公开(公告)号：US10160715B2

公开(公告)日：2018-12-25

申请号：US15249061

申请日：2016-08-26

Applicant: Massachusetts Institute of Technology

Inventor： Timothy M. Swager ,  Yanchuan Zhao ,  Silvia Veleirinho de Oliveira Rocha

IPC: C07C67/293 ,  C07C69/604 ,  B01D53/02 ,  B01J20/26

Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.

公开(公告)号：US20180244602A9

公开(公告)日：2018-08-30

申请号：US15249061

申请日：2016-08-26

Applicant: Massachusetts Institute of Technology

Inventor： Timothy M. Swager ,  Yanchuan Zhao ,  Silvia Veleirinho de Oliveira Rocha

IPC: C07C69/604 ,  C07C67/293 ,  B01D53/02 ,  B01J20/26

CPC classification number: C07C69/604 ,  B01D53/02 ,  B01D2253/20 ,  B01D2257/40 ,  B01D2257/7027 ,  B01D2257/704 ,  B01J20/261 ,  C07C67/293

Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.

公开(公告)号：US20180057443A1

公开(公告)日：2018-03-01

申请号：US15249061

申请日：2016-08-26

Applicant: Massachusetts Institute of Technology

Inventor： Timothy M. Swager ,  Yanchuan Zhao ,  Silvia Veleirinho de Oliveira Rocha

IPC: C07C69/604 ,  C07C67/293 ,  B01D53/02 ,  B01J20/26

CPC classification number: C07C69/604 ,  B01D53/02 ,  B01D2253/20 ,  B01D2257/40 ,  B01D2257/7027 ,  B01D2257/704 ,  B01J20/261 ,  C07C67/293

Abstract: Methods for mechanochemically synthesizing compositions comprising bridged bicyclic-based compounds such as iptycene-based compounds are generally provided. In some cases, two or more polycyclic aromatic hydrocarbons may be mechanochemically reacted such that the product comprises the bridged bicyclic-based compound. In some embodiments, the product (e.g., the bridged bicyclic compound) may comprise two or more [2.2.2] bicyclic cores. In certain embodiments, the mechanochemical reactions described herein may produce higher order bridged bicyclic-based compounds such as oligoiptcyenes or poly-iptycenes. In certain embodiments, the bridged bicyclic based compound comprises a molecular cage.