公开(公告)号：US07651968B2

公开(公告)日：2010-01-26

申请号：US12097017

申请日：2006-12-05

申请人： Marco Bosch ,  Jan Eberhardt ,  Roderich Röttger

发明人： Marco Bosch ,  Jan Eberhardt ,  Roderich Röttger

IPC分类号： B01J29/06 ,  C07C209/60 ,  C07C209/14

CPC分类号： B01J37/0009 ,  B01J29/04 ,  B01J29/06 ,  B01J29/18 ,  B01J29/83 ,  B01J29/85 ,  B01J35/002 ,  B01J2229/42 ,  C07C209/16 ,  C07C211/04

摘要： A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the steps (I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body, wherein a silicone resin having a softening point of ≧30° C. is used as binder, shaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

摘要翻译： 一种用于生产包含微孔材料和至少一种含硅粘合剂的成形体的方法，其包括步骤（I）制备包含微孔材料，粘合剂和润滑剂的混合物，（II）混合和致密化 混合物（III）成型，得到成型体，（IV）成型体的煅烧，其中使用软化点> = 30℃的有机硅树脂作为粘合剂，成型体可以是 通过该方法生产，它们用作催化剂，特别是在有机合成中，非常特别优选用于制备甲胺的方法。

公开(公告)号：US07754921B2

公开(公告)日：2010-07-13

申请号：US12088743

申请日：2006-09-21

申请人： Marco Bosch ,  Roderich Röttger ,  Jan Eberhardt ,  Thomas Krug ,  Manfred Julius ,  Karl-Heínz Roβ ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Röttger ,  Jan Eberhardt ,  Thomas Krug ,  Manfred Julius ,  Karl-Heínz Roβ ,  Theodor Weber

IPC分类号： C07C209/16 ,  B01J29/00

CPC分类号： C07C209/16 ,  B01J21/12 ,  B01J21/16 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0009 ,  B01J37/0018 ,  C07C211/04

摘要： Shaped body comprising an aluminosilicate and aluminum oxide, wherein the shaped body has a molar Al/Si ratio in the range from 10 to 30 and an at least bimodal pore distribution for pores having a diameter of greater than 1 nm, with the volume of the pores of the shaped body having a diameter of greater than 10 nm corresponding to at least 40% of the total pore volume of the shaped body, process for producing it and process for the continuous preparation of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the abovementioned shaped bodies are used as catalyst.

摘要翻译： 包括铝硅酸盐和氧化铝的成形体，其中成形体的Al / Si摩尔比在10至30的范围内，并且对于具有大于1nm直径的孔的至少双峰孔分布，其体积 成形体的孔径大于10nm，对应于成形体的总孔体积的至少40％，其生产方法和通过甲醇和/或二甲醚的反应连续制备甲胺的方法 在存在非均相催化剂的情况下使用氨，其中上述成形体用作催化剂。

公开(公告)号：US07435855B2

公开(公告)日：2008-10-14

申请号：US11629801

申请日：2005-06-16

申请人： Marco Bosch ,  Jan Kurt Eberhardt ,  Roderich Röttger ,  Thomas Krug ,  Johann-Peter Melder

发明人： Marco Bosch ,  Jan Kurt Eberhardt ,  Roderich Röttger ,  Thomas Krug ,  Johann-Peter Melder

IPC分类号： C07C209/14

CPC分类号： C07C209/16 ,  C07C211/04

摘要： Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the steps (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.

摘要翻译： 在多相催化剂存在下，通过甲醇和/或二甲醚与氨的反应连续合成甲胺的方法，其中使用的催化剂是成形体，其包含微孔材料和至少一种有机硅化合物作为粘合剂，并且可以是 通过包括步骤（I）制备包含微孔材料，粘合剂，粘贴剂和溶剂的混合物的方法制备的方法制备，（II）混合和混合物的致密化，（III）使致密混合物成形，得到 （IV）成型体的干燥和（V）干燥成型体的煅烧。

公开(公告)号：US20110184210A1

公开(公告)日：2011-07-28

申请号：US13082030

申请日：2011-04-07

申请人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

IPC分类号： C07C209/60

CPC分类号： C07C209/16 ,  B01J8/0221 ,  B01J8/0285 ,  B01J2208/00132 ,  B01J2208/00353 ,  B01J2208/0053 ,  C07C211/04

摘要： In the continuous process for preparing alkylamines by reacting C1-4-alkanols with ammonia in the gas phase in the presence of a shape-selective fixed-bed catalyst in a cooled reactor, the shape-selective fixed-bed catalyst is present in a single contiguous fixed bed in the reactor and tubes through which coolants are passed run within the fixed bed to regulate the temperature of the fixed bed.

摘要翻译： 在冷却的反应器中，在形状选择性固定床催化剂存在下，在气相中使C 1-4 - 链烷醇与氨反应制备烷基胺的连续方法中，形状选择性固定床催化剂存在于单一 反应器中连续的固定床和冷却剂通过的管通过固定床内以调节固定床的温度。

公开(公告)号：US07951974B2

公开(公告)日：2011-05-31

申请号：US12771414

申请日：2010-04-30

申请人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

IPC分类号： C07C209/16

CPC分类号： C07C209/16 ,  B01J8/0221 ,  B01J8/0285 ,  B01J2208/00132 ,  B01J2208/00353 ,  B01J2208/0053 ,  C07C211/04

摘要： In the continuous process for preparing alkylamines by reacting C1-4-alkanols with ammonia in the gas phase in the presence of a shape-selective fixed-bed catalyst in a cooled reactor, the shape-selective fixed-bed catalyst is present in a single contiguous fixed bed in the reactor and tubes through which coolants are passed run within the fixed bed to regulate the temperature of the fixed bed.

摘要翻译： 在冷却的反应器中，在形状选择性固定床催化剂存在下，在气相中使C 1-4 - 链烷醇与氨反应制备烷基胺的连续方法中，形状选择性固定床催化剂存在于单一 反应器中连续的固定床和冷却剂通过的管通过固定床内以调节固定床的温度。

公开(公告)号：US20100210877A1

公开(公告)日：2010-08-19

申请号：US12771414

申请日：2010-04-30

申请人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

IPC分类号： C07C209/16

CPC分类号： C07C209/16 ,  B01J8/0221 ,  B01J8/0285 ,  B01J2208/00132 ,  B01J2208/00353 ,  B01J2208/0053 ,  C07C211/04

摘要： In the continuous process for preparing alkylamines by reacting C1-4-alkanols with ammonia in the gas phase in the presence of a shape-selective fixed-bed catalyst in a cooled reactor, the shape-selective fixed-bed catalyst is present in a single contiguous fixed bed in the reactor and tubes through which coolants are passed run within the fixed bed to regulate the temperature of the fixed bed.

摘要翻译： 在冷却的反应器中，在形状选择性固定床催化剂存在下，在气相中使C 1-4 - 链烷醇与氨反应制备烷基胺的连续方法中，形状选择性固定床催化剂存在于单一 反应器中连续的固定床和冷却剂通过的管通过固定床内以调节固定床的温度。

公开(公告)号：US07714169B2

公开(公告)日：2010-05-11

申请号：US12258563

申请日：2008-10-27

申请人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Röttger ,  Bernd Stein ,  Thomas Krug ,  Johann-Peter Melder ,  Theodor Weber

IPC分类号： C07C209/16

CPC分类号： C07C209/16 ,  B01J8/0221 ,  B01J8/0285 ,  B01J2208/00132 ,  B01J2208/00353 ,  B01J2208/0053 ,  C07C211/04

摘要： In the continuous process for preparing alkylamines by reacting C1-4-alkanols with ammonia in the gas phase in the presence of a shape-selective fixed-bed catalyst in a cooled reactor, the shape-selective fixed-bed catalyst is present in a single contiguous fixed bed in the reactor and tubes through which coolants are passed run within the fixed bed to regulate the temperature of the fixed bed.

摘要翻译： 在冷却的反应器中，在形状选择性固定床催化剂存在下，在气相中使C 1-4 - 链烷醇与氨反应制备烷基胺的连续方法中，形状选择性固定床催化剂存在于单一 反应器中连续的固定床和冷却剂通过的管通过固定床内以调节固定床的温度。

公开(公告)号：US20080255390A1

公开(公告)日：2008-10-16

申请号：US12088743

申请日：2006-09-21

申请人： Marco Bosch ,  Roderich Rottger ,  Jan Eberhardt ,  Thomas Krug ,  Manfred Julius ,  Karl-Heinz Ross ,  Theodor Weber

发明人： Marco Bosch ,  Roderich Rottger ,  Jan Eberhardt ,  Thomas Krug ,  Manfred Julius ,  Karl-Heinz Ross ,  Theodor Weber

IPC分类号： B01J21/12 ,  B01J21/04 ,  B01J35/10 ,  C07C209/16

CPC分类号： C07C209/16 ,  B01J21/12 ,  B01J21/16 ,  B01J35/002 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/109 ,  B01J35/1095 ,  B01J37/0009 ,  B01J37/0018 ,  C07C211/04

摘要： Shaped body comprising an aluminosilicate and aluminum oxide, wherein the shaped body has a molar Al/Si ratio in the range from 10 to 30 and an at least bimodal pore distribution for pores having a diameter of greater than 1 nm, with the volume of the pores of the shaped body having a diameter of greater than 10 nm corresponding to at least 40% of the total pore volume of the shaped body, process for producing it and process for the continuous preparation of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the abovementioned shaped bodies are used as catalyst.

摘要翻译： 包括铝硅酸盐和氧化铝的成形体，其中成形体的Al / Si摩尔比在10至30的范围内，并且对于具有大于1nm直径的孔的至少双峰孔分布，其体积 成形体的孔径大于10nm，对应于成形体的总孔体积的至少40％，其生产方法和通过甲醇和/或二甲醚的反应连续制备甲胺的方法 在存在非均相催化剂的情况下使用氨，其中上述成形体用作催化剂。

公开(公告)号：US20090005600A1

公开(公告)日：2009-01-01

申请号：US12097017

申请日：2006-12-05

申请人： Marco Bosch ,  Jan Eberhardt ,  Roderich Rottger

发明人： Marco Bosch ,  Jan Eberhardt ,  Roderich Rottger

IPC分类号： C07C209/16 ,  B01J31/06 ,  B01J29/06 ,  B01J29/08 ,  B01J29/18 ,  B01J21/06

CPC分类号： B01J37/0009 ,  B01J29/04 ,  B01J29/06 ,  B01J29/18 ,  B01J29/83 ,  B01J29/85 ,  B01J35/002 ,  B01J2229/42 ,  C07C209/16 ,  C07C211/04

摘要： A process for producing a shaped body comprising a microporous material and at least one silicon-comprising binder, which comprises the steps(I) preparation of a mixture comprising the microporous material, the binder and a lubricant, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body and (IV) calcination of the shaped body, wherein a silicone resin having a softening point of ≧30° C. is used as binder, shaped bodies which can be produced by this process, their use as catalyst, in particular in organic synthesis and very particularly preferably in a process for preparing methylamines.

摘要翻译： 一种用于生产包含微孔材料和至少一种含硅粘合剂的成形体的方法，其包括步骤（I）制备包含微孔材料，粘合剂和润滑剂的混合物，（II）混合和致密化 混合物（III）成型，得到成型体，（IV）成型体的煅烧，其中使用软化点> = 30℃的有机硅树脂作为粘合剂，成型体可以是 通过该方法生产，它们用作催化剂，特别是在有机合成中，非常特别优选用于制备甲胺的方法。

公开(公告)号：US20080033212A1

公开(公告)日：2008-02-07

申请号：US11629801

申请日：2005-06-16

申请人： Marco Bosch ,  Jan Eberhardt ,  Roderich Rottger ,  Thomas Krug ,  Johann-Peter Melder

发明人： Marco Bosch ,  Jan Eberhardt ,  Roderich Rottger ,  Thomas Krug ,  Johann-Peter Melder

IPC分类号： C07C209/24

CPC分类号： C07C209/16 ,  C07C211/04

摘要： Process for the continuous synthesis of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the catalyst used is a shaped body which comprises a microporous material and at least one organosilicon compound as binder and can be produced by a process comprising the steps (I) preparation of a mixture comprising the microporous material, the binder, a pasting agent and a solvent, (II) mixing and densification of the mixture, (III) shaping of the densified mixture to give a shaped body, (IV) drying of the shaped body and (V) calcination of the dried shaped body.

摘要翻译： 在多相催化剂存在下，通过甲醇和/或二甲醚与氨的反应连续合成甲胺的方法，其中使用的催化剂是成形体，其包含微孔材料和至少一种有机硅化合物作为粘合剂，并且可以是 通过包括步骤（I）制备包含微孔材料，粘合剂，粘贴剂和溶剂的混合物的方法制备的方法制备，（II）混合和混合物的致密化，（III）使致密混合物成形，得到 （IV）成型体的干燥和（V）干燥成型体的煅烧。