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公开(公告)号:US10160715B2
公开(公告)日:2018-12-25
申请号:US15249061
申请日:2016-08-26
Applicant: Massachusetts Institute of Technology
IPC: C07C67/293 , C07C69/604 , B01D53/02 , B01J20/26
Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.
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公开(公告)号:US20180244602A9
公开(公告)日:2018-08-30
申请号:US15249061
申请日:2016-08-26
Applicant: Massachusetts Institute of Technology
IPC: C07C69/604 , C07C67/293 , B01D53/02 , B01J20/26
CPC classification number: C07C69/604 , B01D53/02 , B01D2253/20 , B01D2257/40 , B01D2257/7027 , B01D2257/704 , B01J20/261 , C07C67/293
Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.
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公开(公告)号:US20180057443A1
公开(公告)日:2018-03-01
申请号:US15249061
申请日:2016-08-26
Applicant: Massachusetts Institute of Technology
IPC: C07C69/604 , C07C67/293 , B01D53/02 , B01J20/26
CPC classification number: C07C69/604 , B01D53/02 , B01D2253/20 , B01D2257/40 , B01D2257/7027 , B01D2257/704 , B01J20/261 , C07C67/293
Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.
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