公开(公告)号：US20050227865A1

公开(公告)日：2005-10-13

申请号：US10523226

申请日：2003-08-21

申请人： Mario Nappa ,  Velliyur Rao ,  H. Rosenfield ,  Shekhar Surramoney ,  Munirpallam Subramanian ,  Allen Sievert

发明人： Mario Nappa ,  Velliyur Rao ,  H. Rosenfield ,  Shekhar Surramoney ,  Munirpallam Subramanian ,  Allen Sievert

IPC分类号： C01G37/02 ,  B01J23/00 ,  B01J23/26 ,  B01J23/86 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J37/03 ,  B01J37/26 ,  C07B61/00 ,  C07C17/08 ,  C07C17/10 ,  C07C17/158 ,  C07C17/20 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C17/358 ,  C07C17/37 ,  C07C19/07

CPC分类号： C07C17/37 ,  B01J23/26 ,  B01J23/866 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J37/0236 ,  B01J37/03 ,  C07C17/08 ,  C07C17/10 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/25 ,  C07C17/358 ,  C07C19/10

摘要： A crystalline alpha-chromium oxide where from about 0.05 atom % to about 2 atom % of the chromium atoms in the alpha-chromium oxide lattice are substituted by nickel atoms, and optionally, additional chromium atoms in the alpha-chromium oxide lattice are substituted by trivalent cobalt atoms (provided that the total amount of the nickel atoms and the trivalent cobalt atoms in the alpha-chromium oxide lattice is no more than 6 atom %) is disclosed. Also disclosed is a chromium-containing catalyst composition comprising as a chromium-containing component the crystalline substituted alpha-chromium oxide; and a method for preparing a composition comprising the crystalline substituted alpha-chromium oxide. The method comprises (a) co-precipitating a solid by adding ammonium hydroxide to an aqueous solution of a soluble divalent nickel salt, a soluble trivalent chromium salt, and optionally, a soluble divalent or trivalent cobalt salt, that contains at least three moles of nitrate per mole of chromium in the solution, has a nickel concentration of from about 0.05 mole % to about 2 mole % of the total of nickel, chromium, and cobalt in the solution, and has a combined concentration of nickel and cobalt of no more than 6 mole % of the total of nickel, chromium, and cobalt in the solution; and after at least three moles of ammonium per mole of chromium has been added to the solution; (b) collecting the co-precipitated solid formed in (a); (c) drying the collected solid; and (d) calcining the dried solid. Also disclosed is a chromium-containing catalyst composition comprising a chromium-containing component prepared by treating said crystalline substituted alpha-chromium oxide with a fluorinating agent; and a process for changing the fluorine distribution (i.e., content and/or arrangement) in a hydrocarbon or halogenated hydrocarbon in the presence of a catalyst. The process involves using as the catalyst a composition comprising the crystalline substituted alpha-chromium oxide and/or the treated substituted alpha-chromium oxide.