公开(公告)号：US06878801B2

公开(公告)日：2005-04-12

申请号：US10337845

申请日：2003-01-08

申请人： Michiya Fujiki ,  Hiroshi Nakashima ,  Julian R. Koe ,  Masao Morita ,  Hiromi Tamoto

发明人： Michiya Fujiki ,  Hiroshi Nakashima ,  Julian R. Koe ,  Masao Morita ,  Hiromi Tamoto

IPC分类号： C07D333/08 ,  C07D333/18 ,  C08G61/12 ,  C08G75/00 ,  C07D333/10

CPC分类号： C08G61/126 ,  C07D333/08 ,  C07D333/18

摘要： Novel polythiophenes which exhibit strong main chain absorption in the ultraviolet to visible region, show optical activity depending on the polymeric chain alone, and comprise as repeating units thiophene rings containing chiral substituent groups, and are represented by the following general formula: (wherein R1 and R2 are the same or different, each representing a hydrogen atom or an organic group, of which at least one is an enantiopure alkyl group with a branch structure at the β-position, and n represents the number of repeating units selected from 10 to 100,000).

摘要翻译： 在紫外至可见光区域显示出强的主链吸收性的新型聚噻吩显示光学活性，其取决于单独的聚合物链，并且包含作为重复单元含有手性取代基的噻吩环，并且由以下通式表示：（其中R1和 R2相同或不同，各自表示氢原子或有机基团，其中至少一个为具有在β-位上具有支链结构的对映体纯的烷基，n表示选自10至100,000的重复单元的数目 ）。

公开(公告)号：US5717051A

公开(公告)日：1998-02-10

申请号：US530409

申请日：1995-09-19

申请人： Toshiro Hiraoka ,  Yutaka Majima ,  Kenji Todori ,  Julian R. Koe ,  Yoshihiko Nakano ,  Shinji Murai ,  Shuzi Hayase

发明人： Toshiro Hiraoka ,  Yutaka Majima ,  Kenji Todori ,  Julian R. Koe ,  Yoshihiko Nakano ,  Shinji Murai ,  Shuzi Hayase

IPC分类号： C03C14/00 ,  C08G77/02 ,  C08G77/58 ,  C08G77/60 ,  C08G79/00

CPC分类号： C08G79/00 ,  C03C14/00 ,  C03C14/008 ,  C08G77/02 ,  C08G77/58 ,  C08G77/60 ,  C03C2214/12 ,  C03C2214/30 ,  Y10T428/31612

摘要： A glass composite material comprising a polymer chain selected from the group consisting of polysilane, polygermane, polystannane and a copolymer thereof, and a network structure of a metal oxide consisting of a metal atom bonded to the other metal atom through an oxygen atom, wherein the polymer chain is chemically crosslinked with a glass matrix of the network structure of the metal oxide directly or indirectly, and a volume resistivity measured by setting a ratio of a voltage to a film thickness at 10.sup.6 V/cm according to a disc plate electrode method is not more than 3.times.10.sup.6 .OMEGA.cm.

公开(公告)号：US5858541A

公开(公告)日：1999-01-12

申请号：US943792

申请日：1997-10-03

申请人： Toshiro Hiraoka ,  Yutaka Majima ,  Kenji Todori ,  Julian R. Koe ,  Yoshihiko Nakano ,  Shinji Murai ,  Shuzi Hayase

发明人： Toshiro Hiraoka ,  Yutaka Majima ,  Kenji Todori ,  Julian R. Koe ,  Yoshihiko Nakano ,  Shinji Murai ,  Shuzi Hayase

IPC分类号： C03C14/00 ,  C08G77/02 ,  C08G77/58 ,  C08G77/60 ,  C08G79/00 ,  B32B9/00

CPC分类号： C08G79/00 ,  C03C14/00 ,  C03C14/008 ,  C08G77/02 ,  C08G77/58 ,  C08G77/60 ,  C03C2214/12 ,  C03C2214/30 ,  Y10T428/31612

摘要： A glass composite material comprising a polymer chain selected from the group consisting of polysilane, polygermane, polystannane and a copolymer thereof, and a network structure of a metal oxide consisting of a metal atom bonded to the other metal atom through an oxygen atom, wherein the polymer chain is chemically crosslinked with a glass matrix of the network structure of the metal oxide directly or indirectly, and a volume resistivity measured by setting a ratio of a voltage to a film thickness at 10.sup.6 V/cm according to a disc plate electrode method is not more than 3.times.10.sup.6 .OMEGA.cm.

摘要翻译： 一种玻璃复合材料，其包含选自聚硅烷，聚锗烷，聚锡烷及其共聚物的聚合物链，以及由通过氧原子与另一个金属原子键合的金属原子构成的金属氧化物的网状结构，其中， 聚合物链直接或间接地与金属氧化物的网状结构的玻璃基体进行化学交联，并且通过根据盘片电极法将电压与膜厚比设定为106V / cm而测量的体积电阻率是 不超过3x106欧米加厘米。