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公开(公告)号：US5036111A
公开(公告)日：1991-07-30
申请号：US597666
申请日：1990-10-17
IPC分类号： C08G65/48 , C08G73/10 , C08J9/02 , C08L67/00 , C08L67/02 , C08L71/12 , C08L77/00 , C08L79/08 , C08L81/00 , C08L81/06
CPC分类号： C08J9/02 , C08G73/101 , C08L79/085 , C08J2379/08
摘要： Expanded material obtained by heating a composition comprising at least onehermosetting nadimide resin, said heating being performed at a temperature and during a period which are sufficient to cause the expansion of said composition by release of cyclopentadiene. A nadimide resin of the polyimide type and having a number average molecular weight of 600 to 10,000 is preferably used. The composition further comprises preferably 1% to 50% by weight of a linear, preferably thermostable polymer.
摘要翻译： 通过加热包含至少一种热固性nadimide树脂的组合物获得的膨胀材料，所述加热在足以通过释放环戊二烯而使所述组合物膨胀的温度和时间内进行。 优选使用数均分子量为600〜10000的聚酰亚胺型纳米二酰亚胺树脂。 组合物还优选包含1重量％至50重量％的线性，优选热稳定性聚合物。
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公开(公告)号：US4736015A
公开(公告)日：1988-04-05
申请号：US435153
申请日：1982-10-19
申请人： Guy Rabilloud , Michel Senneron , Choua Cohen , Paul Mariaggi , Bernard Sillion
发明人： Guy Rabilloud , Michel Senneron , Choua Cohen , Paul Mariaggi , Bernard Sillion
CPC分类号： C08G73/10
摘要： Aromatic polyimide compositions, useful in particular for manufacturing adhesive materials, varnishes and films withstanding high temperatures, having a high solubility in organic solvents, particularly polar solvents and which are manufactured by reacting, in such a solvent, a tetraester or diacid-diester of benzhydrol 3,3', 4, 4' tetracarboxylic acid with an aromatic diamine for a sufficient time to obtain a polycondensation reaction product having an inherent viscosity at 30.degree. C., at a concentration of 5 g/liter in N-methyl pyrrolidone, ranging from 0.1 to 2 dl/g.
摘要翻译： 芳族聚酰亚胺组合物，特别用于制造粘合剂材料，耐高温清漆和薄膜，在有机溶剂特别是极性溶剂中具有高溶解度，并且通过在这种溶剂中使二苯甲酮的四酯或二酸二酯 3,3'，4,4'-四羧酸与芳族二胺反应足够的时间，得到在30℃下的特性粘度，在N-甲基吡咯烷酮中浓度为5g /升的缩聚反应产物，其范围 为0.1〜2d / g。
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3.发明授权Oligomer compositions of polyaryloxypyridines with acetylenic end groups, their manufacture and lattices obtained by thermal polymerization thereof 失效具有炔末端基的聚芳氧基吡啶的低聚物组合物，其制备和通过其热聚合获得的晶格
公开(公告)号：US4814403A
公开(公告)日：1989-03-21
申请号：US105745
申请日：1987-10-08
IPC分类号： C07D213/63 , C07D213/64 , C07D213/643 , C07F7/08 , C08F38/00 , C08F290/00 , C08F299/00 , C08G65/40 , C08G65/48 , C08F26/06
CPC分类号： C07D213/643 , C07F7/0812 , C08G65/4006 , C08G65/48 , C08G2650/48 , C08G2650/60
摘要： Oligomer compositions of polyaryloxypyridine with acetylenic end groups arebtained by formation of an oligomer composition of polyaryloxypyridine with halogenated end groups from an alkaline diphenolate and a dihalogenopyridine, followed with an ethynylation reaction. The average polycondensation degree may range from 1 to 50. Theses compositions can be used to form cross-linked lattices by polyaddition of the ethynyl groups.
摘要翻译： 具有炔末端基的聚芳氧基吡啶的低聚物组成通过由碱式二酚盐和二卤代吡啶形成具有卤化端基的聚芳氧基吡啶的低聚物组合物，然后进行乙炔化反应而获得。 平均缩聚度可以在1至50之间。这些组合物可用于通过乙炔基的加成形成交联晶格。
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4.发明授权Process for synthesizing bis (phenylglyoxyloyl)benzenes usable for manufacturing polyphenylquinoxaline resins 失效合成可用于制备聚苯基喹喔啉树脂的双（苯基乙氧基羰基）苯的方法
公开(公告)号：US4310699A
公开(公告)日：1982-01-12
申请号：US152895
申请日：1980-05-23
申请人： Guy Rabilloud , Bernard Sillion
发明人： Guy Rabilloud , Bernard Sillion
IPC分类号： C07C49/83 , C07C45/00 , C07C45/29 , C07C49/784 , C07C67/00 , C08G6/00 , C08G73/06 , C07C45/45
CPC分类号： C08G73/0694 , C07C45/00 , C07C45/29 , C07C45/292 , C07C45/296 , C07C45/298 , C07C49/784 , C08G6/00
摘要： Bis (phenylglyoxyloyl) benzenes are manufactured by a method comprising the reaction of terephthalic or isophthalic aldehyde first with a low proportion of an alkali metal cyanide in a solvent, and then with benzaldehyde; the resultant product is oxidized to the desired bis (phenylglyoxyloyl) benzene.
摘要翻译： 双（苯基乙氧基）苯是通过包括在溶剂中首先与低比例的碱金属氰化物反应的对苯二甲酸或间苯二醛，然后与苯甲醛反应的方法制备的; 将所得产物氧化成所需的双（苯基乙氧基羰基）苯。
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公开(公告)号：US3968085A
公开(公告)日：1976-07-06
申请号：US501696
申请日：1974-08-29
申请人： Guy Rabilloud , Bernard Sillion
发明人： Guy Rabilloud , Bernard Sillion
IPC分类号： C08G63/685 , C08L63/00 , C08G17/14
CPC分类号： C08G63/6856 , C08L63/00 , Y10T428/31525
摘要： The invention concerns new aromatic polyamine compositions useful as hardening agents containing a major proportion of polyamines of the formula: ##EQU1## IN WHICH Ar and Ar' are divalent aromatic radicals having from 1 to 6 rings, R.sub.1 is a divalent hydrocarbon radical or a radical (R.sub.4 -O).sub.m R.sub.4, R.sub.4 being an alkylene and m an integer from 1 to 100.
摘要翻译： 本发明涉及可用作含有主要比例的下式的多胺的硬化剂的新型芳族多胺组合物：O OOO并行平行并行平行NH2-Ar-CO-R1-OC-Ar'-CO-R1-OC-Ar-NH2n 其中Ar和Ar'是具有1至6个环的二价芳族基团，R 1是二价烃基或基团（R 4 -O）m R 4，R 4是亚烷基，m是1至100的整数。
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公开(公告)号：US4143077A
公开(公告)日：1979-03-06
申请号：US831447
申请日：1977-09-08
申请人： Bernard Masson , Guy Rabilloud , Bernard Sillion
发明人： Bernard Masson , Guy Rabilloud , Bernard Sillion
IPC分类号： C07C17/12 , C07C41/00 , C07C43/263 , C07C67/00 , C10L1/02 , C10M105/18 , C10N40/08 , C07C43/20 , C10M1/20 , C10M3/14
CPC分类号： C10M105/18 , C07C17/12 , C10M2207/04 , C10N2240/08
摘要： New aromatic compounds with ether functions particularly useful as power transmission fluids and as lubricants withstanding high temperatures, containing at least a major proportion of a compound of the formula: ##STR1## WHEREIN EACH Ar is selected from phenyl and metaphenoxy phenyl and optionally a minor proportion of at least one compound selected from those complying with the general formulas: ##STR2## WHEREIN Ar is defined as above.
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公开(公告)号：US4045414A
公开(公告)日：1977-08-30
申请号：US643837
申请日：1975-12-23
申请人： Guy Rabilloud , Bernard Sillion
发明人： Guy Rabilloud , Bernard Sillion
CPC分类号： C07C45/43 , C07C45/28 , C07C45/46 , C08G73/0694
摘要： New tetracarbonyl compounds of the formulae: ##STR1## where R is a hydrogen atom, an alkyl radical or an aryl radical. The invention also contemplates the thermostable polymers obtained by reacting an aromatic tetra-amine with at least one of the above tetracarbonyl compounds.
摘要翻译： 新的具有下式的四羰基化合物：其中R是氢原子，烷基或芳基。 本发明还考虑通过使芳族四胺与至少一种上述四羰基化合物反应而获得的热稳定性聚合物。
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公开(公告)号：US5104968A
公开(公告)日：1992-04-14
申请号：US564236
申请日：1990-08-08
申请人： Serge Gonzalez , Paul Mariaggi , Guy Rabilloud , Bernard Sillion
发明人： Serge Gonzalez , Paul Mariaggi , Guy Rabilloud , Bernard Sillion
CPC分类号： C08G73/1003 , C08G73/1007 , C08G73/1042 , H01B3/306 , Y10T428/31504
摘要： Polyimide precursor compositions incorporating at least one compound of fula (1), at least one compound of formula (2), at least one compound of formula (3) and at least one compound of formula (4) ##STR1## in which one of the groups R.sup.3 and R.sup.4 represents a hydrogen atom and the other, in the same way as the groups R.sup.1 and R.sup.2, which can be the same or different, in each case represent a hydrocarbon group having 1 to 16 carbon atoms, m is a number between 5 and 20, n is an integer between 1 and 5 and R.sup.5 represents a hydrogen atom, a halogen atom, a hydrocarbon group with 1 to 16 carbon atoms, or a group of formula R.sup.6 --O-- in which R.sup.6 represents a hydrocarbon group having 1 to 16 carbon atoms. The preferred composition contains 30 to 70% by weight of dry matter of compounds of formulas (1), (2) and (3), in which the groups R.sup.1, R.sup.2 and one of the groups R.sup.3 and R.sup.4 is a methyl or ethyl group and the compound of formula (4) is benzyl alcohol. These compositions are usable as smoothing and/or protective coatings for metals, metal alloys or other substrates and in particular in the electrical and electronic industries, e.g. for the formation of dielectric films.
摘要翻译： 引入至少一种式（1）化合物，至少一种式（2）化合物，至少一种式（3）化合物和至少一种式（4）化合物的聚酰亚胺前体组合物 图像（2）
（3） （4）其中R3和R4中的一个代表氢原子，另一个与R1和R2基团相同，可以相同 或者不同，在每种情况下都表示具有1至16个碳原子的烃基，m是5至20之间的数，n是1和5之间的整数，R 5表示氢原子，卤素原子，具有1个 至16个碳原子的基团，或其中R 6表示具有1至16个碳原子的烃基的式R6-O-基团。 优选的组合物包含30至70重量％的式（1），（2）和（3）化合物的干物质，其中基团R 1，R 2和基团R 3和R 4中的一个是甲基或乙基 并且式（4）的化合物是苄醇。 这些组合物可用作金属，金属合金或其它基材的平滑和/或保护涂层，特别是在电气和电子工业中。 用于形成介电膜。 -
9.发明授权Compositions of polyaryloxypyridine oligomers with phthalonitrile end groups, their preparation and use for manufacturing polyaryloxypyridine co-phthalocyanine lattices 失效具有邻苯二甲腈端基的聚芳氧基吡啶低聚物的组成及其制备和用于制备聚芳氧基吡啶共酞菁晶格
公开(公告)号：US4764578A
公开(公告)日：1988-08-16
申请号：US907905
申请日：1986-09-16
申请人： Jean Malinge , Guy Rabilloud , Bernard Sillion
发明人： Jean Malinge , Guy Rabilloud , Bernard Sillion
CPC分类号： C08G65/48 , C08G65/4006 , C08G73/0627 , C08G2650/64
摘要： The disclosed compositions of polyaryloxypyridine oligomers with phthalonile end groups are obtained by formation of a composition of polyaryloxypyridine oligomers with alkali phenolate end groups, followed with the reaction of said composition with 4-nitrophthalonitrile. Their average polycondensation degree may range from 1 to 50. They can be used in combination with a co-reactant derived from benzhydrol and containing one or two ortho-dinitrile functional groups, to constitute polyaryloxypyridine co-polyphthalocyanine lattices.
摘要翻译： 所公开的具有邻苯二甲腈端基的聚芳氧基吡啶低聚物的组合物通过用碱性酚盐端基形成聚芳氧基吡啶低聚物的组合物，随后将所述组合物与4-硝基邻苯二腈反应而获得。 它们的平均缩聚度可以在1至50之间。它们可以与衍生自二苯甲醛并含有一个或两个邻二甲苯基官能团的共反应物组合使用，以构成聚芳氧基吡啶共聚酞菁晶格。
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10.发明授权Polyimide precursor compositions, their manufacture, the resultant polyimides and their use, particularly for manufacturing enamelling varnishes for electric wires 失效聚酰亚胺前体组合物，它们的制造，所得聚酰亚胺及其用途，特别用于制造用于电线的搪瓷清漆
公开(公告)号：US4720539A
公开(公告)日：1988-01-19
申请号：US920824
申请日：1986-09-10
申请人： Guy Rabilloud , Paul Marriagi , Serge Gonzales , Bernard Sillion
发明人： Guy Rabilloud , Paul Marriagi , Serge Gonzales , Bernard Sillion
CPC分类号： C08G73/1067 , C08G73/1042 , H01B3/306
摘要： Polyimide precursor compositions are described which may be prepared by rting a biprimary aromatic diamine with a diester-diacid or an aromatic tetraacid, and then with the substantially stoichiometrical complement of an aromatic dianhydride.The polyimide precursor compositions are used in the manufacture of insulating coatings, films, impregnating or enamelling varnishes for electric wires etc., and have excellent qualities of flexibility, adhesiveness and heat resistance.
摘要翻译： 描述了聚酰亚胺前体组合物，其可以通过使双原子芳族二胺与二酯 - 二酸或芳族四酸反应，然后与基本上化学计量的芳族二酐的补体反应来制备。 聚酰亚胺前体组合物用于制造用于电线等的绝缘涂料，薄膜，浸渍或搪瓷清漆，并且具有优异的柔韧性，粘合性和耐热性。
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