摘要:
It is an object of the present invention to provide a fused ring compound which can exhibit sufficient charge transport properties and which has excellent solubility in a solvent. The fused ring compound according to the present invention is represented by the following general formula (1), wherein R11 and R12 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an optionally substituted aryl group having 6 to 60 carbon atoms, an optionally substituted heterocyclic group having 4 to 60 carbon atoms, or a cyano group, provided that at least one of R11 and R12 is not a hydrogen atom; R13 and R14 each independently represent a monovalent group, and n and m each independently denote an integer of 0 to 2; and Y11 and Y12 are each independently a divalent group comprising a sulfur atom, an oxygen atom, a nitrogen atom, a selenium atom or a tellurium atom.
摘要翻译:本发明的目的是提供一种能够显示足够的电荷传输性能并且在溶剂中具有优异溶解性的稠环化合物。 根据本发明的稠环化合物由以下通式(1)表示,其中R 11和R 12各自独立地表示氢原子,具有1至20个碳原子的烷基,烷氧基,烷硫基, 烷基氨基,烷氧基羰基,任选取代的碳原子数6〜60的芳基,碳原子数为4〜60的任选取代的杂环基或氰基,条件是R 11和R 12中的至少一个不是氢原子 ; R 13和R 14各自独立地表示一价基团,n和m各自独立地表示0〜2的整数。 Y 11和Y 12各自独立地为包含硫原子,氧原子,氮原子,硒原子或碲原子的二价基团。
摘要:
It is an object of the present invention to provide a fused ring compound which can exhibit sufficient charge transport properties and which has excellent solubility in a solvent. The fused ring compound according to the present invention is represented by the following general formula (1), wherein R11 and R12 each independently represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an optionally substituted aryl group having 6 to 60 carbon atoms, an optionally substituted heterocyclic group having 4 to 60 carbon atoms, or a cyano group, provided that at least one of R11 and R12 is not a hydrogen atom; R13 and R14 each independently represent a monovalent group, and n and m each independently denote an integer of 0 to 2; and Y11 and Y12 are each independently a divalent group comprising a sulfur atom, an oxygen atom, a nitrogen atom, a selenium atom or a tellurium atom.
摘要翻译:本发明的目的是提供一种能够显示足够的电荷传输性能并且在溶剂中具有优异溶解性的稠环化合物。 根据本发明的稠环化合物由以下通式(1)表示,其中R 11和R 12各自独立地表示氢原子,具有1至20个碳原子的烷基,烷氧基,烷硫基, 烷基氨基,烷氧基羰基,任选取代的碳原子数6〜60的芳基,碳原子数为4〜60的任选取代的杂环基或氰基,条件是R 11和R 12中的至少一个不是氢原子 ; R 13和R 14各自独立地表示一价基团,n和m各自独立地表示0〜2的整数。 Y 11和Y 12各自独立地为包含硫原子,氧原子,氮原子,硒原子或碲原子的二价基团。
摘要:
It is an object of the present invention to provide a method for manufacturing a fused ring compound, with which a fused ring compound that has excellent charge transport property and that has excellent solubility in solvents can be obtained efficiently. The method of the present invention for manufacturing a fused ring compound involves reacting a compound expressed by the following General Formula (1a) and a compound expressed by the following General Formula (1b) in the presence of an amine and a metal complex catalyst: (where Ar11 and Ar12 are each independently an atom group constituting an aromatic ring or a heterocyclic ring; X11 and X12 are each independently a hydrogen atom or a halogen atom, and at least one is a halogen atom; and R11 and R12 are each independently a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an aryl group, a heterocyclic group, or a cyano group, provided that at least one of R11 and R12 is not a hydrogen atom).
摘要翻译:本发明的目的是提供一种制备稠环化合物的方法,可以有效地获得具有优异的电荷传输性并且在溶剂中具有优异溶解性的稠环化合物。 本发明的制备稠环化合物的方法包括使由下列通式(1a)表示的化合物与下述通式(1b)表示的化合物在胺和金属络合物催化剂的存在下反应:( 其中Ar 11和Ar 12各自独立地为构成芳香环或杂环的原子团; X 11和X 12各自独立地为氢原子或卤素原子,并且至少一个为卤素原子; R 11和R 12各自独立地为 氢原子,烷基,烷氧基,烷硫基,烷基氨基,烷氧基羰基,芳基,杂环基或氰基,条件是R11和R12中的至少一个不是氢原子 )。
摘要:
It is an object of the present invention to provide a method for manufacturing a fused ring compound, with which a fused ring compound that has excellent charge transport property and that has excellent solubility in solvents can be obtained efficiently. The method of the present invention for manufacturing a fused ring compound involves reacting a compound expressed by the following General Formula (1a) and a compound expressed by the following General Formula (1b) in the presence of an amine and a metal complex catalyst: (where Ar11 and Ar12 are each independently an atom group constituting an aromatic ring or a heterocyclic ring; X11 and X12 are each independently a hydrogen atom or a halogen atom, and at least one is a halogen atom; and R11 and R12 are each independently a hydrogen atom, an all group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group, an aryl group, a heterocyclic group, or a cyano group, provided that at least one of R11 and R12 is not a hydrogen atom).
摘要翻译:本发明的目的是提供一种制备稠环化合物的方法,可以有效地获得具有优异的电荷传输性并且在溶剂中具有优异溶解性的稠环化合物。 本发明的制备稠环化合物的方法包括使由下列通式(1a)表示的化合物与下述通式(1b)表示的化合物在胺和金属络合物催化剂的存在下反应:( 其中Ar 11和Ar 12各自独立地为构成芳香环或杂环的原子团; X 11和X 12各自独立地为氢原子或卤素原子,并且至少一个为卤素原子; R 11和R 12各自独立地为 氢原子,全部基团,烷氧基,烷硫基,烷基氨基,烷氧基羰基,芳基,杂环基或氰基,条件是R 11和R 12中的至少一个不是氢原子 )。
摘要:
An object of the present invention is to provide a polycyclic fused ring polymer which has a structure capable of showing high charge transport properties and also is excellent in solubility into a solvent. The polycyclic fused ring polymer according to the present invention includes: a plurality of one of a first structural unit represented by the following formula (1) and a second structural unit represented by the following formula (2); or the first structural unit and the second structural unit in combination: wherein X1 and X2 represent an oxygen atom, a sulfur atom or a selenium atom, and R1 and R2 represent a halogen atom, an unsaturated alkyl group, an alkyl group, a non-alkyl group containing an alkyl group, an aryl group, or a monovalent heterocyclic group; R3 and R4 represent a monovalent group, and when a plurality of R3 and R4 exist, these may be the same or different; and m, n, s and t are an integer of 0 to 2.
摘要:
An object of the present invention is to provide a fused ring compound which can show sufficient charge transport properties and also has excellent solubility in a solvent. The fused ring compound of the present invention is represented by the following formula (1): wherein R11 and R12 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group having 3 or more carbon atoms in the alkyl moiety thereof, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, or a cyano group, wherein at least one of R11 and R12 is not a hydrogen atom; R13 and R14 each independently represent a monovalent group and m and n are an integer of 0 to 2; Y11, Y12, Y13 and Y14 are a predetermined divalent group containing S, O, N, Se, Te or a double bond; Y11 and Y12 are selected so that a ring containing the groups forms a five-membered ring; and Y13 and Y14 are selected so that a ring containing the groups forms a five or six-membered ring.
摘要:
An object of the present invention is to provide a fused ring compound which can show sufficient charge transport properties and also has excellent solubility in a solvent. The fused ring compound of the present invention is represented by the following formula (1): wherein R11 and R12 each independently represent a hydrogen atom, an alkyl group, an alkoxy group, an alkylthio group, an alkylamino group, an alkoxycarbonyl group having 3 or more carbon atoms in the alkyl moiety thereof, an aryl group which may have a substituent, a monovalent heterocyclic group which may have a substituent, or a cyano group, wherein at least one of R11 and R12 is not a hydrogen atom; R13 and R14 each independently represent a monovalent group and m and n are an integer of 0 to 2; Y11, Y12, Y13 and Y14 are a predetermined divalent group containing S, O, N, Se, Te or a double bond; Y11 and Y12 are selected so that a ring containing the groups forms a five-membered ring; and Y13 and Y14 are selected so that a ring containing the groups forms a five or six-membered ring.
摘要:
An inkjet recording device, wherein air can be retained in an ink supply pipe by using a simple structure without applying substantial changes to the inkjet recording device, a variation in an ink supply pressure is mitigated by the retained air, and ink can be ejected with high stability. An inkjet recording device is provided with an inkjet head for ejecting ink, an ink flow path for supplying the ink, which is supplied from an ink supply source, to a pressure chamber of the inkjet head and having at least a portion thereof constructed from an ink supply pipe, and an air retaining member inserted in the ink supply pipe, with the ink allowed to pass through the air retaining member, and retaining air in at least a portion of a space formed between the air retaining member and the inner surface of the ink supply pipe.
摘要:
Disclosed is an ink jet head exhibiting good assemblability while protecting an electrode portion. An ink jet head (10) comprising a head chip (2) including drive walls (22) and channels (23) juxtaposed alternately with a drive electrode (25) being formed on the drive wall (22), and a nozzle plate (24) wherein a connection electrode is formed on the rear surface of the head chip (2), a wiring board (3) on which an electrode portion (32) is formed is bonded to project from the head chip (2), and ink in the channel (23) is ejected by causing shear deformation of the drive wall (22) is further provided with a holding member (5) disposed at a position covering the electrode portion (32) and holding a portion (31) of the wiring board (3) projecting from the head chip (2), and an electrode portion protection member (4) bonded between the holding member (5) and the electrode portion (32) using adhesive and having a thickness in the range of 0.01-0.5 mm at a part covering the electrode portion (32).
摘要:
A branched compound having a construction with a core portion, at least 3 side chain portions bonded to the core portion, and end portions bonded to each of the side chain portions, wherein the side chain portions arc groups in which a plurality of conjugated units are linked, at least one of the conjugated units being a divalent heterocyclic group, at least one of the end portions is a group represented by formula (1), and the side chain portions and the end portions are conjugated with the core portion. [In the formula, Ar represents a trivalent aromatic hydrocarbon or a trivalent heterocyclic group, and X represents oxygen, sulfur, or a group represented by formula (a).] [In the formula, A represents hydrogen, a halogen or a monovalent group, and at least one A group is an electron-withdrawing group.]