Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure

    公开(公告)号:US07425285B2

    公开(公告)日:2008-09-16

    申请号:US11797114

    申请日:2007-05-01

    IPC分类号: H01B1/04

    摘要: There are provided an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an intermetallic compound containing at least tin is dispersed in a silicon phase and an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an at least one intermetallic compound containing at least one element selected from the group consisting of aluminum, zinc, indium, antimony, bismuth and lead is dispersed in a silicon phase. Thereby, an electrode material for a lithium secondary battery, an electrode structure comprising the electrode material and a secondary battery comprising the electrode structure are provided in which a drop in capacity due to repeated charging/discharging is small, and the charge/discharge cycle life is improved.

    Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure
    4.
    发明申请
    Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure 失效
    用于锂二次电池的电极材料,包括电极材料的电极结构和包括电极结构的二次电池

    公开(公告)号:US20070200101A1

    公开(公告)日:2007-08-30

    申请号:US11797114

    申请日:2007-05-01

    IPC分类号: H01M4/60

    摘要: There are provided an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an intermetallic compound containing at least tin is dispersed in a silicon phase and an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an at least one intermetallic compound containing at least one element selected from the group consisting of aluminum, zinc, indium, antimony, bismuth and lead is dispersed in a silicon phase. Thereby, an electrode material for a lithium secondary battery, an electrode structure comprising the electrode material and a secondary battery comprising the electrode structure are provided in which a drop in capacity due to repeated charging/discharging is small, and the charge/discharge cycle life is improved.

    摘要翻译: 提供了一种用于锂二次电池的电极材料,其包括以硅为主要成分并且平均粒径为0.02μm至5μm的合金颗粒,其中合金的微晶尺寸不小于2nm,但是 不超过500nm,并且至少含有锡的金属间化合物分散在硅相中,并且包含包含以硅为主要成分并且平均粒径为0.02μm至5μm的合金颗粒的锂二次电池用电极材料 其中所述合金的微晶尺寸不小于2nm但不大于500nm,以及至少一种含有至少一种选自铝,锌,铟,锑,铋和铋的元素的金属间化合物 铅分散在硅相中。 由此,提供锂二次电池用电极材料,包含该电极材料的电极结构体和包含该电极结构体的二次电池,由于反复充放电而导致的容量下降小,充放电循环寿命 改进了

    ELECTRODE MATERIAL FOR LITHIUM SECONDARY BATTERY AND ELECTRODE STRUCTURE HAVING THE ELECTRODE MATERIAL
    5.
    发明申请
    ELECTRODE MATERIAL FOR LITHIUM SECONDARY BATTERY AND ELECTRODE STRUCTURE HAVING THE ELECTRODE MATERIAL 审中-公开
    用于锂二次电池的电极材料和具有电极材料的电极结构

    公开(公告)号:US20090061322A1

    公开(公告)日:2009-03-05

    申请号:US12260056

    申请日:2008-10-28

    IPC分类号: H01M4/58

    摘要: The electrode material for a lithium secondary battery according to the present invention includes particles of a solid state alloy having silicon as a main component, wherein the particles of the solid state alloy have a microcrystal or amorphous material including an element other than silicon, dispersed in microcrystalline silicon or amorphized silicon. The solid state alloy preferably contains a pure metal or a solid solution. The composition of the alloy preferably has an element composition in which the alloy is completely mixed in a melted liquid state, whereby the alloy has a single phase in a melted liquid state without presence of two or more phases. The element composition can be determined by the kind of elements constituting the alloy and an atomic ratio of the elements.

    摘要翻译: 根据本发明的用于锂二次电池的电极材料包括以硅为主要成分的固态合金颗粒,其中固态合金的颗粒具有微晶或非晶材料,其包含除了硅之外的元素,分散在 微晶硅或非晶硅。 固态合金优选含有纯金属或固溶体。 合金的组成优选具有其中合金在熔融液态完全混合的元素组成,由此合金具有熔融液态中的单相,而不存在两相或更多相。 元素组成可以通过构成合金的元素的种类和元素的原子比来确定。

    Electrode material for lithium secondary battery and electrode structure having the electrode material
    7.
    发明申请
    Electrode material for lithium secondary battery and electrode structure having the electrode material 审中-公开
    用于锂二次电池的电极材料和具有电极材料的电极结构

    公开(公告)号:US20060040182A1

    公开(公告)日:2006-02-23

    申请号:US10541222

    申请日:2004-03-24

    IPC分类号: H01M4/58 H01M4/38

    摘要: The electrode material for a lithium secondary battery according to the present invention includes particles of a solid state alloy having silicon as a main component, wherein the particles of the solid state alloy have a microcrystal or amorphous material including an element other than silicon, dispersed in microcrystalline silicon or amorphized silicon. The solid state alloy preferably contains a pure metal or a solid solution. The composition of the alloy preferably has an element composition in which the alloy is completely mixed in a melted liquid state, whereby the alloy has a single phase in a melted liquid state without presence of two or more phases. The element composition can be determined by the kind of elements constituting the alloy and an atomic ratio of the elements.

    摘要翻译: 根据本发明的用于锂二次电池的电极材料包括以硅为主要成分的固态合金颗粒,其中固态合金的颗粒具有微晶或非晶材料,其包含除了硅之外的元素,分散在 微晶硅或非晶硅。 固态合金优选含有纯金属或固溶体。 合金的组成优选具有其中合金在熔融液态完全混合的元素组成,由此合金具有熔融液态中的单相,而不存在两相或更多相。 元素组成可以通过构成合金的元素的种类和元素的原子比来确定。

    Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure
    9.
    发明授权
    Electrode material for lithium secondary battery, electrode structure comprising the electrode material and secondary battery comprising the electrode structure 失效
    用于锂二次电池的电极材料,包括电极材料的电极结构和包括电极结构的二次电池

    公开(公告)号:US07378041B2

    公开(公告)日:2008-05-27

    申请号:US10809483

    申请日:2004-03-26

    IPC分类号: H01B1/04

    摘要: There are provided an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an intermetallic compound containing at least tin is dispersed in a silicon phase and an electrode material for a lithium secondary battery which comprises alloy particles comprising silicon as a major component and having an average particle diameter of 0.02 μm to 5 μm, wherein the size of a crystallite of the alloy is not less than 2 nm but no more than 500 nm and an at least one intermetallic compound containing at least one element selected from the group consisting of aluminum, zinc, indium, antimony, bismuth and lead is dispersed in a silicon phase. Thereby, an electrode material for a lithium secondary battery, an electrode structure comprising the electrode material and a secondary battery comprising the electrode structure are provided in which a drop in capacity due to repeated charging/discharging is small, and the charge/discharge cycle life is improved.

    摘要翻译: 提供了一种用于锂二次电池的电极材料,其包括以硅为主要成分并且平均粒径为0.02μm至5μm的合金颗粒,其中合金的微晶尺寸不小于2nm,但是 不超过500nm,并且至少含有锡的金属间化合物分散在硅相中,并且包含包含以硅为主要成分并且平均粒径为0.02μm至5μm的合金颗粒的锂二次电池用电极材料 其中所述合金的微晶尺寸不小于2nm但不大于500nm,以及至少一种含有至少一种选自铝,锌,铟,锑,铋和铋的元素的金属间化合物 铅分散在硅相中。 由此,提供锂二次电池用电极材料,包含该电极材料的电极结构体和包含该电极结构体的二次电池,由于反复充放电而导致的容量下降小,充放电循环寿命 改进了