-
1.发明授权Method for preparing aqueous dispersion of developer and pressure-sensitive recording paper 失效制备显影剂和压敏记录纸的水性分散体的方法
公开(公告)号：US5204190A
公开(公告)日：1993-04-20
申请号：US905834
申请日：1992-06-29
IPC分类号： B41M5/155
CPC分类号： B41M5/155 , Y10S428/913 , Y10T428/26 , Y10T428/31536 , Y10T428/31967 , Y10T428/31996
摘要： Herein disclosed are a method for preparing an aqueous developer dispersion which comprises the steps of dissolving, in an organic solvent, a developer which comprises a nuclear-substituted salicylic acid salt represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group having not more than 15 carbon atoms, a cycloalkyl group, a phenyl group, a nuclear-substituted phenyl group, an aralkyl group or a nculear-substituted aralkyl group, or two adjacent groups selected from R.sub.1 to R.sub.4 may be bonded together to form a ring; n is an integer of not less than 1; and M represents magnesium, calcium, zinc, aluminum, iron, cobalt, nickel or a basic ion thereof; emulsifying and dispersing the resulting solution in an aqueous solution of an acrylamide copolymer having a degree of polymerization of not less than 100 obtained by copolymerizing 96 to 70 mole % of acrylamide with 4 to 30 mole % of an alkyl or alkoxyalkyl, having not more than 4 carbon atoms, ester of acrylic acid, methacrylic acid, itaconic acid or maleic acid; then heating the emulsified dispersion to remove the organic solvent by distillation; and optionally finely wet-pulverizing the resulting aqueous dispersion to an extent that reduction in the average particle size of the developer dispersed in the dispersion does not exceed 10%; as well as pressure-sensitive recording paper obtained using the aqueous developer dispersion. The recording paper is substantially improved in the developing density, developing velocity and printability.
摘要翻译： 本文公开了一种制备水性显影剂分散体的方法，其包括以下步骤：在有机溶剂中溶解包含由以下通式（I）表示的核取代的水杨酸盐的显影剂： 其中R1，R2，R3和R4可以相同或不同，表示氢原子，卤素原子，碳原子数不超过15个的烷基，环烷基，苯基，核取代的苯基 ，芳烷基或仲胺取代的芳烷基或选自R 1至R 4的两个相邻基团可以结合在一起形成环; n为不小于1的整数; M表示镁，钙，锌，铝，铁，钴，镍或其碱性离子; 将得到的溶液乳化分散在丙烯酰胺共聚物的水溶液中，聚丙烯酰胺共聚物的水溶液中聚合度不低于100，通过共聚96〜70摩尔％的丙烯酰胺与4〜30摩尔％的烷基或烷氧基烷基不同 4个碳原子，丙烯酸，甲基丙烯酸，衣康酸或马来酸的酯; 然后加热乳化分散液通过蒸馏除去有机溶剂; 并且任选地将得到的水分散体精细地湿粉碎至分散在分散体中的显影剂的平均粒径的降低不超过10％的程度; 以及使用含水显影剂分散体获得的压敏记录纸。 记录纸在显影密度，显影速度和可印刷性方面显着提高。
-
2.发明授权
公开(公告)号：US5164001A
公开(公告)日：1992-11-17
申请号：US616788
申请日：1990-11-21
CPC分类号： B41M5/155
摘要： Herein disclosed are a method for preparing an aqueous developer dispersion which comprises the steps of dissolving, in an organic solvent, a developer which comprises a nuclear-substituted salicylic acid salt represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group having not more than 15 carbon atoms, a cycloalkyl group, a phenyl group, a nuclear-substituted phenyl group, an aralkyl group or a nuclear-substituted aralkyl group, or two adjacent groups selected from R.sub.1 to R.sub.4 may be bonded together to form a ring; n is an integer of not less than 1; and M represents magnesium, calcium, zinc, aluminum, iron, cobalt, nickel or a basic ion thereof; emulsifying and dispersing the resulting solution in an aqueous solution of an acrylamide copolymer having a degree of polymerization of not less than 100 obtained by copolymerizing 96 to 70 mol % of acrylamide with 4 to 30 mol % of an alkyl or alkoxyalkyl, having not more than 4 carbon atoms, ester of acrylic acid, methacrylic acid, itaconic acid or maleic acid; then heating the emulsified dispersion to remove the organic solvent by distillation; and optionally finely wet-pulverizing the resulting aqueous dispersion to an extent that reduction in the average particle size of the developer dispersed in the dispersion does not exceed 10%. The recording paper is substantially improved in the developing density, developing velocity and printability.
-
3.发明授权Color developer composition, process for preparing aqueous dispersion thereof and pressure sensitive manifold sheet using thereof 失效彩色显影剂组合物，其水分散体的制备方法和使用其的压力敏感性歧管片
公开(公告)号：US5250108A
公开(公告)日：1993-10-05
申请号：US679690
申请日：1991-04-01
CPC分类号： B41M5/155
摘要： The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.
摘要翻译： 本发明提供了一种彩色显影剂组合物，其特征在于该组合物含有着色显影剂，其包含以下述式（1）表示的核取代的水杨酸盐作为其主要成分，以及至少一种选自以下的酰胺化合物： 的由下式给出的式（2）和式（3）表示的化合物。 式（1）
式（2）其中R 1至R 10如说明书中所定义的式（3）。 -
4.发明授权
公开(公告)号：US5328884A
公开(公告)日：1994-07-12
申请号：US27987
申请日：1993-03-08
IPC分类号： B41M5/155
CPC分类号： B41M5/155
摘要： The present invention provides a color developer composition characterized in that the composition contains a color developer comprising as its main component a nucleus-substituted salicylic acid salt represented by the formula (1) given below, and at least one amide compound selected from the group consisting of the compounds of represented by the formula (2) and formula (3) given below. ##STR1## wherein R.sub.1 to R.sub.10 are as defined in the specification.
摘要翻译： 本发明提供了一种彩色显影剂组合物，其特征在于该组合物含有着色显影剂，其包含以下述式（1）表示的核取代的水杨酸盐作为其主要成分，以及至少一种选自以下的酰胺化合物： 的由下式给出的式（2）和式（3）表示的化合物。 式（1）
式（2）其中R 1至R 10如说明书中所定义的式（3）。 -
5.发明授权
公开(公告)号：US5118443A
公开(公告)日：1992-06-02
申请号：US644678
申请日：1991-01-22
IPC分类号： B41M5/155
CPC分类号： B41M5/155
摘要： A developer comprising at least one polyvalent metal salt of a nuclear substituted salicylic acid of the following general formula is provided. ##STR1## In the formula, R.sub.1 represents an alkyl group having from 1 to 12 carbon atoms, R.sub.2 represents a hydrogen atom or an alkyl group having from 1 to 12 carbon atoms, R.sub.3 represents a hydrogen atom or a methyl group provided that at least one of R.sub.1 and R.sub.2 is a secondary butyl group, a secondary hexyl group, an isohexyl group, a secondary octyl group, an isononyl group, a secondary decyl group, a secondary dodecyl group or an isododecyl group and the total number of the carbon atoms in R.sub.1, R.sub.2 and R.sub.3 is from 9 to 18, M is a polyvalent metal atom, and m is a valence of M. An aqueous dispersion containing the developer and a method for preparing the developer are also described.
-
6.发明授权
公开(公告)号：US4950330A
公开(公告)日：1990-08-21
申请号：US405063
申请日：1989-09-07
IPC分类号： B41M5/155
CPC分类号： B41M5/155
摘要： An aqueous dispersion of a developer for pressure-sensitive recording sheet, having superior handling performance and storage stability in a high concentration and a process for producing the dispersion are provided, which developer is expressed by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and represent H, halogen, alkyl of 1 to 9 carbon atoms, alkylene, cycloalkyl, cycloalkylene, phenyl, nucleus-substituted phenyl, aralkyl or nucleus-aralkyl; adjacent two of R.sub.1 to R.sub.4 may form a ring; n is an integer of one or more; and M is Mg, Ca, Zn, Al, Fe, Co, Ni or a basic ion of the foregoing, and which developer has a softening point of 30.degree. C. or higher and is dispersed in water, containing a dispersing agent, the size of particles of the developer being 0.3 to 5.mu. in terms of average particle diameter, and the proportion of right spherical particles in the total particles being 50% or more; and which process comprises emulsifying-dispersing the developer in water containing a dispersing agent at a temperature higher by at least 30.degree. C. than the softening point of the developer, follower by cooling, or dissolving the developer in an organic solvent, emulsifying-dispersing the solution in water containing a dispersing agent and distilling off the solvent from the dispersion on heating, or using a polyvinyl alcohol having a polymerization degree of 500 or more and a saponification degree of 70% or more.
-
公开(公告)号：US4688060A
公开(公告)日：1987-08-18
申请号：US826016
申请日：1986-02-04
申请人： Masato Tanaka , Shinsuke Irii , Tomoharu Shiozaki
发明人： Masato Tanaka , Shinsuke Irii , Tomoharu Shiozaki
摘要： Disclosed is a pressure sensitive manifold paper prepared by coating a substrate with a coating composition containing microcapsules of polyurethane resin or polyurea resin wall film and drying the resulting coating, the pressure sensitive manifold paper being characterized in that a latex of copolymer of comonomers comprising about 10 to about 50% by weight of styrene, about 15 to about 55% by weight of butadiene, about 10 to about 40% by weight of methyl methacrylate and up to about 15% by weight of acrylonitrile is incorporated in the coating composition in an amount of about 5 to about 30% by weight (calculated as solids) based on the microcapsules (calculated as solids).The pressure sensitive manifold paper has an adequate balance between the color forming ability and susceptibility to color smudges due to contact or friction.
摘要翻译： 公开了一种通过用包含聚氨酯树脂或聚脲树脂壁膜的微胶囊的涂料组合物涂覆基材并干燥所得涂层而制备的压敏集成纸，其特征在于包含约10个共聚单体的共聚单体的胶乳 至约50重量％的苯乙烯，约15至约55重量％的丁二烯，约10至约40重量％的甲基丙烯酸甲酯和至多约15重量％的丙烯腈，其量以 约5至约30重量％（以固体计算），基于微胶囊（以固体计算）。 压敏集成纸在成色能力和由于接触或摩擦引起的颜色污迹的易感性之间具有足够的平衡。
-
公开(公告)号：US4486762A
公开(公告)日：1984-12-04
申请号：US439626
申请日：1982-11-04
申请人： Shigeo Okamoto , Tomoharu Shiozaki
发明人： Shigeo Okamoto , Tomoharu Shiozaki
CPC分类号： B41M5/1243 , Y10T428/253
摘要： A self-contained type pressure sensitive record sheet prepared by coating a substrate with a mixture of a color acceptor and microcapsules containing a color former in the form of a single layer and drying the resulting coating, the mixture containing 40 to 200 parts by weight, per 100 parts by weight of the microcapsules calculated as solids, of a pulp powder having a weight average fiber length of 20 to 80.mu., has well-balanced improved properties in respect of color forming ability, prevention of color smudging and printability.
摘要翻译： 一种独立型压敏记录片，其通过用单色层形式的含有着色剂的彩色受体和微胶囊的混合物涂覆基底并干燥所得涂层而制备，所述混合物含有40至200重量份， 相对于100重量份作为固体计算的微胶囊，重均纤维长度为20〜80μm的纸浆粉末在成色能力，防止着色和印刷性方面具有良好的均衡改善的性能。
-
公开(公告)号：US4435340A
公开(公告)日：1984-03-06
申请号：US340972
申请日：1982-01-20
申请人： Tetsuro Horiike , Takio Kuroda , Tomoharu Shiozaki
发明人： Tetsuro Horiike , Takio Kuroda , Tomoharu Shiozaki
CPC分类号： B41M5/165 , Y10S428/914 , Y10T428/2985
摘要： A process for preparing microcapsules for pressure sensitive manifold paper characterized by emulsifying in a hydrophilic liquid a hydrophobic liquid containing an aromatic isocyanate represented by the formula ##STR1## wherein n is an integer of 1 to 10, an aliphatic isocyanate and an electron donating organic chromogenic material, and forming a polymer at the interface to cover hydrophobic liquid droplets with the polymer.
摘要翻译： 一种用于制备用于压敏歧管纸的微胶囊的方法，其特征在于在亲水性液体中乳化含有由式“IMAGE”表示的芳族异氰酸酯的疏水性液体，其中n为1至10的整数，脂族异氰酸酯和给电子有机显色剂 材料，并在界面处形成聚合物以用聚合物覆盖疏水液滴。
-
公开(公告)号：US4403051A
公开(公告)日：1983-09-06
申请号：US157537
申请日：1980-06-09
CPC分类号： B41M5/1243
摘要： This invention concerns with an improved microcapsule dispersion prepared by adding the following components to a known microcapsule dispersion containing PVA; a pulp having a specific weighted average fiber length, another type of pulp, carboxymethyl cellulose and/or a specified periodic acid type compound, and is characterized by overcoming the drawbacks of known microcapsule dispersions attended by use of PVA.
摘要翻译： 本发明涉及一种改进的微胶囊分散体，其通过将以下组分加入到含有PVA的已知微胶囊分散体中制备; 具有特定加权平均纤维长度的纸浆，另一种纸浆，羧甲基纤维素和/或特定的高碘酸型化合物，其特征在于克服使用PVA所存在的已知微胶囊分散体的缺点。
-
-
-
-
-
-
-
-
-
搜索结果
16 条记录 (耗时 0.025 秒)
