Photoconductive elements having a polymeric barrier layer
    2.
    发明授权
    Photoconductive elements having a polymeric barrier layer 失效
    具有聚合物阻挡层的光导元件

    公开(公告)号:US06866977B2

    公开(公告)日:2005-03-15

    申请号:US10243702

    申请日:2002-09-14

    摘要: Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyamide-co-imide having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2. The amount of aromatic tetracarbonylbisimide content in the polymer is selected such that the barrier layer can be coated onto the support as a relatively thick layer, which provides for enhanced performance as a photoconductor when used in an electrophotographic process.

    摘要翻译: 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子机构输送电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中具有作为重复单元共价键合的聚酰胺 - 共 - 酰亚胺,下式的芳族四羰基双酰亚胺基团:其中Ar 1和Ar 2分别表示6至约20的四价或三价芳族基团 碳原子,X是O,C(CF 3)2,S = O或SO 2。 选择聚合物中芳族四羰基二酰亚胺含量的量使得阻挡层可以涂覆在载体上作为相对较厚的层,当用于电子照相方法时,这提供了作为光电导体的增强的性能。

    Photoconductive elements having a polymeric barrier layer
    3.
    发明授权
    Photoconductive elements having a polymeric barrier layer 有权
    具有聚合物阻挡层的光导元件

    公开(公告)号:US06593046B2

    公开(公告)日:2003-07-15

    申请号:US09954907

    申请日:2001-09-18

    IPC分类号: G03G510

    摘要: Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic, or both electronic and ionic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyester-co-imides, polyesterionomer-co-imides, or polyamide-co-imides having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2.

    摘要翻译: 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子或电子和离子机制两者传输电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯型聚异氰酸酯 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,其中Ar 1和Ar 2分别表示四价或三价的芳族四羰基二酰亚胺基团 6至约20个碳原子的芳基,X是O,C(CF 3)2,S = O或SO 2。

    Polymer and photoconductive element having a polymeric barrier layer
    4.
    发明授权
    Polymer and photoconductive element having a polymeric barrier layer 失效
    具有聚合物阻挡层的聚合物和光电导元件

    公开(公告)号:US06451956B2

    公开(公告)日:2002-09-17

    申请号:US09877763

    申请日:2001-06-08

    IPC分类号: C08G7310

    摘要: In a photoconductive element comprising a conductive support, e.g., an electrically conductive film, drum or belt on which a negatively chargeable photoconductive layer is formed, an electrical barrier layer is formed between the support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges but transports electrons under an applied electric field. The barrier layer of the invention transports charge by electronic rather than ionic mechanisms and, therefore, is not substantially affected by humidity changes. The barrier layer comprises a polyester-co-imide, polyesterionomer-co-imide or polyamide-co-imide having covalently bonded as repeating units in the polymer chain, aromatic tetracarboxylbisimide groups of the formula: wherein Ar1 and Ar2 represent, respectively, tetravalent and trivalent aromatic groups of 6 to 20 carbon atoms.

    摘要翻译: 在包含导电性支持体(例如形成有可带电电荷的光电导层的导电膜,鼓或带)的光电导元件中,在支撑体和光电导层之间形成电阻隔层。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 本发明的阻挡层通过电子而不是离子机制传输电荷,因此基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯共聚物 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,下式的芳族四羧基双酰亚胺基团:其中Ar1和Ar2分别表示四价和 6-20个碳原子的三价芳族基团。

    Polymer and photoconductive element having a polymeric barrier layer
    5.
    发明授权
    Polymer and photoconductive element having a polymeric barrier layer 失效
    具有聚合物阻挡层的聚合物和光电导元件

    公开(公告)号:US06294301B1

    公开(公告)日:2001-09-25

    申请号:US09574775

    申请日:2000-05-19

    IPC分类号: G03G510

    摘要: In a photoconductive element comprising a conductive support, e.g., an electrically conductive film, drum or belt on which a negatively chargeable photoconductive layer is formed, an electrical barrier layer is formed between the support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges but transports electrons under an applied electric field. The barrier layer of the invention transports charge by electronic rather than ionic mechanisms and, therefore, is not substantially affected by humidity changes. The barrier layer comprises a polyester-co-imide, polyesterionomer-co-imide or polyamide-co-imide having covalently bonded as repeating units in the polymer chain, aromatic tetracarboxylbisimide groups of the formula: wherein Ar1 and Ar2 represent, respectively, tetravalent and trivalent aromatic groups of 6 to 20 carbon atoms.

    摘要翻译: 在包含导电性支持体(例如形成有可带电电荷的光电导层的导电膜,鼓或带)的光电导元件中,在支撑体和光电导层之间形成电阻隔层。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 本发明的阻挡层通过电子而不是离子机制传输电荷,因此基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯共聚物 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,下式的芳族四羧基双酰亚胺基团:其中Ar1和Ar2分别表示四价和 6-20个碳原子的三价芳族基团。

    Electrophotographic charge generating element containing primer layer
    6.
    发明授权
    Electrophotographic charge generating element containing primer layer 有权
    含有底漆层的电子照相电荷产生元件

    公开(公告)号:US6066425A

    公开(公告)日:2000-05-23

    申请号:US222639

    申请日:1998-12-30

    摘要: Electrophotographic charge generating elements comprise a solid electrolyte layer having improved image discrimination and layer adhesion. The solid electrolyte layer includes a complex of a silsesquioxane and a charge carrier, and is adhered to an underlying photoconductor layer using a primer layer that includes specific addition polymers. This primer layer has a resistivity of at least 10.sup.10 ohms/square and contains substantially no free ACTIVE moieties as defined herein. Such groups, when present in the primer layer, appear to reduce image discrimination.

    摘要翻译: 电子照相电荷产生元件包括具有改进的图像鉴别和层粘合的固体电解质层。 固体电解质层包括倍半硅氧烷和电荷载体的络合物,并且使用包含特定加成聚合物的底涂层粘附到下面的光电导体层。 该底层具有至少1010欧姆/平方的电阻率,并且基本上不含本文定义的游离的活性部分。 当这些基团存在于底漆层中时,似乎减少了图像鉴别。

    Organic charge transporting polymers including charge transport moieties and silane groups, and silsesquioxane compositions prepared therefrom
    7.
    发明授权
    Organic charge transporting polymers including charge transport moieties and silane groups, and silsesquioxane compositions prepared therefrom 失效
    包括电荷传输部分和硅烷基团的有机电荷传输聚合物和由其制备的倍半硅氧烷组合物

    公开(公告)号:US07700248B2

    公开(公告)日:2010-04-20

    申请号:US10615089

    申请日:2003-07-08

    IPC分类号: G03G5/047

    摘要: Disclosed are polymers which include tertiary aryl amine moieties that can function as hole transport agents and which also have reactive silane groups thereon capable of being condensed to a silsesquioxane composition, as well as the silsesquioxane compositions prepared therefrom. The silsesquioxanes can be coated onto substrates to form abrasion-resistant layers having hole transport properties useful in devices that require charge transport properties, such as light-emitting diodes and organic electrophotographic elements such as photoreceptors or photoconductors. Also disclosed are electrophotographic elements which comprise an electrically conducting layer, a charge generating layer overlying the electrically conducting layer, and a charge transport layer overlying the electrically conducting layer. The charge transport layer, which can be an overcoat overlying the charge generating layer, comprises the condensed reaction product of the disclosed polymers.

    摘要翻译: 公开了包括可以用作空穴传输剂的叔芳基胺部分的聚合物,并且其上还具有能够被缩合成倍半硅氧烷组合物的反应性硅烷基团,以及由其制备的倍半硅氧烷组合物。 可以将倍半硅氧烷涂覆到基材上以形成具有空穴传输特性的耐磨层,该层具有可用于需要电荷传输性能的器件,例如发光二极管和有机电子照相元件如感光体或感光体。 还公开了电子照相元件,其包括导电层,覆盖导电层的电荷产生层和覆盖在导电层上的电荷传输层。 可以是覆盖电荷产生层的外涂层的电荷输送层包括所公开的聚合物的缩合反应产物。

    Lubricating layer in photographic elements
    9.
    发明授权
    Lubricating layer in photographic elements 有权
    摄影元素中的润滑层

    公开(公告)号:US06573222B1

    公开(公告)日:2003-06-03

    申请号:US09568835

    申请日:2000-05-11

    IPC分类号: C10M16100

    摘要: The present invention is an imaging element which includes a support, at least one imaging layer superposed on the support and a protective topcoat superposed farthest from the support. The topcoat includes a binder and lubricant droplets. The lubricant droplets are composed of a lubricant and a water soluble polymer containing heterocyclic aromatic nitrogen groups wherein the droplets are surrounded by a particulate stabilizer. The present invention is also directed to the lubricant droplets.

    摘要翻译: 本发明是一种成像元件,其包括支撑体,叠置在支撑体上的至少一个成像层和与支撑体最远重叠的保护面漆。 面漆包括粘合剂和润滑剂液滴。 润滑剂液滴由润滑剂和含有杂环芳族氮基团的水溶性聚合物组成,其中液滴被颗粒稳定剂包围。 本发明还涉及润滑剂液滴。

    Toner image pressure transfer method and toner useful therefor
    10.
    发明授权
    Toner image pressure transfer method and toner useful therefor 失效
    调色剂图像压力转印方法和碳粉有用

    公开(公告)号:US5162189A

    公开(公告)日:1992-11-10

    申请号:US723590

    申请日:1991-07-01

    IPC分类号: B01J13/06 G03G9/087 G03G9/093

    摘要: Pressure-sensitive, heat-fusible, encapsulated toner particles are provided which have very uniform size and physical characteristics. A method for making the particles is provided wherein a latex copolymer functions as a stabilizer controlling particle size of the core composition of the toner particles. The latex copolymer becomes the shell composition thereof. The particles are particularly useful in a process for transferring a toned image comprised of such particles from a photoconductor to a receiver.

    摘要翻译: 提供了具有非常均匀的尺寸和物理特性的压敏的,易熔融的包封的调色剂颗粒。 提供了制备颗粒的方法,其中胶乳共聚物用作控制调色剂颗粒的芯组合物的颗粒尺寸的稳定剂。 胶乳共聚物成为其壳组合物。 该颗粒在用于将由这种颗粒组成的调色图像从光电导体转印到接收器的过程中特别有用。