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公开(公告)号：US20100092829A1
公开(公告)日：2010-04-15
申请号：US12520473
申请日：2007-12-19
申请人： Marie-Laure Fontaine , Fabrice Mauvy , Pascal Lenormand , Jean-Marc Bassat , Florence Ansart , Jean-Claude Grenier
发明人： Marie-Laure Fontaine , Fabrice Mauvy , Pascal Lenormand , Jean-Marc Bassat , Florence Ansart , Jean-Claude Grenier
CPC分类号： H01M4/861 , C01F17/0018 , C01G53/42 , C01G53/44 , C01G53/70 , C01P2002/34 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2004/84 , C01P2006/40 , H01M4/8657 , H01M4/8885 , H01M4/9016 , H01M4/9033 , H01M2008/1293
摘要： A gas electrode includes a plurality of stacked layers (2, 3, 4), wherein the first layer (2) is in contact with a solid substrate (1) while the last layer (4) has a free outer surface to be contacted with a gas, each layer being made of at least one mixed oxide selected from the group including perovskites and Ruddlesden-Popper phases, the micro-structure of the first layer (2) being different from that of the last layer (4), the porosity of the different layers (2, 3, 4) increasing from the first layer (2) towards the last layer (4), and the different layers stacked on each other defining a network of a solid interconnected material between the free outer surface of the last layer (4) and the solid substrate with a total thickness higher than 1 μm. A method for making such an electrode and its use in an electrochemical cell are disclosed.
摘要翻译： 气体电极包括多个堆叠层（2,3,4），其中第一层（2）与固体衬底（1）接触，而最后层（4）具有与第一层（2）接触的自由外表面 气体，每层由至少一种选自包括钙钛矿和Ruddlesden-Popper相的混合氧化物制成，第一层（2）的微结构与最后一层（4）的微结构不同，孔隙率 的不同层（2,3,4）从第一层（2）向最后层（4）增加，并且彼此堆叠的不同层限定了固体互连材料的网络，其中，所述互连材料的自由外表面 最后一层（4）和总厚度大于1μm的固体基质。 公开了制造这种电极的方法及其在电化学电池中的应用。
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2.发明申请Process and Device for Water Electrolysis Comprising a Special Oxide Electrode Material 审中-公开包含特殊氧化物电极材料的水电解工艺和装置公开(公告)号：US20080011604A1
公开(公告)日：2008-01-17
申请号：US11570859
申请日：2005-06-21
CPC分类号： C25B1/04 , C25B11/0452 , H01M4/9025 , Y02E60/366
摘要： The invention relates to a method for water electrolysis consisting in using an electrode containing at least one type of oxide material of general formula A2−x−yA′xA″yM1−zM′zO4+δ, wherein A is a lanthanide and/or alkaline and/or alkaline earth metal cation, A′ is at least one lanthanide and/or alkaline and/or alkaline earth metal cation, A″ is a cation gap, M is a transition metal element, M′ is at least one type of transition metal element, wherein said metal is such that 0
摘要翻译： 本发明涉及一种水电解方法，其包括使用含有至少一种类型的通式为A-2-xy A'x A'的氧化物材料的电极， 其中A是镧系元素和/或碱性和/或碱土金属离子， /或碱土金属阳离子，A'是至少一种镧系元素和/或碱土金属和/或碱土金属阳离子，A“是阳离子间隙，M是过渡金属元素，M'是至少一种过渡类型 金属元素，其中所述金属使得0
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公开(公告)号：US07572532B2
公开(公告)日：2009-08-11
申请号：US10599132
申请日：2005-03-21
CPC分类号： H01M4/9025 , C01G1/00 , C01G3/006 , C01G37/006 , C01G45/1264 , C01G49/0054 , C01G51/40 , C01G51/70 , C01G53/40 , C01G53/70 , C01P2006/40 , H01M4/9016 , H01M2008/1293
摘要： The invention relates to an oxide material of general formula (I) A2−x−yA′XA″yM1−z M′Z04+δ, wherein A and A′ are independently a metal cation of a group formed by lanthanides and/or alkalis and/or alkaline earths, A″ is a cationic gap, i.e. a cation vacancy A and/or A′, M and M′ are independently a metal of a group formed by transition metals such as 0
摘要翻译： 本发明涉及通式（Ⅰ）A2-x-yA'A''yM1-zM'Z04 +δ的氧化物材料，其中A和A'独立地是由镧系元素形成的基团的金属阳离子和/或 碱和/或碱土金属，A“是阳离子间隙，即阳离子空位A和/或A'，M和M'独立地是由过渡金属如0
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