PARTIALLY FLUORINATED KETONES AND METHODS OF MAKING AND USING THE SAME
    1.
    发明申请
    PARTIALLY FLUORINATED KETONES AND METHODS OF MAKING AND USING THE SAME 有权
    部分氟化酮及其制备方法和使用方法

    公开(公告)号:US20140130713A1

    公开(公告)日:2014-05-15

    申请号:US14123788

    申请日:2012-05-22

    摘要: Partially fluorinated ketones are provided that include a terminal alkyl group having from 1 to 6 carbon atoms bonded to a carbonyl group and a hydrofluoroether moiety having from 2 to 4 carbon atoms that contains at least one hydrogen substituent. The hydrofluoroether moiety is bonded to the carbonyl group with a carbon-carbon bond. The ether oxygen is bonded to a carbon atom that is at least two carbon atoms removed from the carbonyl group. Additionally, a fluorinated alkyl group having from 1 to 10 carbon atoms is bonded to the ether oxygen of the hydrofluoroether moiety. These partially fluorinated ketones can be used in a wide variety of electronics applications.

    摘要翻译: 提供部分氟化的酮,其包括具有1-6个碳原子的与羰基键合的末端烷基和含有至少一个氢取代基的含2至4个碳原子的氢氟醚部分。 氢氟醚部分与碳 - 碳键连接在羰基上。 醚氧键与从羰基除去至少两个碳原子的碳原子结合。 另外,具有1〜10个碳原子的氟化烷基与氢氟醚部分的醚氧键合。 这些部分氟化酮可用于各种电子应用。

    Fluorinated composition, method of coating the composition, and article thereby
    2.
    发明授权
    Fluorinated composition, method of coating the composition, and article thereby 有权
    氟化组合物,涂覆组合物的方法和由此制成的制品

    公开(公告)号:US08664323B2

    公开(公告)日:2014-03-04

    申请号:US13111504

    申请日:2011-05-19

    IPC分类号: C09D181/02

    摘要: A fluorinated composition includes: a polyfluoropolyether silane represented by the formula: RfaO(CF(CF3)CF2O)pCF(CF3)CH2OZ1Si(Y1)3; and a polyfluoropolyether silane represented by the formula: Rfb[R5CH2OZ2Si(Y2)3]2 Rfa represents a perfluoroalkyl group having from 1 to 12 carbon atoms, optionally substituted with at least one catenated oxygen atom or —NR8— group, wherein R8 represents a perfluoroalkyl group; Z1 represents —R1SR2—, —R1S(═O)R2—, or —R1S(═O)2R2, wherein R1 and R2 independently represent alkylene groups having from 1 to 12 carbon atoms; each Y1 independently represents a hydrolyzable group; and p is a number in a range of from 3 to 50; Z2 independently represents —R3SR4—, —R3S(═O)R4—, or —R3S(═O)2R4, wherein R3 and R4 independently represent alkylene groups having from 1 to 12 carbon atoms; Y2 independently represents a hydrolyzable group; Rfb represents a perfluoroalkylene group having at least 3 carbon atoms, optionally substituted with at least one catenated oxygen atom or —NR6— group, wherein R6 represents a perfluoroalkyl group; R5 independently represents a covalent bond, or —(OR7)b—, and wherein R7 independently represents a branched perfluoroalkylene group, and b independently represents a number greater than or equal to one.

    摘要翻译: 氟化组合物包括:由式:RfaO(CF(CF 3)CF 2 O)pCF(CF 3)CH 2 OZ 1 Si(Y 1)3表示的多氟聚醚硅烷; 和由式Rfb [R5CH2OZ2Si(Y2)3] 2表示的多氟聚醚硅烷,Rfa表示任选被至少一个连接的氧原子或-NR 8 - 基团取代的具有1至12个碳原子的全氟烷基,其中R 8表示 全氟烷基 Z1表示-R1SR2-,-R1S(= O)R2-或-R1S(= O)2R2,其中R1和R2独立地表示具有1至12个碳原子的亚烷基; 每个Y1独立地表示可水解基团; 并且p是3至50范围内的数字; Z2独立地表示-R3SR4​​-,-R3S(= O)R4-或-R3S(= O)2R4,其中R3和R4独立地表示具有1至12个碳原子的亚烷基; Y2独立地表示可水解基团; Rfb表示具有至少3个碳原子的全氟亚烷基,任选被至少一个连接的氧原子或-NR 6 - 基团取代,其中R 6表示全氟烷基; R5独立地表示共价键,或 - (OR7)b-,其中R7独立地表示支链全氟亚烷基,b独立地表示大于或等于1的数。

    FLUORINATED COMPOSITION, METHOD OF COATING THE COMPOSITION, AND ARTICLE THEREBY
    4.
    发明申请
    FLUORINATED COMPOSITION, METHOD OF COATING THE COMPOSITION, AND ARTICLE THEREBY 有权
    氟化组合物,涂料组合物的方法及其制品

    公开(公告)号:US20110319546A1

    公开(公告)日:2011-12-29

    申请号:US13111504

    申请日:2011-05-19

    摘要: A fluorinated composition includes: a polyfluoropolyether silane represented by the formula: RfaO(CF(CF3)CF2O)pCF(CF3)CH2OZ1Si(Y1)3; and a polyfluoropolyether silane represented by the formula: Rfb[R5CH2OZ2Si(Y2)3]2 Rfa represents a perfluoroalkyl group having from 1 to 12 carbon atoms, optionally substituted with at least one catenated oxygen atom or —NR8— group, wherein R8 represents a perfluoroalkyl group; Z1 represents —R1SR2—, —R1S(═O)R2—, or —R1S(═O)2R2, wherein R1 and R2 independently represent alkylene groups having from 1 to 12 carbon atoms; each Y1 independently represents a hydrolyzable group; and p is a number in a range of from 3 to 50; Z2 independently represents —R3SR4—, —R3S(═O)R4—, or —R3S(═O)2R4, wherein R3 and R4 independently represent alkylene groups having from 1 to 12 carbon atoms; Y2 independently represents a hydrolyzable group; Rfb represents a perfluoroalkylene group having at least 3 carbon atoms, optionally substituted with at least one catenated oxygen atom or —NR6— group, wherein R6 represents a perfluoroalkyl group; R5 independently represents a covalent bond, or —(OR7)b—, and wherein R7 independently represents a branched perfluoroalkylene group, and b independently represents a number greater than or equal to one.

    摘要翻译: 氟化组合物包括:由式:RfaO(CF(CF 3)CF 2 O)pCF(CF 3)CH 2 OZ 1 Si(Y 1)3表示的多氟聚醚硅烷; 和由式Rfb [R5CH2OZ2Si(Y2)3] 2表示的多氟聚醚硅烷,Rfa表示任选被至少一个连接的氧原子或-NR 8 - 基团取代的具有1至12个碳原子的全氟烷基,其中R 8表示 全氟烷基 Z1表示-R1SR2-,-R1S(= O)R2-或-R1S(= O)2R2,其中R1和R2独立地表示具有1至12个碳原子的亚烷基; 每个Y1独立地表示可水解基团; 并且p是3至50范围内的数字; Z 2独立地表示-R 3 SR 4 - , - R 3 S(= O)R 4 - 或-R 3 S(= O)2 R 4,其中R 3和R 4独立地表示具有1至12个碳原子的亚烷基; Y2独立地表示可水解基团; Rfb表示具有至少3个碳原子的全氟亚烷基,任选被至少一个连接的氧原子或-NR 6 - 基团取代,其中R 6表示全氟烷基; R5独立地表示共价键,或 - (OR7)b-,其中R7独立地表示支链全氟亚烷基,b独立地表示大于或等于1的数。

    HYDROFLUOROACETAL COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE
    9.
    发明申请
    HYDROFLUOROACETAL COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE 有权
    氢氟醚化合物及其制备和使用的方法

    公开(公告)号:US20090326083A1

    公开(公告)日:2009-12-31

    申请号:US12164369

    申请日:2008-06-30

    摘要: The present disclosure provides a compound according to the formula: Rf1[CH(—O—CH(3-m)Rf2m)(—O—CF2—CFH—Rf3)]n   [I] wherein n is 1 or 2, wherein m is 1, 2 or 3, wherein, when n is 1, Rf1 is selected from the group consisting of highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein, when n is 2, Rf1 is selected from the group consisting of highly fluorinated alkylene groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein each Rf2 is independently selected from the group consisting of alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein at least one Rf2 is highly fluorinated; wherein each Rf3 is independently selected from the group consisting of fluorine and highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms. Also provided are methods of use and manufacture of such compounds.

    摘要翻译: 本公开提供了下式的化合物:Rf1 [CH(-O-CH(3-m)Rf2m)(-O-CF2-CFH-Rf3)] n [I],其中n为1或2,其中m 是1,2或3,其中当n为1时,Rf1选自直链,支链,环状或其组合的高度氟化的烷基,其可任选被取代,并且其可任选地含有 一个或多个连环杂原子; 其中当n为2时,R f1选自直链,支链,环状或其组合的高度氟化的亚烷基,其可以任选地被取代,并且可以任选地含有一个或多个链状杂原子; 其中每个Rf 2独立地选自直链,支链,环状或其组合的烷基,其可以任选地被取代,并且其可以任选地含有一个或多个连接的杂原子; 其中至少一个Rf 2是高度氟化的; 其中每个Rf 3独立地选自直链,支链,环状或其组合的氟和高度氟化的烷基,其可以任选地被取代,并且其可任选地含有一个或多个连接的杂原子。 还提供了使用和制造这些化合物的方法。

    HYDROFLUOROETHER AS A HEAT-TRANSFER FLUID
    10.
    发明申请
    HYDROFLUOROETHER AS A HEAT-TRANSFER FLUID 有权
    氢氟烃作为传热流体

    公开(公告)号:US20080245509A1

    公开(公告)日:2008-10-09

    申请号:US12119571

    申请日:2008-05-13

    IPC分类号: F28D15/00 C07C41/20

    CPC分类号: C07C43/126 C09K5/10

    摘要: The present invention provides an apparatus comprising a device and a mechanism for heat transfer comprising a hydrofluoroether heat-transfer fluid wherein the heat transfer fluid is represented by the following structure: Rf—O—Rh—O—Rf′ wherein O is oxygen; Rf and Rf′ are, independently, a fluoroaliphatic group, wherein each Rf and Rf′ contain 1 hydrogen atom; Rh is independently a linear, branched or cyclic alkylene group having from 2 to about 8 carbon atoms and at least 4 hydrogen atoms, and wherein the hydrofluoroether compound is free of —O—CH2—O—. Another embodiment of the present invention is a method therefor.

    摘要翻译: 本发明提供了一种包括装置和用于传热的机构的装置,其包括氢氟醚传热流体,其中传热流体由以下结构表示:<?在线公式描述=“在线公式”结束 =“lead”?> R 在线公式描述=“在线公式 “end =”tail“?>其中O是氧; R f和R f'独立地是氟代脂族基团,其中每个R f和R f' 含有1个氢原子; R h独立地是具有2至约8个碳原子和至少4个氢原子的直链,支链或环状亚烷基,其中所述氢氟醚化合物不含-O-CH 2 -O-。 本发明的另一个实施方案是其方法。