摘要:
One exemplary embodiment can be a system for separating a plurality of naphtha components. The system can include a column, an overhead condenser, and a side condenser. Generally, the column includes a dividing imperforate wall with one surface facing a feed and another surface facing at least one side stream. Typically, the wall extends a significant portion of the column height to divide the portion into at least two substantially vertical, parallel contacting sections. Typically, the overhead condenser receives an overhead stream including a light naphtha from the column. Usually, a side condenser receives a process stream from the column and returns the stream to the column to facilitate separation. A cooling stream may pass through the overhead condenser and then the side condenser.
摘要:
The selective saturation of unsaturated aliphatic hydrocarbons (e.g., diolefins) in a hydrogenation feed stream comprising an aromatic compound (e.g., benzene) and one or more nitrogen compounds renders it beneficial when the stream or a portion thereof is subsequently treated (e.g., with a zeolitic adsorbent) to remove nitrogen. In particular, the selective saturation of, for example, olefins and diolefins prolongs the life of the nitrogen guard bed. In a representative embodiment, the selective hydrogenation is applied to a recycle benzene-containing stream recovered in the separation section (e.g., from the benzene/toluene splitter overhead) of a styrene production process, prior to treatment with a nitrogen guard bed adsorbent.
摘要:
In an oligomerization apparatus comprising at least two oligomerization reactors, at least portions of product streams from two reactors are separated in the same separator vessel; a liquid product stream from the first oligomerization reactor is fed to a fractionation column and a side cut from the fractionation column feeds the second oligomerization reactor.
摘要:
Methods are disclosed for the dehydrogenation of feed streams, such as in the manufacture of styrene from ethylbenzene, using a catalyst bed having catalyst with differing activities. In particular, the use of upstream and downstream catalyst beds of relatively low and high activities, respectively, can reduce the production of unwanted byproducts, especially in styrene production processes employing an oxidative reheat step (oxidation zone) prior to ethylbenzene dehydrogenation. The methods allow the maximum temperature in the oxidation zone to be decreased, thereby reducing the formation of unwanted oxygenated byproducts (e.g., phenol).
摘要:
In an oligomerization process comprising at least two oligomerization reactors, at least portions of product streams from two reactors are separated in the same separator vessel. In an embodiment, a liquid product stream from the first oligomerization reactor is fed to a fractionation column and a side cut from the fractionation column feeds the second oligomerization reactor.
摘要:
One exemplary embodiment can be a system for separating a plurality of naphtha components. The system can include a column, an overhead condenser, and a side condenser. Generally, the column includes a dividing imperforate wall with one surface facing a feed and another surface facing at least one side stream. Typically, the wall extends a significant portion of the column height to divide the portion into at least two substantially vertical, parallel contacting sections. Typically, the overhead condenser receives an overhead stream including a light naphtha from the column. Usually, a side condenser receives a process stream from the column and returns the stream to the column to facilitate separation. A cooling stream may pass through the overhead condenser and then the side condenser.
摘要:
A liquid polishing composition of the invention suitable for polishing an automobile and the like comprises about 0.01 to about 3 percent by weight of at least one silicone-based wax, about 0.20 to about 10 percent by weight of poly(alpha olefin) compounds including about 0.1 to about 5 percent by weight of at least one hyperbranched poly(alpha olefin), about 6 to about 60 percent by weight of at least one polydimethylsiloxane silicone fluid, about 1 to about 20 percent by weight of at least one volatile cyclic silicone, about 0.25 to about 3 percent by weight of at least one amino-functional silicone, about 0.01 to about 5 percent by weight of at least one UV absorber, and a petroleum-based carrier therefor. The liquid polishing composition can be packaged together with a microfiber polishing cloth in the form of a polishing kit. The liquid polishing composition provides a long lasting showroom finish and can be used directly on rubber, vinyl, and plastic components without leaving a white residue, commonly associated with conventional polishing compositions.
摘要:
In an alkylation zone, a benzene recycle stream and a propylene feed stream are contacted with an alkylation catalyst to convert the propylene and benzene into cumene. In a transalkylation zone, a polyisopropylbenzene stream and a benzene recycle stream are contacted with a transalkylation catalyst to convert the polyisopropylbenzene and benzene into cumene. The alkylation and transalkylation zone effluents are passed into a dividing wall fractionation column.A cumene product stream is removed from an intermediate point of the dividing wall fractionation column. A benzene recycle stream is removed from a first end, and another benzene recycle stream is removed from an intermediate point of the dividing wall fractionation column. A polyisopropylbenzene stream is removed from a second end of the dividing wall fractionation column. The polyisopropylbenzene stream is passed to a polyisopropylbenzene fractionation column to separate the polyisopropylbenzene from a heavy ends stream.
摘要:
This cumene process involves contacting, in an alkylation zone, a first benzene recycle stream and a propylene feed stream with an alkylation catalyst to form cumene. In a transalkylation zone, a polyisopropylbenzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional cumene. The effluents are passed into a benzene distillation column. From the benzene distillation column, a first benzene recycle stream is removed as overhead; a second benzene recycle stream is removed as a side draw; and a bottoms stream comprising polyisopropylbenzene, cumene, and heavy aromatics is removed from an end. The bottoms stream is passed to a dividing wall distillation column where the polyisopropylbenzene recycle stream is removed from an intermediate point; a cumene product stream is removed from a first end, and a heavy aromatic stream is removed from a second end.
摘要:
This ethylbenzene process involves contacting, in an alkylation zone, a first benzene recycle stream and an ethylene feed stream with an alkylation catalyst to form ethylbenzene. In a transalkylation zone, a polyethylbenzene recycle stream and a second benzene recycle stream are contacted with a transalkylation catalyst to form additional ethylbenzene. The effluents are passed into a benzene distillation column. From the benzene distillation column, a first benzene recycle stream is removed as overhead; a second benzene recycle stream is removed as a side draw; and a bottoms stream comprising polyethylbenzene, ethylbenzene, and flux oil is removed from an end. The bottoms stream is passed to a dividing wall distillation column where the polyethylbenzene recycle stream is removed from an intermediate point; an ethylbenzene product stream is removed from a first end, and a heavy oil stream is removed from a second end.