公开(公告)号：US08969123B2

公开(公告)日：2015-03-03

申请号：US13580782

申请日：2011-02-24

申请人： Hiroaki Hayashi ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Shuzi Hayase ,  Taiichi Mure ,  Yasuhiro Shishida

发明人： Hiroaki Hayashi ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Shuzi Hayase ,  Taiichi Mure ,  Yasuhiro Shishida

IPC分类号： H01L31/18 ,  H01L51/48 ,  H01G9/20

CPC分类号： H01G9/2068 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/542 ,  Y02P70/521

摘要： In an apparatus for manufacturing a dye-sensitized solar cell, a photosensitization dye solution makes contact with an electrode material layer that functions as a working electrode of a dye-sensitized solar cell so that the photosensitizing dye is adsorbed on the layer. Such an apparatus for manufacturing a dye-sensitized solar cell has a substrate housing section to house a substrate with the electrode material layer formed on its surface, and a circulation mechanism to circulate the photosensitization dye solution in such a way that the solution passes a surface of the substrate housed in the substrate housing section. In such an apparatus, a cross-sectional area of a flow path for the photosensitization dye solution in a portion facing the substrate in the substrate housing section is set smaller than a cross-sectional area of a flow path for the photosensitization dye solution in other portions.

摘要翻译： 在染料敏化太阳能电池的制造装置中，光敏染料溶液与作为染料敏化太阳能电池的工作电极的电极材料层接触，使得光敏染料被吸附在该层上。 用于制造染料敏化太阳能电池的这种装置具有：基板容纳部，用于容纳其表面上形成有电极材料层的基板;以及循环机构，使光敏染料溶液循环使得溶液通过表面 的衬底容纳在衬底容纳部分中。 在这样的装置中，在基板容纳部中面向基板的部分中的光敏染料溶液的流路的截面积被设定为小于其他光敏染料溶液的流路的截面面积 部分。

公开(公告)号：US08637680B2

公开(公告)日：2014-01-28

申请号：US13255095

申请日：2010-03-10

申请人： Shuzi Hayase ,  Yoshihiro Yamaguchi ,  Shyam Sudhir Pandey

发明人： Shuzi Hayase ,  Yoshihiro Yamaguchi ,  Shyam Sudhir Pandey

IPC分类号： C07D209/02 ,  C07D209/04 ,  H01L31/042

CPC分类号： H01G9/2059 ,  C09B23/0066 ,  C09B57/007 ,  H01G9/2031 ,  H01L51/0064 ,  Y02E10/542 ,  Y02E10/549

摘要： Provided are a squarylium dye having a carboxyindolenine structure and an N-alkyl substituent, and a photoelectric conversion element having high photoelectric conversion efficiency in a near-infrared region and a dye-sensitized solar cell, both of which are produced using the squarylium dye. The photoelectric conversion element or dye-sensitized solar cell uses a compound represented by the formula (1) as the squarylium dye. In the formula (1), R1 and R2 represent a substituted or unsubstituted C5 to C30 alkyl group; X represents C(CH3)2; and A and B represent a carboxy group.

摘要翻译： 本发明提供了具有羧基吲哚宁结构和N-烷基取代基的方酸菁染料，以及在近红外区域和染料敏化太阳能电池中具有高光电转换效率的光电转换元件，它们均使用方酸菁染料制备。 光电转换元件或染料敏化太阳能电池使用由式（1）表示的化合物作为方酸菁染料。 在式（1）中，R 1和R 2表示取代或未取代的C 5至C 30烷基; X表示C（CH 3）2; A和B表示羧基。

公开(公告)号：US20120073643A1

公开(公告)日：2012-03-29

申请号：US13303326

申请日：2011-11-23

申请人： Shuzi HAYASE ,  Ryuichi SHIRATSUCHI ,  Suehiro OHKUBO ,  Yoshihiro YAMAGUCHI

发明人： Shuzi HAYASE ,  Ryuichi SHIRATSUCHI ,  Suehiro OHKUBO ,  Yoshihiro YAMAGUCHI

IPC分类号： H01L31/0224 ,  H01L31/18

CPC分类号： H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/542 ,  Y02P70/521

摘要： A dye-sensitized solar cell is provided, wherein it can be produced by a relatively easy and simple process and ensures high conversion efficiency even in cases where the thickness of the porous semiconductor layer is increased. The dye-sensitized solar cell 10 includes, in the interior of or on the conductive-substrate-side surface of the porous semiconductor layer 16, conductive metal film 20, such as a film of tungsten, having a large number of randomly located penetrations 24. Penetrations 24 of the conductive metal film 20 are formed by forming a fine-particle layer on the surface of the porous semiconductor layer, forming a conductive metal film on the surface of the fine-particle layer, and making the fine-particle layer disappear by heating or solvent-cleaning.

摘要翻译： 提供了一种染料敏化太阳能电池，其中其可以通过相对简单和简单的方法制造，并且即使在多孔半导体层的厚度增加的情况下也确保高转换效率。 染料敏化太阳能电池10在多孔半导体层16的内部或导电性基板侧表面上包括具有大量随机定位的穿透件24的导电金属膜20（例如钨膜） 通过在多孔半导体层的表面形成微粒层，在微粒层的表面形成导电性金属膜，使微粒层消失，形成导电性金属膜20的穿透部24 通过加热或溶剂清洗。

公开(公告)号：US20120048357A1

公开(公告)日：2012-03-01

申请号：US13036540

申请日：2011-02-28

申请人： Shuzi HAYASE ,  Shyam S. Pandey ,  Yoshihiro Yamaguchi

发明人： Shuzi HAYASE ,  Shyam S. Pandey ,  Yoshihiro Yamaguchi

IPC分类号： H01L31/06 ,  H01L51/44

CPC分类号： H01G9/2072 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0064 ,  Y02E10/542 ,  Y02P70/521

摘要： To provide a tandem dye-sensitized solar cell having a novel structure capable of improving the light absorption efficiency and being manufactured less expensively. A dye-sensitized solar cell 10 is configured by including, in order from the light incident side, an anode substrate 12, a first dye-carrying porous oxide semiconductor layer 14, a first electrolyte layer 16a, an electrolyte redox catalyst layer 18, a second dye-carrying porous oxide semiconductor layer 20, a porous support layer 19, a second electrolyte layer 16b, and a cathode substrate 22. The electrons extracted from a conductor layer 12b by a conductor are introduced into the cathode substrate 22, so that a battery circuit, for example, for a lighting power source is configured.

摘要翻译： 提供一种具有能够提高光吸收效率并且制造成本低的新型结构的串联染料敏化太阳能电池。 染料敏化太阳能电池10通过从光入射侧依次包括阳极基板12，第一染料负载多孔氧化物半导体层14，第一电解质层16a，电解质氧化还原催化剂层18， 第二染料负载多孔氧化物半导体层20，多孔支撑层19，第二电解质层16b和阴极衬底22.通过导体从导体层12b提取的电子被引入阴极衬底22中，使得 配置用于照明电源的电池电路。

公开(公告)号：US20120017974A1

公开(公告)日：2012-01-26

申请号：US13203456

申请日：2010-02-24

申请人： Hiroaki Hayashi ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Masato Takasaki ,  Shuzi Hayase

发明人： Hiroaki Hayashi ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Masato Takasaki ,  Shuzi Hayase

IPC分类号： H01L31/0216 ,  B05C5/00 ,  H01L31/18

CPC分类号： H01G9/2059 ,  H01G9/2031 ,  H01G9/2068 ,  Y02E10/542 ,  Y02P70/521

摘要： A method for adsorption of a photosensitizing dye includes adsorbing the photosensitizing dye to the layer of an electrode material that functions as the working electrode of a dye-sensitized solar cell, within a reaction vessel containing a solution of the photosensitizing dye, wherein a flow of the photosensitizing dye solution is generated by means of a flow generation part in a direction perpendicular to the electrode material layer, a direction parallel thereto or both, and the flow rate of the photosensitizing dye solution to the electrode material layer is higher than the diffusion velocity of the photosensitizing dye.

摘要翻译： 吸附光敏染料的方法包括在含有感光染料溶液的反应容器内将感光染料吸附到作为染料敏化太阳能电池的工作电极的电极材料层上，其中流过 光敏染料溶液是通过在垂直于电极材料层的方向上的流动产生部分，与其平行的方向或两者产生的，并且光敏染料溶液对电极材料层的流速高于扩散速度 的光敏染料。

公开(公告)号：US20100151616A1

公开(公告)日：2010-06-17

申请号：US12711694

申请日：2010-02-24

申请人： Ryuichi SHIRATSUCHI ,  Shuzi Hayase

发明人： Ryuichi SHIRATSUCHI ,  Shuzi Hayase

IPC分类号： H01L31/18 ,  H01L31/0224 ,  H01L31/04

CPC分类号： H01L31/022466 ,  H01G9/2031 ,  H01L31/1884 ,  Y02E10/542 ,  Y02P70/521

摘要： A dye-sensitized solar cell is provided that includes a transparent electrode formed by depositing, in order on a transparent substrate, a transparent conductive film containing tin oxide as a main component, and a compact titanium oxide layer and/or a porous titanium oxide layer, wherein the transparent conductive film, which contains tin oxide as the main component, has a fluorine concentration not exceeding 0.2 wt %, and the transparent conductive film on the transparent substrate has in an X-ray diffraction pattern thereof diffraction peaks attributable to (110), (200), and (211) planes satisfying the conditions that, relative to the sum of the diffraction intensities of the three planes, the ratios of both the (110) and (211) diffraction intensities are larger than 0.25 and smaller than 0.4, and the ratio of the (200) diffraction intensity is larger than 0.25 and smaller than 0.5. The dye-sensitized solar cell has high light conversion efficiency and has an FTO film that are highly heat resistant and does not easily deteriorate during a thermal treatment step when forming a titanium oxide porous film.

摘要翻译： 提供一种染料敏化太阳能电池，其包括通过在透明基板上依次沉积含有氧化锡作为主要成分的透明导电膜和紧密的氧化钛层和/或多孔氧化钛层而形成的透明电极 其中，含有氧化锡作为主要成分的透明导电膜的氟浓度不超过0.2重量％，透明基板上的透明导电膜的X射线衍射图可归因于（110 ），（200）和（211）面满足相对于三个平面的衍射强度之和的条件，（110）和（211）的衍射强度之比大于0.25且小于 （200）衍射强度的比例大于0.25且小于0.5。 染料敏化太阳能电池具有高的光转换效率，并且具有高耐热性并且在形成氧化钛多孔膜时在热处理步骤期间不容易劣化的FTO膜。

公开(公告)号：US5811497A

公开(公告)日：1998-09-22

申请号：US526327

申请日：1995-09-11

申请人： Shuzi Hayase ,  Yoshihiko Nakano ,  Shinji Murai ,  Yukihiro Mikogami

发明人： Shuzi Hayase ,  Yoshihiko Nakano ,  Shinji Murai ,  Yukihiro Mikogami

IPC分类号： C08G59/68 ,  C08G59/06 ,  C08G59/24

CPC分类号： C08G59/68 ,  C08G59/681

摘要： Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.

摘要翻译： 本文公开了包含至少一种化合物的固化催化剂，所述化合物是取代或未取代的芳族或杂芳族化合物，并且具有（I）-O-R 1，（II）-O-CY-R 1或（III） - O-CY-X-R1，其直接键合到铠装或杂芳族环上，其数量为1至10，其中R 1可以相同或不同，并且是具有1至20个碳原子的取代或未取代的烃基， X是O或NH，Y是O或S.此外，公开了包含固化催化剂的环氧树脂组合物。

公开(公告)号：US5705540A

公开(公告)日：1998-01-06

申请号：US781852

申请日：1997-01-10

申请人： Ken Uchida ,  Yasuyuki Hotta ,  Shuzi Hayase

发明人： Ken Uchida ,  Yasuyuki Hotta ,  Shuzi Hayase

IPC分类号： B29B15/10 ,  C08K9/06 ,  C09C1/30 ,  C09C3/12 ,  C08K9/10

CPC分类号： C08K9/06 ,  C08L63/00 ,  C09C1/3081 ,  C09C3/12 ,  B29K2105/16 ,  C01P2004/61

摘要： Disclosed is a resin composition excellent in mechanical and electrical properties. The composition contains an inorganic filler such as fused silica or silicon nitride having the surface covered with a substance resulting from decomposition of a polysilane compound and a base resin such as an epoxy resin or a maleimide resin.

摘要翻译： 公开了机械和电学性能优异的树脂组合物。 该组合物含有表面被聚硅烷化合物分解的物质和环氧树脂或马来酰亚胺树脂等基础树脂所覆盖的物质的熔融二氧化硅或氮化硅等无机填料。

公开(公告)号：US5063134A

公开(公告)日：1991-11-05

申请号：US455783

申请日：1990-01-02

申请人： Rumiko Horiguchi ,  Shuzi Hayase ,  Yasunobu Onishi

发明人： Rumiko Horiguchi ,  Shuzi Hayase ,  Yasunobu Onishi

IPC分类号： C08G8/06 ,  C08G8/28 ,  C09D161/04 ,  G03F7/075

CPC分类号： G03F7/0758 ,  C08G8/06 ,  C08G8/28 ,  C09D161/04

摘要： A photosensitive composition contains a polymer having a unit represented by formula I, and a photosensitive agent: ##STR1## wherein each of R.sub.1 to R.sub.4 represents a hydrogen atom, an alkyl group, an alkoxyl group, or a substituted or non-substituted allyl group, at least one of R.sub.1 to R.sub.4 being an alkyl groups having 1 to 10 carbon atoms and containing silicon, l represents a positive integer, and each of a and b represents an integer from 1 to 3, and c represents an integer from 0 to 2, a+b+c not exceeding 4.

摘要翻译： 感光性组合物含有具有式I表示的单元的聚合物和光敏剂：其中R 1〜R 4各自表示氢原子，烷基，烷氧基或取代或未取代的光敏剂， 取代的烯丙基，R 1至R 4中的至少一个为具有1至10个碳原子且含有硅的烷基，l表示正整数，a和b各自表示1至3的整数，c表示整数 从0到2，a + b + c不超过4。

公开(公告)号：US08754323B2

公开(公告)日：2014-06-17

申请号：US12304038

申请日：2007-06-21

申请人： Shuzi Hayase ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Yoshihiro Yamaguchi

发明人： Shuzi Hayase ,  Ryuichi Shiratsuchi ,  Suehiro Ohkubo ,  Yoshihiro Yamaguchi

IPC分类号： H01G9/20

CPC分类号： H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  Y02E10/542 ,  Y02P70/521

摘要： A dye-sensitized solar cell is provided, wherein it can be produced by a relatively easy and simple process and ensures high conversion efficiency even in cases where the thickness of the porous semiconductor layer is increased. The dye-sensitized solar cell 10 includes, in the interior of or on the conductive-substrate-side surface of the porous semiconductor layer 16, conductive metal film 20, such as a film of tungsten, having a large number of randomly located penetrations 24. Penetrations 24 of the conductive metal film 20 are formed by forming a fine-particle layer on the surface of the porous semiconductor layer, forming a conductive metal film on the surface of the fine-particle layer, and making the fine-particle layer disappear by heating or solvent-cleaning.

摘要翻译： 提供了一种染料敏化太阳能电池，其中其可以通过相对简单和简单的方法制造，并且即使在多孔半导体层的厚度增加的情况下也确保高转换效率。 染料敏化太阳能电池10在多孔半导体层16的内部或导电性基板侧表面上包括具有大量随机定位的穿透件24的导电金属膜20（例如钨膜） 通过在多孔半导体层的表面形成微粒层，在微粒层的表面形成导电性金属膜，使微粒层消失，形成导电性金属膜20的穿透部24 通过加热或溶剂清洗。