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    CONJUGATED COMPOUND, AND ORGANIC THIN FILM AND ORGANIC THIN FILM ELEMENT EACH COMPRISING SAME
    4.
    发明申请
    CONJUGATED COMPOUND, AND ORGANIC THIN FILM AND ORGANIC THIN FILM ELEMENT EACH COMPRISING SAME 审中-公开
    共轭化合物，有机薄膜和有机薄膜元件

    公开(公告)号：US20120049174A1

    公开(公告)日：2012-03-01

    申请号：US13255373

    申请日：2010-03-10

    Applicant: Yutaka Ie ,  Makoto Okabe ,  Yoshio Aso ,  Masato Ueda

    Inventor： Yutaka Ie ,  Makoto Okabe ,  Yoshio Aso ,  Masato Ueda

    IPC: H01L51/30 ,  C07D409/10 ,  C07D495/04 ,  C07D409/14 ,  C07D333/78

    CPC classification number: H01L51/0068 ,  C07D333/78 ,  C07D495/04 ,  C07D495/14 ,  C09B3/78 ,  C09B23/0058 ,  C09B23/04 ,  C09B57/00 ,  C09B57/001 ,  H01L51/0036 ,  H01L51/0051 ,  H01L51/0074 ,  H01L51/008 ,  H01L51/0541 ,  Y02E10/549

    Abstract: A conjugated compound having a group represented by formula (I) and/or formula (II). [In the formulas, Ar represents an optionally substituted trivalent aromatic hydrocarbon or optionally substituted trivalent heterocyclic group, and A represents hydrogen, a halogen atom or a monovalent group. When multiple A groups are present they may be the same or different, and at least one A represents an electron-withdrawing group. Ar′ represents an optionally substituted C6 or greater divalent aromatic hydrocarbon or optionally substituted C4 or greater divalent heterocyclic group, and R1 and R2 are the same or different and each represents hydrogen, a halogen atom or a monovalent group, while A′ represents hydrogen, a halogen atom or a monovalent group. When multiple A′ groups are present they may be the same or different, and at least one A′ represents an electron-withdrawing group.]

    Abstract translation: 具有由式（I）和/或式（II）表示的基团的共轭化合物。 [式中，Ar表示任意取代的3价芳香族烃或任意取代的3价杂环基，A表示氢原子，卤原子或1价基团。 当存在多个A基团时，它们可以相同或不同，并且至少一个A表示吸电子基团。 Ar'表示任选取代的C 6以上的二价芳香族烃或任选取代的C 4以上的2价杂环基，R 1和R 2相同或不同，分别表示氢原子，卤素原子或一价基团，A'表示氢原子， 卤素原子或一价基团。 当存在多个A'基团时，它们可以相同或不同，并且至少一个A'表示吸电子基团。

    Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same
    5.
    发明授权
    Condensation compound between fluorinated cyclopentane ring and aromatic ring, and process for producing the same 失效
    氟化环戊烷环和芳环之间的缩合化合物及其制备方法

    公开(公告)号：US08008336B2

    公开(公告)日：2011-08-30

    申请号：US11885913

    申请日：2006-03-02

    Applicant: Yutaka Ie ,  Yoshio Aso

    Inventor： Yutaka Ie ,  Yoshio Aso

    IPC: A61K31/409 ,  C07D495/22

    CPC classification number: C07D495/20 ,  C07D333/78 ,  H01L51/0036

    Abstract: A condensation compound of a fluorinated cyclopentane ring and an aromatic ring, which is useful, for example, for electronic materials, and a process for producing the same are provided. For instance, according to Scheme 1 below, a compound (68) containing a condensed structure formed of a hexafluorocyclopentane ring and an aromatic ring is synthesized. The aromatic ring is not limited to a thiophene ring but can be any ring and any substituent can be used. Thus a compound containing a condensed ring structure formed of a hexafluorocyclopentane ring and an aromatic ring, particularly, for instance, a thiophene ring, which was impossible to produce conventionally, can be produced easily with high yield. The compound of the present invention is particularly suitable to be applied to, for example, electronic materials or semiconductors. When it is polymerized and thereby the π-electronic conjugation is extended, it also is expected to be applied to, for example, n-type organic semiconductors and molecular wires that are indispensable for developing molecular electronics elements.

    Abstract translation: 提供氟化环戊烷环和芳环的缩合化合物，其可用于例如电子材料，以及其制备方法。 例如，根据下述方案1，合成含有由六氟环戊烷环和芳香环形成的稠合结构的化合物（68）。 芳环不限于噻吩环，而是可以是任何环，并且可以使用任何取代基。 因此，可以容易地以高产率制备含有由六氟环戊烷环和芳环形成的稠环结构的化合物，特别是例如噻吩环，这是不可能制备的。 本发明的化合物特别适用于例如电子材料或半导体。 当其被聚合并由此延长了电子共轭时，也可以应用于例如用于开发分子电子元件不可或缺的n型有机半导体和分子线。

    CONJUGATED COMPOUND, NITROGENATED CONDENSED-RING COMPOUND, NITROGENATED CONDENSED-RING POLYMER, ORGANIC THIN FILM, AND ORGANIC THIN FILM ELEMENT
    7.
    发明申请
    CONJUGATED COMPOUND, NITROGENATED CONDENSED-RING COMPOUND, NITROGENATED CONDENSED-RING POLYMER, ORGANIC THIN FILM, AND ORGANIC THIN FILM ELEMENT 失效
    连结化合物，氮化聚合环化合物，氮化聚合物聚合物，有机薄膜和有机薄膜元件

    公开(公告)号：US20100301314A1

    公开(公告)日：2010-12-02

    申请号：US12745481

    申请日：2008-11-27

    Applicant: Yoshio Aso ,  Yutaka Ie ,  Makoto Okabe ,  Masashi Nitani ,  Masato Ueda

    Inventor： Yoshio Aso ,  Yutaka Ie ,  Makoto Okabe ,  Masashi Nitani ,  Masato Ueda

    IPC: H01L51/30 ,  C07D513/04 ,  C07D513/20 ,  C07D411/14

    CPC classification number: H01L51/0069 ,  C07D277/60 ,  C07D333/22 ,  C07D333/78 ,  C07D409/14 ,  C07D417/14 ,  C09B3/78 ,  C09B57/00 ,  C09B57/001 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

    Abstract: According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar′ represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, R1 and R2 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar″ represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms.According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

    Abstract translation: 根据第一发明组，提供具有两个以上由下式（I）或下式（II）表示的基团的共轭化合物：其中Ar和Ar'中的一个表示C6以上的二价芳香族烃基， 其它表示C4以上的二价杂环基，其中各基团可以具有取代基，条件是基团整体上不含氟原子，R 1和R 2各自独立地表示氢原子，卤素原子或一价基团 ，Ar“表示三价芳香族烃或三价杂环基; 当共轭化合物具有两个以上由式（I）表示的基团时，不包括这些基团的部分不含氟原子。 根据本发明的第二组，提供由下式（α-I）表示的含氮稠环化合物：在式（α-I）中，R 21和R 22各自独立地表示氢原子，卤素 原子或任选取代的一价基团，Z 21和Z 22各自独立地表示由下式（α-i） - （α-ix）表示的基团中的任一个。 其中R 23，R 24，R 25和R 26各自独立地表示氢原子，卤素原子或一价基团，R 23和R 24可以键合在一起形成环，式（α）表示的基团的左侧和右侧 -viii）可以互换。

    Agglomerate of whiskers or short fibers
    8.
    发明授权
    Agglomerate of whiskers or short fibers 失效
    织物或短纤维

    公开(公告)号：US5185204A

    公开(公告)日：1993-02-09

    申请号：US539626

    申请日：1990-06-18

    Applicant: Tadao Shimizu ,  Yoshio Aso ,  Hidefumi Konnai

    Inventor： Tadao Shimizu ,  Yoshio Aso ,  Hidefumi Konnai

    IPC: C04B14/38 ,  C04B18/02 ,  C08K7/02 ,  C30B29/62

    CPC classification number: C08K7/02 ,  C04B18/02 ,  Y10S428/903 ,  Y10T428/29 ,  Y10T428/2982

    Abstract: Whiskers having a diameter of 0.1-10 .mu.m and a length of 5-200 .mu.m are pelletized and granulated into agglomerates which have a size of 0.1-10 mm and a bulk density of 0.2-1.0 kg/liter.To pelletize, powders of whiskers are moistened with water while mixing to form primary aggregates. Then, the powders and the primary aggregates are subjected to a rolling movement to cause the primary aggregates to grow into secondary aggregates having desired size distribution. Finally, the secondary aggregates are dried to obtain pelletized or granulated agglomerates of whiskers.Handling of whiskers is facilitated because the agglomerates are less bulky and less likely to fly up in the air. When blended into molding materials for fiber reinforcement, however, the agglomerates are readily disintegrated back into separated individual fibers to provide homogeneous dispersion.

    Conjugated compound, nitrogenated condensed-ring compound, nitrogenated condensed-ring polymer, organic thin film, and organic thin film element
    10.
    发明授权
    Conjugated compound, nitrogenated condensed-ring compound, nitrogenated condensed-ring polymer, organic thin film, and organic thin film element 失效
    共轭化合物，氮化稠环化合物，氮化缩合环聚合物，有机薄膜和有机薄膜元件

    公开(公告)号：US08378338B2

    公开(公告)日：2013-02-19

    申请号：US12745481

    申请日：2008-11-27

    Applicant: Yoshio Aso ,  Yutaka Ie ,  Makoto Okabe ,  Masashi Nitani ,  Masato Ueda

    Inventor： Yoshio Aso ,  Yutaka Ie ,  Makoto Okabe ,  Masashi Nitani ,  Masato Ueda

    IPC: H01L29/08

    CPC classification number: H01L51/0069 ,  C07D277/60 ,  C07D333/22 ,  C07D333/78 ,  C07D409/14 ,  C07D417/14 ,  C09B3/78 ,  C09B57/00 ,  C09B57/001 ,  H01L51/0036 ,  H01L51/0558 ,  Y02E10/549

    Abstract: According to the first invention group there are provided conjugated compounds having two or more groups represented by the following formula (I) or the following formula (II): wherein one of Ar and Ar′ represents a C6 or greater divalent aromatic hydrocarbon group and the other represents a C4 or greater divalent heterocyclic group, wherein the groups each may have a substituent, with the proviso that the groups as a whole contain no fluorine atoms, R1 and R2 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and Ar″ represents a trivalent aromatic hydrocarbon or trivalent heterocyclic group; when the conjugated compound has two or more groups represented by formula (I), the portion excluding these groups contain no fluorine atoms. According to the second group of the present invention there are provided nitrogen-containing fused-ring compounds represented by the following formula (α-I): in formula (α-I), R21 and R22 each independently represent a hydrogen atom, a halogen atom or an optionally substituted monovalent group, and Z21 and Z22 each independently represent any one of the groups represented by the following formulas (α-i)-(α-ix); wherein R23, R24, R25 and R26 each independently represent a hydrogen atom, a halogen atom or a monovalent group, and R23 and R24 may bond together to form a ring, the left side and the right side of the group represented by formula (α-viii) may be interchanged.

    Abstract translation: 根据第一发明组，提供具有两个以上由下式（I）或下式（II）表示的基团的共轭化合物：其中Ar和Ar'中的一个表示C6以上的二价芳香族烃基， 其它表示C4以上的二价杂环基，其中各基团可以具有取代基，条件是基团整体上不含氟原子，R 1和R 2各自独立地表示氢原子，卤素原子或一价基团 ，Ar“表示三价芳香族烃或三价杂环基; 当共轭化合物具有两个以上由式（I）表示的基团时，不包括这些基团的部分不含氟原子。 根据本发明的第二组，提供由下式（α-I）表示的含氮稠环化合物：在式（α-I）中，R 21和R 22各自独立地表示氢原子，卤素 原子或任选取代的一价基团，Z 21和Z 22各自独立地表示由下式（α-i） - （α-ix）表示的基团中的任一个。 其中R 23，R 24，R 25和R 26各自独立地表示氢原子，卤素原子或一价基团，R 23和R 24可以键合在一起形成环，式（α）表示的基团的左侧和右侧 -viii）可以互换。

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