摘要:
An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li(2+2x)/(2+x)M′2x/(2+x)M(2−2x)/(2+x)O2−δ, in which 0≦x
摘要:
An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi2MnO3.(1−x)LiMn2-yMyO4 for 0.5
摘要:
Processes are provided for making dense, spherical mixed-metal carbonate or phosphate precursors that are particularly well suited for the production of active materials for electrochemical devices such as lithium ion secondary batteries. Exemplified methods include precipitating dense, spherical particles of metal carbonates or metal phosphates from a combined aqueous solution using a precipitating agent such as ammonium hydrogen carbonate, sodium hydrogen carbonate, or a mixture that includes sodium hydrogen carbonate. Other exemplified methods include precipitating dense, spherical particles of metal phosphates using a precipitating agent such as ammonium hydrogen phosphate, ammonium dihydrogen phosphate, sodium phosphate, sodium hydrogen phosphate, sodium dihydrogen phosphate, or a mixture of any two or more thereof. Further provided are compositions of and methods of making dense, spherical metal oxides and metal phosphates using the dense, spherical metal precursors. Still further provided are electrodes and batteries using the same.
摘要:
A number of materials with the composition Li1+xNiαMnβCoγM′δO2−zFz (M′=Mg, Zn, Al, Ga, B, Zr, Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, α is between about 0.2 and 0.6, β is between about 0.2 and 0.6, γ is between about 0 and 0.3, δ is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li1+xNiαCoβMnγM′δOyFz (M′=Mg, Zn, Al, Ga, B, Zr, Ti), where the x is between 0 and 0.2, the α between 0 and 1, the β between 0 and 1, the γ between 0 and 2, the δ between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.
摘要:
A positive electrode active material for lithium-ion rechargeable batteries of general formula Li1+xNiαMnβAγO2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0
摘要翻译:1.一种用于锂离子可再充电电池的正极活性材料,其通式为Li 1 + x Ni 2 O 3, 并且其中A是Mg,Zn,Al,Co,Ga,B,Zr或Ti,0
摘要:
An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi2−yHyO.xM′O2.(1−x)Li1−zHzMO2 in which 0
摘要:
Processes are provided for making dense, spherical mixed-metal carbonate or phosphate precursors that are particularly well suited for the production of active materials for electrochemical devices such as lithium ion secondary batteries. Exemplified methods include precipitating dense, spherical particles of metal carbonates or metal phosphates from a combined aqueous solution using a precipitating agent such as ammonium hydrogen carbonate, sodium hydrogen carbonate, or a mixture that includes sodium hydrogen carbonate. Other exemplified methods include precipitating dense, spherical particles of metal phosphates using a precipitating agent such as ammonium hydrogen phosphate, ammonium dihydrogen phosphate, sodium phosphate, sodium hydrogen phosphate, sodium dihydrogen phosphate, or a mixture of any two or more thereof. Further provided are compositions of and methods of making dense, spherical metal oxides and metal phosphates using the dense, spherical metal precursors. Still further provided are electrodes and batteries using the same.
摘要:
A number of materials with the composition Li1+xNiαMnβCoγM′δO2−zFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, α is between about 0.2 and 0.6, β is between about 0.2 and 0.6, γ is between about 0 and 0.3, δ is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li1+xNiαCoβMnγM′δOyFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the α between 0 and 1, the β between 0 and 1, the γ between 0 and 2, the δ between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.
摘要:
A number of materials with the composition Li1+xNiαMnβCoγM′δO2−zFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, α is between about 0.2 and 0.6, β is between about 0.2 and 0.6, γ is between about 0 and 0.3, δ is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li1+xNiαCoβMnγM′δOyFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the α between 0 and 1, the β between 0 and 1, the γ between 0 and 2, the δ between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.
摘要翻译:具有以下组成的多种材料:Li 1 + x Ni 2 O 3 N 2 N 2 C 1 N 2 (M'= Mg,Zn,Al,Ga,B,Zr,Ti),用于可再充电电池,其中 x在约0和0.3之间,α在约0.2和0.6之间,β在约0.2和0.6之间,γ在约0和0.3之间,δ在约0和0.15之间,z在约0和0.2之间。 添加上述金属和氟掺杂剂影响电化学循环期间层状氧化物结构的能力,阻抗和稳定性。 本发明的另一方面包括具有以下组成的材料:具有下式的材料:Li 1 + x Ni 2 O 3 M 1 M 2 M 2 M' (M'= Mg,Zn,Al,Ga,B,Zr,Ti),其中x在 0和0.2之间,α在0和1之间,β在0和1之间,γ在0和2之间,δ在约0和约0.2之间,y在2和4之间,z在0和0.5之间 。
摘要:
A number of materials with the composition Li1+xNiαMnβCoγM′δO2−zFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, α is between about 0.2 and 0.6, β is between about 0.2 and 0.6, γ is between about 0 and 0.3, δ is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling.
摘要翻译:具有以下组成的多种材料:Li 1 + x Ni 2 O 3 N 2 N 2 C 1 N 2 (M'= Mg,Zn,Al,Ga,B,Zr,Ti),用于可再充电电池,其中 x在约0和0.3之间,α在约0.2和0.6之间,β在约0.2和0.6之间,γ在约0和0.3之间,δ在约0和0.15之间,z在约0和0.2之间。 添加上述金属和氟掺杂剂影响电化学循环期间层状氧化物结构的容量,阻抗和稳定性。