物生长至所需程度的时间,从而嵌入填料填料的至少一部分 在氧化反应产物内形成陶瓷复合结构。 填料的床垫可以具有任何合适的形状,包括中空体的形状,其内部与熔融母体金属接触,以通过成型的中空填料体生长氧化反应产物。

    Self-supporting ceramic structures and methods of making the same
    4.
    发明授权
    Self-supporting ceramic structures and methods of making the same 失效
    自支撑陶瓷结构及其制作方法

    公开(公告)号:US5024794A

    公开(公告)日:1991-06-18

    申请号:US168301

    申请日:1988-03-15

    IPC分类号: C04B35/65

    CPC分类号: C04B35/652

    摘要: A method of producing a self-supporting ceramic or ceramic composite structures which includes providing a first self-supporting ceramic or ceramic composite body comprising (i) a polycrystalline oxidation reaction product formed upon oxidation of a first molten parent metal with a first oxidant, and (ii) interconnected porosity at least partially accessible from one or more surfaces of said first ceramic body. A second ceramic body is used to form, by reaction with an oxidant, a second polycrystalline material which is infiltrated into the porosity of at least a portion of said first ceramic body.

    Reservoir feed method of making ceramic composite structures and
structures made thereby
    5.
    发明授权
    Reservoir feed method of making ceramic composite structures and structures made thereby 失效
    由此制作陶瓷复合结构和结构的储层进料方法

    公开(公告)号:US5086019A

    公开(公告)日:1992-02-04

    申请号:US478845

    申请日:1990-02-12

    IPC分类号: B28B7/34 C04B35/65

    摘要: A method for producing a self-supporting ceramic composite structure comprising a ceramic matrix embedding a filler, includes oxidizing a parent metal to form a polycrystalline material comprising the oxidation reaction product of the parent metal and, optionally, one or more metallic constituents. The method includes heating the parent metal to provide a source of molten parent metal and a reservoir of molten metal which is in communication with the parent metal and contacting the molten parent metal with a permeable bedding of filler. The molten parent metal reacts with the oxidant to form the oxidation reaction product and is replenished by the reservoir as the reacting continues for a time sufficient to grow the oxidation reaction product to a desired extent and thereby embed at least a portion of the bedding of filler within the oxidation reaction product to form the ceramic composite structure. The bedding of filler may have any suitable shape, including that of a hollow body, the interior of which is contacted by the molten parent metal to grow the oxidation reaction product through the shaped, hollow body of filler.

    摘要翻译: 一种生产包含填充填料的陶瓷基体的自支撑陶瓷复合结构体的方法包括氧化母体金属以形成包含母体金属和任选的一种或多种金属成分的氧化反应产物的多晶材料。 该方法包括加热母体金属以提供熔融母体金属源和与母体金属连通并与熔融母体金属与填充物的可渗透层合物接触的熔融金属储存器。 熔融母体金属与氧化剂反应形成氧化反应产物,并由储存器补充,因为反应继续进行足以将氧化反应产物生长至所需程度的时间,从而嵌入填料填料的至少一部分 在氧化反应产物内形成陶瓷复合结构。 填料的床垫可以具有任何合适的形状,包括中空体的形状,其内部与熔融母体金属接触,以通过成型的中空填料体生长氧化反应产物。

    Method of making shaped ceramic composites with the use of a barrier and
articles produced thereby
    7.
    发明授权
    Method of making shaped ceramic composites with the use of a barrier and articles produced thereby 失效
    使用阻挡物制造成形陶瓷复合材料的方法和由此制备的制品

    公开(公告)号:US5340655A

    公开(公告)日:1994-08-23

    申请号:US819308

    申请日:1992-01-09

    摘要: In the present invention, there is provided a method for producing a self-supporting ceramic or ceramic composite body by the oxidation of a parent metal to form a polycrystalline ceramic material comprising the oxidation reaction product of said parent metal with an oxidant, including a vapor-phase oxidant, and optionally one or more metallic constituents dispersed throughout the polycrystalline ceramic material. The method comprises the steps of providing at least a portion of said parent metal with a barrier means at least partially spaced from said parent metal for establishing at least one surface of the ceramic body, and heating said parent metal to a temperature above its melting point but below the melting point of the oxidation reaction product to form a body of molten metal. At that temperature, the molten metal is reacted with the oxidant, thus forming the oxidation reaction product. At least a portion of the oxidation reaction product is maintained in contact with and between the molten metal and oxidant to transport the molten metal through the oxidation reaction product toward the barrier means and into contact with the oxidant so that fresh oxidation reaction product continues to form at an interface between the oxidant and previously formed oxidation reaction product. The reaction is continued until the oxidation reaction product contacts the barrier means to produce a ceramic body having the surface established by the barrier means. A shaped ceramic composite is formed by superimposing a barrier means onto either a loose mass of filler material or a self-supporting preform, and infiltrating the mass of filler or preform with the polycrystalline ceramic matrix, which grows until it contacts the barrier means.

    摘要翻译: 在本发明中,提供了一种通过母体金属的氧化制造自支撑陶瓷或陶瓷复合体的方法,以形成多晶陶瓷材料,该多晶陶瓷材料包括所述母体金属的氧化反应产物与氧化剂,包括蒸汽 相氧化剂和任选的一种或多种分散在整个多晶陶瓷材料中的金属成分。 该方法包括以下步骤:使所述母体金属的至少一部分具有与所述母体金属至少部分间隔开的阻挡装置,用于建立陶瓷体的至少一个表面,并将所述母体金属加热到高于其熔点的温度 但低于氧化反应产物的熔点以形成熔融金属体。 在该温度下,熔融金属与氧化剂反应,形成氧化反应产物。 氧化反应产物的至少一部分保持与熔融金属和氧化剂接触并且在熔融金属和氧化剂之间输送熔融金属通过氧化反应产物朝向阻挡装置并与氧化剂接触,使得新鲜的氧化反应产物继续形成 在氧化剂和预先形成的氧化反应产物之间的界面处。 反应继续进行,直到氧化反应产物与阻挡装置接触以产生具有通过阻挡装置建立的表面的陶瓷体。 通过将隔离装置叠加在松散的填充材料或自支撑预成型件上,并将多孔陶瓷基体浸入填料或预成型体中,形成成形的陶瓷复合材料,该多晶陶瓷基体生长直至与阻挡装置接触。

    Method of forming a filler material for use in various metal matrix
composite body formation processes
    8.
    发明授权
    Method of forming a filler material for use in various metal matrix composite body formation processes 失效
    形成用于各种金属基复合体形成工艺中的填充材料的方法

    公开(公告)号:US5329984A

    公开(公告)日:1994-07-19

    申请号:US59441

    申请日:1993-05-07

    摘要: The present invention relates to a novel process for forming a filler material which can be used in various metal matrix composite formation processes for forming metal matrix composite bodies. Particularly, an infiltration enhancer or an infiltration enhancer precursor or an infiltrating atmosphere are in communication with a filler material or a preform, at least at some point during the process, which permits molten matrix metal to spontaneously infiltrate the filler material or preform. Such spontaneous infiltration occurs without the requirement for the application of any pressure or vacuum. The amount of matrix metal provided is sufficient only to coat, to a desired thickness, substantially all of the filler material. The coated filler material is thereafter comminuted for use in any desired metal matrix composite formation process.

    摘要翻译: 本发明涉及可用于形成金属基质复合体的各种金属基复合材料形成方法中的填充材料的形成方法。 特别地,渗透增强剂或渗透增强剂前体或渗透气氛至少在该过程中的某一点处与填料或预型体连通,这允许熔融基体金属自发地渗入填料或预型体。 发生这种自发性渗透,而不需要施加任何压力或真空。 提供的基体金属的量足以仅涂覆到所需的厚度,基本上全部填充材料。 然后将涂覆的填充材料粉碎以用于任何所需的金属基质复合物形成工艺。

    Method of modifying the properties of a metal matrix composite body
    9.
    发明授权
    Method of modifying the properties of a metal matrix composite body 失效
    改性金属基复合体的性能的方法

    公开(公告)号:US5301738A

    公开(公告)日:1994-04-12

    申请号:US841241

    申请日:1992-02-24

    摘要: The present invention relates to modifying the properties of a metal matrix composite body by a post formation process modification treatment. The post formation process treatment may be applicable to a variety of metal matrix composite bodies produced by various techniques, and is particularly applicable to modifying the properties of a metal matrix composite body produced by a spontaneous infiltration technique. Particularly, at least a portion of the matrix metal of the metal matrix composite body and/or the filler material of the metal matrix composite body is modified or altered after the formation process. Preferably, the preform contains a second non-metal material, an infiltration enhancer of infiltration enhancer precursor, and an infiltration atmosphere.

    摘要翻译: 本发明涉及通过后形成工艺改性处理改性金属基复合体的性能。 后形成处理可以适用于通过各种技术制造的各种金属基复合体,特别适用于通过自发渗透技术制造的金属基复合体的特性。 特别地,金属基体复合体的基体金属的至少一部分和/或金属基复合体的填充材料在形成工序之后被修改或改变。 优选地,预成型体包含第二非金属材料,渗透增强剂前体的渗透增强剂和渗透气氛。

    Inverse shape replication method of making ceramic composite articles
and articles obtained thereby
    10.
    发明授权
    Inverse shape replication method of making ceramic composite articles and articles obtained thereby 失效
    制造陶瓷复合制品的反型复制方法及由此得到的制品

    公开(公告)号:US5275987A

    公开(公告)日:1994-01-04

    申请号:US983191

    申请日:1992-11-30

    摘要: A method of producing a self-supporting ceramic composite body having therein at least one cavity which inversely replicates the geometry of a positive mold of parent metal. The method includes embedding the mold of parent metal within a conformable bed of filler to provide therein a cavity shaped and filled by the mold. The assembly is heated to melt the parent metal mold, e.g., an aluminum parent metal mold, and contacted with an oxidant to oxidize the molten parent metal to form a polycrystalline material which grows through the surrounding bed of filler, the molten metal being drawn through the growing polycrystalline material to be oxidized at the interface between the oxidant and previously formed oxidation reaction product whereby the cavity formerly filled by the mold of parent metal is eventually evacuated of the metal. There remains behind a cavity whose shape inversely replicates the original shape of the mold. The method provides ceramic composite articles having therein at least one cavity inversely replicating the shape of the mold which supplied the parent metal for oxidation.

    摘要翻译: 一种自支撑陶瓷复合体的制造方法,其中具有至少一个反向复制母体金属正模的几何形状的空腔。 该方法包括将母体金属模具嵌入到适形的填料床中,以在其中提供由模具成型并填充的空腔。 将组件加热以熔化母体金属模具,例如铝母体金属模具,并与氧化剂接触以氧化熔融母体金属,以形成通过周围的填料床生长的多晶材料,熔融金属被吸入 在氧化剂和预先形成的氧化反应产物之间的界面处被氧化的生长中的多晶材料,由此母体金属的模具以前被填充的空腔最终被排出金属。 在其后面仍然存在一个模腔,其形状相反地复制了模具的原始形状。 该方法提供了陶瓷复合材料制品,其中具有至少一个空腔,其相反地复制了供应母体金属进行氧化的模具的形状。