公开(公告)号：US07385089B2

公开(公告)日：2008-06-10

申请号：US11567398

申请日：2006-12-06

申请人： Michael G. Costello ,  Richard M. Flynn ,  Jay F. Schulz ,  George G. I. Moore

发明人： Michael G. Costello ,  Richard M. Flynn ,  Jay F. Schulz ,  George G. I. Moore

IPC分类号： C07C49/173 ,  C07C43/00 ,  C10M107/34 ,  C09K5/04

CPC分类号： C07C49/175 ,  C08G65/007

摘要： A fluorochemical ketone compound consists of two terminal, branched, independently fluoroalkylcarbonyl or perfluoroalkylcarbonyl groups and an intervening linear perfluoropolyether segment, each of the terminal groups optionally comprising at least one catenated heteroatom, and the perfluoropolyether segment consisting essentially of at least one tetrafluoroethyleneoxy moiety and, optionally, at least one difluoromethyleneoxy moiety, the moieties being randomly or non-randomly distributed within the perfluoropolyether segment.

摘要翻译： 含氟酮化合物由两个末端，支链，独立的氟代烷基羰基或全氟烷基羰基和插入的直链全氟聚醚链段组成，每个末端基团任选地包含至少一个连接的杂原子，并且全氟聚醚链段主要由至少一个四氟乙烯氧基部分组成， 任选地，至少一个二氟亚甲基氧基部分，所述部分是随机或非随机分布在全氟聚醚部分内。

公开(公告)号：US20070163710A1

公开(公告)日：2007-07-19

申请号：US11567398

申请日：2006-12-06

申请人： Michael G. Costello ,  Richard M. Flynn ,  Jay F. Schulz ,  George G. I. Moore

发明人： Michael G. Costello ,  Richard M. Flynn ,  Jay F. Schulz ,  George G. I. Moore

IPC分类号： C10M107/34 ,  B32B27/00 ,  C07C49/753

CPC分类号： C07C49/175 ,  C08G65/007

摘要： A fluorochemical ketone compound consists of two terminal, branched, independently fluoroalkylcarbonyl or perfluoroalkylcarbonyl groups and an intervening linear perfluoropolyether segment, each of the terminal groups optionally comprising at least one catenated heteroatom, and the perfluoropolyether segment consisting essentially of at least one tetrafluoroethyleneoxy moiety and, optionally, at least one difluoromethyleneoxy moiety, the moieties being randomly or non-randomly distributed within the perfluoropolyether segment.

摘要翻译： 含氟酮化合物由两个末端，支链，独立的氟代烷基羰基或全氟烷基羰基和插入的直链全氟聚醚链段组成，每个末端基团任选地包含至少一个连接的杂原子，并且全氟聚醚链段主要由至少一个四氟乙烯氧基部分组成， 任选地，至少一个二氟亚甲基氧基部分，所述部分是随机或非随机分布在全氟聚醚部分内。

公开(公告)号：US07795332B2

公开(公告)日：2010-09-14

申请号：US11420416

申请日：2006-05-25

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Löchhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Löchhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method for removing a fluorinated carboxylic acid or salt thereof from an aqueous liquid by contacting the aqueous liquid with adsorbent particles. The fluorinated carboxylic acid or salt thereof is selected from the group consisting of partially fluorinated carboxylic acids or salts thereof and fully fluorinated carboxylic acids or salts thereof.

摘要翻译： 通过使含水液体与吸附剂颗粒接触从水性液体中除去氟化羧酸或其盐的方法。 氟化羧酸或其盐选自部分氟化的羧酸或其盐和完全氟化的羧酸或其盐。

公开(公告)号：US07671112B2

公开(公告)日：2010-03-02

申请号：US11420386

申请日：2006-05-25

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性部分或完全氟化的亚烷基或脂族烃基，Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化脂族基，X i +表示具有i价和 我是1,2或3; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

公开(公告)号：US08222322B2

公开(公告)日：2012-07-17

申请号：US12684239

申请日：2010-01-08

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链部分或完全氟化的脂族基团或被一个氧原子间隔的直链部分或全氟化的脂族基团，X i +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

公开(公告)号：US07754795B2

公开(公告)日：2010-07-13

申请号：US11420431

申请日：2006-05-25

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08K5/00

CPC分类号： C09D127/18 ,  C08K5/06 ,  C08K5/09 ,  C08L27/12 ,  C08L71/02 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2205/035 ,  C08L2666/02 ,  C08L2666/14

摘要： A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.

摘要翻译： 一种涂料组合物，其具有（i）含氟聚合物颗粒的水分散体，其包含四氟乙烯的不可熔融加工聚合物，（ii）氟化表面活性剂，（iii）非离子非氟化表面活性剂和（iv）非氟化聚合物 其中氟化表面活性剂选自通式（I）的氟化羧酸或其盐：[Rf-OL-COO-] iXi +（I）其中L表示直链部分或完全氟化的亚烷基或脂族烃基 Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化的脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子。

公开(公告)号：US06649719B2

公开(公告)日：2003-11-18

申请号：US09931215

申请日：2001-08-16

申请人： George G. I. Moore ,  Michael A. Yandrasits ,  Jay F. Schulz ,  Richard M. Flynn

发明人： George G. I. Moore ,  Michael A. Yandrasits ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08F1418

CPC分类号： C09D133/16 ,  C07C69/63 ,  C08F20/24 ,  C08F120/24

摘要： Described is a compound having at least one acrylate monomer, said monomer including at least one pendant group of the structure —O—CH(Rf)(Rf′), wherein Rf is a straight chain or branched perfluoroalkyl group with five or less carbon atoms, and Rf′ is a branched perfluoroalkyl group with three to five carbon atoms; and a method of reducing the surface tension of a liquid by adding a compound of the invention to the liquid. Also described is a composition that includes a compound of the invention in an aqueous solution or dispersion; a method of treating a substrate to render it oil- and/or water-repellent that includes treating a substrate with a composition of the invention; a method of coating an electrical device that includes applying a composition of the invention; a method of coating optical fibers that includes applying a composition of the invention; and an article that includes a substrate treated with a composition of the invention.

摘要翻译： 描述了具有至少一种丙烯酸酯单体的化合物，所述单体包括至少一个-O-CH（Rf）（Rf'）结构的侧基，其中Rf是具有五个或更少碳原子的直链或支链全氟烷基 ，Rf'为3〜5个碳原子的支链全氟烷基; 以及通过将本发明的化合物加入到液体中来降低液体的表面张力的方法。 还描述了在水溶液或分散体中包含本发明化合物的组合物; 处理基材以使其具有油和/或防水性的方法，其包括用本发明的组合物处理基材; 包括施用本发明的组合物的电气装置的涂覆方法; 涂布光纤的方法，其包括施加本发明的组合物; 以及包含用本发明的组合物处理的基材的制品。

公开(公告)号：US08614265B2

公开(公告)日：2013-12-24

申请号：US13494260

申请日：2012-06-12

申请人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

发明人： Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Helmut Lochhaas ,  Andreas R. Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael C. Dadalas ,  George G. I. Moore ,  Jay F. Schulz ,  Richard M. Flynn

IPC分类号： C08L1/00

CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

公开(公告)号：US06255535B1

公开(公告)日：2001-07-03

申请号：US09470034

申请日：1999-12-22

申请人： Jay F. Schulz ,  George G. I. Moore ,  Werner Schwertfeger ,  Klaus Hintzer ,  Zai-Ming Qiu ,  Miguel A. Guerra ,  Erik D. Hare ,  Allan T. Worm

发明人： Jay F. Schulz ,  George G. I. Moore ,  Werner Schwertfeger ,  Klaus Hintzer ,  Zai-Ming Qiu ,  Miguel A. Guerra ,  Erik D. Hare ,  Allan T. Worm

IPC分类号： C07C4330

CPC分类号： C07C43/17 ,  C07C41/16 ,  C07C41/22 ,  C07C41/24 ,  C07C43/313 ,  C07C43/126

摘要： The present invention describes a novel process for the preparation of perfluoro allyl ethers. The process involves providing a hydrogen-containing precursor comprising at least one 1,2-dichloro alkyl ether moiety, fluorinating the precursor to provide a perfluorinated intermediate, and dechlorinating the perfluorinated intermediate to the corresponding perfluorinated ether. A reaction product of a perfluorinated olefin and an allyl ether may also be used as a precursor. Such a reaction product is chlorinated before the fluorination step. Perfluoro vinyl or allyl ethers may be used in place of the perfluorinated olefin. Novel perfluoro alkoxy compounds are also described.

摘要翻译： 本发明描述了制备全氟烯丙基醚的新方法。 该方法包括提供包含至少一个1,2-二氯烷基醚部分的含氢前体，氟化前体以提供全氟化中间体，并将全氟化中间体脱氯至相应的全氟化醚。 全氟化烯烃和烯丙基醚的反应产物也可以用作前体。 这样的反应产物在氟化步骤之前被氯化。 可以使用全氟乙烯基或烯丙基醚代替全氟化烯烃。 还描述了新的全氟烷氧基化合物。

公开(公告)号：US06005137A

公开(公告)日：1999-12-21

申请号：US872235

申请日：1997-06-10

申请人： George G. I. Moore ,  Fred B. McCormick ,  Mita Chattoraj ,  Elisa M. Cross ,  Junkang Jacob Liu ,  Ralph R. Roberts ,  Jay F. Schulz

发明人： George G. I. Moore ,  Fred B. McCormick ,  Mita Chattoraj ,  Elisa M. Cross ,  Junkang Jacob Liu ,  Ralph R. Roberts ,  Jay F. Schulz

IPC分类号： C07C45/45 ,  C07C69/653 ,  C07D213/64 ,  C07D213/65 ,  C07D213/68 ,  C07D213/70 ,  C08F20/22 ,  C08F20/34 ,  C08F20/38 ,  C07C69/00

CPC分类号： C07D213/64 ,  C07C45/455 ,  C07C69/653 ,  C08F20/22 ,  C08F20/34 ,  C08F20/38

摘要： Acrylates having a high degree of halogenation, as well as polymers that include one or more mer units derived from such acrylates provide materials having tailorable optical and physical properties. The polymers find utility particularly in optical devices including optical waveguides and interconnecting devices.

摘要翻译： 具有高度卤化度的丙烯酸酯以及包含衍生自这种丙烯酸酯的一个或多个聚合单体的聚合物提供具有可裁剪的光学和物理性质的材料。 聚合物特别适用于包括光波导和互连装置的光学装置。