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1.发明申请公开(公告)号：US20050234269A1
公开(公告)日：2005-10-20
申请号：US10513290
申请日：2003-04-29
申请人： Melvyn Kilner , Derek Tyers , Simon Crabtree , Michael Wood
发明人： Melvyn Kilner , Derek Tyers , Simon Crabtree , Michael Wood
IPC分类号： C07D307/04 , B01J31/24 , B01J31/40 , C07B61/00 , C07C27/04 , C07C29/149 , C07C31/10 , C07C31/20 , C07C209/50 , C07C211/07 , C07D309/30
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J2231/641 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/842 , B01J2531/96 , C07C27/04 , C07C29/149 , Y02P20/52 , Y02P20/584 , C07C31/10 , C07C31/205 , C07C31/207 , C07C31/04
摘要： A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
摘要翻译： 描述了在包含钌，铑，铁，锇或钯的催化剂和有机膦的存在下氢化羧酸和/或其衍生物的均匀方法，其中氢化在存在下进行 至少约1重量％的水。 还描述了一种用于再生含有钌，铑，铁，锇或钯和有机膦的催化剂的方法，其中再生在氢和水的存在下进行。
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2.发明申请公开(公告)号：US20130029831A1
公开(公告)日：2013-01-31
申请号：US13588595
申请日：2012-08-17
IPC分类号： B01J31/40
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J2231/641 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/842 , B01J2531/96 , C07C27/04 , C07C29/149 , Y02P20/52 , Y02P20/584 , C07C31/10 , C07C31/205 , C07C31/207 , C07C31/04
摘要： A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
摘要翻译： 描述了在包含钌，铑，铁，锇或钯的催化剂和有机膦的存在下氢化羧酸和/或其衍生物的均匀方法，其中氢化在存在下进行 至少约1重量％的水。 还描述了一种用于再生含有钌，铑，铁，锇或钯和有机膦的催化剂的方法，其中再生在氢和水的存在下进行。
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3.发明授权公开(公告)号：US07709689B2
公开(公告)日：2010-05-04
申请号：US10513290
申请日：2003-04-29
IPC分类号： C07C27/04
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J2231/641 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/842 , B01J2531/96 , C07C27/04 , C07C29/149 , Y02P20/52 , Y02P20/584 , C07C31/10 , C07C31/205 , C07C31/207 , C07C31/04
摘要： A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
摘要翻译： 描述了在包含钌，铑，铁，锇或钯的催化剂和有机膦的存在下氢化羧酸和/或其衍生物的均匀方法，其中氢化在存在下进行 至少约1重量％的水。 还描述了一种用于再生含有钌，铑，铁，锇或钯和有机膦的催化剂的方法，其中再生在氢和水的存在下进行。
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公开(公告)号：US09636671B2
公开(公告)日：2017-05-02
申请号：US13588595
申请日：2012-08-17
IPC分类号： C07C27/04 , B01J31/24 , B01J31/40 , C07C29/149
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J2231/641 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/842 , B01J2531/96 , C07C27/04 , C07C29/149 , Y02P20/52 , Y02P20/584 , C07C31/10 , C07C31/205 , C07C31/207 , C07C31/04
摘要： A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
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5.发明申请公开(公告)号：US20100099550A1
公开(公告)日：2010-04-22
申请号：US12546187
申请日：2009-08-24
CPC分类号： B01J31/2409 , B01J31/24 , B01J31/4023 , B01J31/4046 , B01J31/4053 , B01J2231/641 , B01J2531/0258 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/842 , B01J2531/96 , C07C27/04 , C07C29/149 , Y02P20/52 , Y02P20/584 , C07C31/10 , C07C31/205 , C07C31/207 , C07C31/04
摘要： A homogenous process for the hydrogenation of the carboxylic acids and/or derivatives thereof in the presence of a catalyst comprising ruthenium, rhodium, iron, osmium or palladium, and an organic phosphine is described in which the hydrogenation is carried out in the presence of at least about 1% by weight water. A process for regenerating a catalyst comprising ruthenium, rhodium, iron, osmium or palladium and an organic phosphine is also described in which the regeneration is carried out in the presence of hydrogen and water.
摘要翻译： 描述了在包含钌，铑，铁，锇或钯的催化剂和有机膦的存在下氢化羧酸和/或其衍生物的均匀方法，其中氢化在存在下进行 至少约1重量％的水。 还描述了一种用于再生含有钌，铑，铁，锇或钯和有机膦的催化剂的方法，其中再生在氢和水的存在下进行。
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