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公开(公告)号:US4265662A
公开(公告)日:1981-05-05
申请号:US971835
申请日:1978-12-19
申请人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
发明人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
CPC分类号: C22C29/00
摘要: This invention relates to a hard alloy comprising a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten as a predominant component, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt, nickel and chromium, in which a hard phase consisting of a compound of M.sub.2 C type having a crystal structure of hexagonal type is evenly dispersed.
摘要翻译: 本发明涉及一种硬质合金,其包含由至少一种具有简单的六方晶系MC型(M:金属; C:碳)的晶体结构的化合物组成的硬质合金,所述晶体结构选自由混合碳化物,碳氮化物和钼的羧基氮化物组成的组, 钨作为主要组分,以及由选自铁,钴,镍和铬中的至少一种元素组成的粘结相,其中由具有六方晶系结构的M2C型化合物组成的硬相为 均匀分散。
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公开(公告)号:US4216034A
公开(公告)日:1980-08-05
申请号:US927903
申请日:1978-07-25
申请人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
发明人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
CPC分类号: B82Y30/00 , B22F9/20 , B22F9/24 , C01B31/34 , C22C1/055 , C22C29/06 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/40 , C01P2006/80
摘要: This invention relates to a process for the production of a solid solution of compounds consisting of, in combination, at least 10 mol %, based on all metallic components, of molybdenum, at least one metallic element selected from the Group IVa, Va and VIa elements of the Periodic Table and at least one of non-metallic elements, which comprises mixing the metallic elements in the form of compounds or solutions thereof, adding carbon, optionally with at least one of non-metallic elements to the mixture, subjecting the resulting mixture to a reducing reaction with carbon and then subjecting to a solid solution-forming treatment in a reducing, carburizing or nitriding atmosphere.
摘要翻译: 本发明涉及一种制备化合物固体溶液的方法,所述化合物由至少一种选自Ⅳa族,Ⅴa和Ⅵa族的金属元素组合在一起,所述化合物基于所有金属组分,至少10mol% 周期表的元素和至少一种非金属元素,其包括以化合物或其溶液的形式混合金属元素,任选地与至少一种非金属元素一起加入到混合物中,使所得到的 混合物与碳的还原反应,然后在还原,渗碳或氮化气氛中进行固溶成型处理。
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3.
公开(公告)号:US4216009A
公开(公告)日:1980-08-05
申请号:US927904
申请日:1978-07-25
申请人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
发明人: Masaya Miyake , Minol Nakano , Takaharu Yamamoto , Akio Hara
CPC分类号: B82Y30/00 , B22F9/20 , B22F9/24 , C01B31/34 , C22C1/045 , C22C1/055 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/40 , C01P2006/80
摘要: The present invention relates to a process for the production of an alloy powder (Mo, W) for powder metallurgy, which comprises chemically or mechanically mixing molybdenum and tungsten in the form of compounds and reducing the mixed powder with hydrogen, and a process for the production of a hard solid solution (Mo, W)C from the alloy powder (Mo, W), which comprises carburizing the alloy powder (Mo, W).
摘要翻译: 本发明涉及一种用于生产粉末冶金的合金粉末(Mo,W)的方法,其包括化学或机械混合化合物形式的钼和钨并用氢还原混合粉末的方法 从合金粉末(Mo,W)生产硬质固溶体(Mo,W)C,其包括渗碳合金粉末(Mo,W)。
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4.
公开(公告)号:US4384884A
公开(公告)日:1983-05-24
申请号:US222902
申请日:1981-01-05
申请人: Masaya Miyake , Minol Nakano , Mitsuo Kodama , Akio Hara
发明人: Masaya Miyake , Minol Nakano , Mitsuo Kodama , Akio Hara
IPC分类号: C01B21/082 , C01B32/949 , C22C1/05 , C22C1/04
CPC分类号: C01B21/0828 , C01B31/34 , C22C1/055 , C01P2002/50 , C01P2004/03 , C01P2004/10 , C01P2006/80
摘要: The present invention relates to a process for the production of a solid solution constructed of at least one hard phase having a crystal structure of simple hexagonal type and selected from mixed carbides or carbonitrides of molybdenum and tungsten, which process comprises preparing an alloy powder consisting of a solid solution of molybdenum and tungsten, adding to the alloy powder carbon in an amount necessary for forming (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN), heating the mixture at a temperature at which (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN) is stable, adding to the (Mo, W).sub.2 C and/or (Mo, W).sub.2 (CN) carbon in an amount necessary for forming (Mo, W)C and/or (Mo, W)(CN) optionally with an iron group metal and then heating the mixture at a temperature at which (Mo, W)C and/or (Mo, W)(CN) is stable.
摘要翻译: 本发明涉及一种由至少一种具有简单六边形晶体结构并选自钼和钨的混合碳化物或碳氮化物的硬相构成的固溶体的方法,该方法包括制备由 将钼和钨的固溶体加入到形成(Mo,W)2C和/或(Mo,W)2(CN)所需的量的合金粉末碳上,在(Mo, W)2C和/或(Mo,W)2(CN)是稳定的,以(Mo,W)2和/或(Mo,W)2(CN) )和/或(Mo,W)(CN),然后在(Mo,W)C和/或(Mo,W)(CN)稳定的温度下加热混合物。
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公开(公告)号:US4639352A
公开(公告)日:1987-01-27
申请号:US808228
申请日:1985-12-13
申请人: Mitsuo Kodama , Masaya Miyake , Minol Nakano , Tsuyoshi Asai , Akio Hara
发明人: Mitsuo Kodama , Masaya Miyake , Minol Nakano , Tsuyoshi Asai , Akio Hara
CPC分类号: C01B31/34 , C01B31/301 , C22C1/051 , C22C29/00 , C22C29/02 , C01P2004/80 , C01P2006/10 , C01P2006/80 , C01P2006/90
摘要: This invention relates to a hard alloy comprising two phases: a hard phase consisting of at least one compound having a crystal structure of simple hexagonal MC type (M: metal; C: carbon) selected from the group consisting of mixed carbides, carbonitrides and carboxynitrides of molybdenum and tungsten, and a binder phase consisting of at least one element selected from the group consisting of iron, cobalt and nickel. The hard phase is prepared by carburizing an (Mo, W) alloy obtained by reducing oxides of molybdenum and tungsten with a particle size of at most 1 micron, is composed of coarse particles with a mean particle size of at least 3 microns, and has a uniform molybdenum to tungsten ratio in the particles. The hard alloy has a gross composition within the range of the shaded portion ABCDEA in FIG. 1.
摘要翻译: 本发明涉及包含两相的硬质合金:由至少一种具有简单的六方晶系MC型(M:金属; C:碳)的晶体结构的化合物组成的硬质相,该化合物选自混合碳化物,碳氮化物和羧基氮化物 的钼和钨,以及由至少一种选自铁,钴和镍的元素组成的粘结相。 硬相是通过将通过还原氧化钼和钨的粒径至多为1微米的(Mo,W)合金进行渗碳制备的,由具有至少3微米的平均粒度的粗颗粒组成,并且具有 颗粒中钼与钨的比例均匀。 该硬质合金的总组成在图7中的阴影部分ABCDEA的范围内。 1。
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6.
公开(公告)号:US4225344A
公开(公告)日:1980-09-30
申请号:US925697
申请日:1978-07-17
申请人: Naoji Fujimori , Masaya Miyake , Takaharu Yamamoto , Akio Hara
发明人: Naoji Fujimori , Masaya Miyake , Takaharu Yamamoto , Akio Hara
CPC分类号: C22C1/051 , B22F3/003 , B22F3/101 , B22F2998/00
摘要: This invention relates to a process for producing sintered hard metals which comprises sintering a compact for the sintered hard metals or sintering a formed body obtained from the compact through a presintering treatment and, if necessary, a machining treatment, a part or all of the heating steps and cooling steps being carried out in an atmospheres of hydrogen and an atmosphere of carbon monoxide.
摘要翻译: 本发明涉及一种烧结硬质金属的制造方法,其特征在于,烧结硬质合金用烧结体,或通过预烧处理烧结由该坯体得到的成形体,如果需要,进行加工处理,加热部分或全部 步骤和冷却步骤在氢气和一氧化碳气氛中进行。
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公开(公告)号:US4279651A
公开(公告)日:1981-07-21
申请号:US974512
申请日:1978-12-28
CPC分类号: C22C29/00
摘要: The invention relates to a sintered hard metal having a high wear resistance and heat resistance as material for cutting tools and wear resistant tools and the method for producing the same. The sintered hard metal has a hard phase comprising a phase having a B-1 type crystal structure containing more than one kind of IVa, Va and VIa group metals in the Periodic Table and also the elements, carbon, nitrogen and oxygen and a WC phase, the hard phase and a bonding phase chiefly consisting of a ferrous metal which is sintered by a powder metallurgy technique, whereas the oxygen in particular is added thereto making it possible to obtain a sintered hard metal having said excellent properties.
摘要翻译: 本发明涉及具有高耐磨性和耐热性的烧结硬金属作为切削工具和耐磨工具的材料及其制造方法。 烧结硬质金属具有包含在周期表中含有多于一种IVa,Va和VIa族金属的B-1型晶体结构的相的硬相以及元素,碳,氮和氧以及WC相 硬质相和主要由通过粉末冶金技术烧结的黑色金属组成的结合相,特别是加入氧,使得可以获得具有优异性能的烧结硬质金属。
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公开(公告)号:US4492846A
公开(公告)日:1985-01-08
申请号:US433533
申请日:1982-10-08
申请人: Akio Hara , Masaya Miyake , Shuji Yazu
发明人: Akio Hara , Masaya Miyake , Shuji Yazu
CPC分类号: B23K1/0056 , B23K15/00 , B23K35/30
摘要: Process for the production of bonded hard alloys, which comprises inserting a thin sheet of a Fe group metal or its alloy as a filler in between the surfaces of at least one kind of hard alloy, and applying a high energy beam to a part or all of the thin sheet to melt and solidify the thin sheet in a slit form, thereby bonding the hard alloys together.
摘要翻译: 粘结硬质合金的制造方法,其包括在至少一种硬质合金的表面之间插入作为填料的Fe族金属或其合金的薄片,并将高能束施加到部分或全部 的薄片以狭缝形式熔化和固化薄片,从而将硬合金粘合在一起。
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9.
公开(公告)号:US4008090A
公开(公告)日:1977-02-15
申请号:US609729
申请日:1975-09-02
申请人: Masaya Miyake , Akio Hara , Noriyuki Ayano
发明人: Masaya Miyake , Akio Hara , Noriyuki Ayano
CPC分类号: C04B35/5626 , C01B31/301 , C01B31/34 , C04B35/5607 , C04B35/5611 , C04B35/65 , C01P2004/03 , C01P2004/61 , C01P2004/62 , C01P2004/84 , C01P2006/60 , C01P2006/80 , C01P2006/90
摘要: A process for the production of tungsten carbide or mixed metal carbides, which comprises mixing tungsten oxide powder of mixed high melting point metal oxide powders with carbon powder in an amount sufficient to form the corresponding carbide, heating the mixture at a temperature of higher than 1000.degree. C in an inert atmosphere or in vacuum to reduce the oxygen content and then heating at a temperature of higher than 1400.degree. C in hydrogen atmosphere, thereby to form tungsten carbide or mixed metal carbides directly from the corresponding oxide.
摘要翻译: 一种生产碳化钨或混合金属碳化物的方法,其包括将混合的高熔点金属氧化物粉末的氧化钨粉末与足以形成相应碳化物的量的碳粉混合,在高于1000℃的温度下加热该混合物 在惰性气氛中或在真空中进行,以降低氧含量,然后在氢气氛中在高于1400℃的温度下加热,从而直接从相应的氧化物形成碳化钨或混合的金属碳化物。
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公开(公告)号:US5306679A
公开(公告)日:1994-04-26
申请号:US24820
申请日:1993-03-01
申请人: Kouhei Shimoda , Takao Maeda , Kouichi Sogabe , Masaya Miyake
发明人: Kouhei Shimoda , Takao Maeda , Kouichi Sogabe , Masaya Miyake
IPC分类号: C04B35/581 , H01L21/48 , C04B35/58
CPC分类号: C04B35/581 , H01L21/4807
摘要: A heat conductive aluminum nitride sintered body contains 100 parts by weight of aluminum nitride, at least 0.005 parts by weight and not more than 0.5 parts by weight of carbon, at least 0.01 parts by weight and not more than 15 parts by weight of a rare earth aluminum oxide in terms of the simple substance of a rare earth element, and at least 0.01 parts by weight and not more than 15 parts by weight of at least one element selected from a group of compounds containing elements belonging to the groups IVB, VB and VIB of the periodic table in terms of the simple substance of the element. Such a sintered body has a heat conductivity of at least 100 W/m.multidot.K. and not more than 270 W/m.multidot.K. at room temperature.
摘要翻译: 导热氮化铝烧结体含有100重量份的氮化铝,至少0.005重量份,不超过0.5重量份的碳,至少0.01重量份,不超过15重量份的稀有金属 以稀土元素的单质为基准的至少0.01重量份至少15重量份的选自包含属于IVB族,VB族的元素的化合物的族中的至少一种元素 和元素周期表的VIB。 这种烧结体的导热率至少为100W / m×K。 不超过270 W / m * K。 在室温下。
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