公开(公告)号：US5618783A

公开(公告)日：1997-04-08

申请号：US395994

申请日：1995-02-28

申请人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Ryuichi Akagi ,  Shu Yamaguchi ,  Masaki Tsumadori

发明人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Ryuichi Akagi ,  Shu Yamaguchi ,  Masaki Tsumadori

IPC分类号： B01J39/14 ,  C01B33/36 ,  C11D3/12 ,  C11D7/02 ,  C11D7/14

CPC分类号： B01J39/14 ,  C01B33/36 ,  C11D3/1246

摘要： The synthesized inorganic crystalline ion exchange material has a composition represented by the following general formula in an anhydride form:aX.sub.2 O.bSiO.sub.2.cX'O,wherein X represents Na and K; X' represents Ca, or Ca and Mg; b/a is 1.4 to 2.1; c/a is 0.001 to 0.35; K/Na in X.sub.2 O is 0.09 to 1.11; Mg/Ca in X'O is 0 to 100; and K.sub.2 O/SiO.sub.2 is 0.06 to 0.25. The synthesized inorganic crystalline ion exchange material exhibits main shift peaks at least at 1080.+-.6 cm.sup.-1 in Raman scattering spectra in the range of from 900 to 1200 cm.sup.-1. The inorganic ion exchange material of the present invention is excellent in cationic exchange capacity, cationic exchange speed, and anti-solubility, making it useful to be used for a water softener and an alkalinity adjusting agent in detergents.

摘要翻译： 合成的无机结晶离子交换材料具有由以下通式表示的组成，其为酸酐形式：aX2O.bSiO2.cX'O，其中X表示Na和K; X'表示Ca或Ca和Mg; b / a为1.4〜2.1; c / a为0.001〜0.35; X2O中的K / Na为0.09〜1.11; X'O中的Mg / Ca为0〜100; K2O / SiO2为0.06〜0.25。 合成的无机结晶离子交换材料在900-1200cm -1范围内的拉曼散射光谱中至少在1080 +/- 6cm -1处显示出主要的偏移峰。 本发明的无机离子交换材料的阳离子交换能力，阳离子交换速度，抗溶解性优异，可用于洗涤剂中的软水剂和碱性调节剂。

公开(公告)号：US5427711A

公开(公告)日：1995-06-27

申请号：US246711

申请日：1994-05-20

申请人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

发明人： Mikio Sakaguchi ,  Ichiro Sakamoto ,  Mutsumi Kuroda ,  Masaki Tsumadori ,  Motomitsu Hasumi ,  Yuichi Sakamoto ,  Ryuichi Akagi ,  Fumio Sai

IPC分类号： B01J39/08 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/12 ,  C11D3/386 ,  C01B33/24 ,  C01B33/32 ,  C11D7/02

CPC分类号： C11D3/38636 ,  B01J39/085 ,  B01J39/14 ,  C01B33/20 ,  C01B33/36 ,  C11D3/1246 ,  C11D3/126

摘要： The synthesized crystalline ion exchange material or a hydrate thereof has a chain structure and a composition represented by the following general formula (A) in an anhydride form:xM.sub.2 O.ySiO.sub.2.zM'O, (A)wherein M represents Na and/or K; M' represents Ca and/or Mg; y/x is 0.5 to 2.0; and z/x is 0.005 to 1.0. The chain structure exhibits at least one main scattering peak at 970.+-.20 cm.sup.-1 in Raman spectra. The detergent composition contains the above synthesized inorganic crystalline ion exchange material. The inorganic ion exchange material of the present invention is excellent in both cationic exchange capacity and anti-solubility, making it useful to be used for a water softener and alkalinity regulator in detergents. The detergent composition of the present invention contains an inorganic ion exchange material which has anti-solubility as well as excellent ion exchange capacity and alkaline capacity, thereby offering excellent washing effects and is suitable for the concentration of detergent.

摘要翻译： 合成的结晶离子交换材料或其水合物具有以下通式（A）表示的链状结构和酸酐形式的组成：xM2O.ySiO2.zM'O，（A）其中M表示Na和/或K ; M'表示Ca和/或Mg; y / x为0.5〜2.0; z / x为0.005〜1.0。 该链结构在拉曼光谱中显示出970 +/- 20cm-1处的至少一个主散射峰。 洗涤剂组合物含有上述合成的无机结晶离子交换材料。 本发明的无机离子交换材料的阳离子交换容量和抗溶解性均优异，因此可用于洗涤剂中的软水剂和碱度调节剂。 本发明的洗涤剂组合物含有具有抗溶解性以及优异的离子交换容量和碱性能的无机离子交换材料，从而提供优异的洗涤效果，适用于洗涤剂的浓缩。

公开(公告)号：US06211141B1

公开(公告)日：2001-04-03

申请号：US09101510

申请日：1998-07-13

申请人： Shu Yamaguchi ,  Hiromitsu Hayashi ,  Masaki Tsumadori ,  Masaaki Yamamura ,  Noboru Moriyama

发明人： Shu Yamaguchi ,  Hiromitsu Hayashi ,  Masaki Tsumadori ,  Masaaki Yamamura ,  Noboru Moriyama

IPC分类号： C11D183

CPC分类号： C11D17/065 ,  C11D1/04 ,  C11D1/146 ,  C11D1/22 ,  C11D1/72 ,  C11D1/83 ,  C11D3/128 ,  C11D3/33

摘要： A high-density powdered detergent composition which has a bulk density of 0.6 to 1.2 g/ml and which comprises 0.5 to 30% by weight of (a) a glycine-N,N-diacetic acid derivative, 5 to 45% by weight of (b) a nonionic surfactant having an HLB value of 10.5 to 15.0, 0.5 to 18% by weight of (c) an anionic surfactant and 1 to 30% by weight of (d) an aluminosilicate, each percentage being based on the total weight of the composition, and the weight ratio of the component (b) to the component (c) lying between 90:1 and 60:40. This composition contains both a glycine-N,N-diacetic acid derivative which is a builder excellent in biodegradability and sequestering power and an inorganic builder such as zeolite or crystalline silicate, and exhibits high detergency.

摘要翻译： 一种高密度粉末状洗涤剂组合物，其堆积密度为0.6〜1.2g / ml，含有0.5〜30重量％的（a）甘氨酸-N，N-二乙酸衍生物，5〜45重量％ （b）HLB值为10.5〜15.0，0.5〜18重量％（c）阴离子表面活性剂和1〜30重量％（d）铝硅酸盐的非离子性表面活性剂，各自以总重量计 的组分，和组分（b）与组分（c）的重量比在90:1和60:40之间。 该组合物含有作为生物降解性和螯合能力优异的助洗剂的甘氨酸-N，N-二乙酸衍生物和沸石或结晶性硅酸盐等无机助洗剂，并且显示出高洗涤性。

公开(公告)号：US5980580A

公开(公告)日：1999-11-09

申请号：US817999

申请日：1997-05-01

申请人： Shu Yamaguchi ,  Katsuhiko Kasai ,  Yoko Yamaguchi ,  Shigeru Tamura ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Katsuhiko Kasai ,  Yoko Yamaguchi ,  Shigeru Tamura ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D3/08 ,  C11D3/10 ,  C11D3/12 ,  C11D11/00 ,  C11D17/00 ,  D06L1/16

CPC分类号： C11D3/08 ,  C11D11/0017 ,  C11D17/0039 ,  C11D3/10 ,  C11D3/126

摘要： A washing method characterized in that washing is carried out under conditions that a pH of a washing liquid starts increasing after a water hardness of the washing liquid starts decreasing; a detergent composition characterized by containing particles capable of delayed-exerting an alkalizing effect of a washing liquid, wherein a pH of a washing liquid starts increasing after a water hardness of the washing liquid starts decreasing; and a detergent composition comprising an alkalizing agent coated with an organic material, or organic and inorganic materials, the alkalizing agent occupying an amount of 70% by weight or more of the entire alkalizing agents in the detergent composition. In the washing method and the detergent composition of the present invention, since washing is carried out under conditions that a pH of a washing liquid starts increasing after a water hardness of the washing liquid starts decreasing, excellent detergency can be achieved even at a low surfactant concentration in a washing liquid.

摘要翻译： PCT No.PCT / JP96 / 02485第 371日期1997年5月1日 102（e）日期1997年5月1日PCT PCT 1996年9月2日PCT公布。 公开号WO97 / 09414 日期1997年3月13日一种洗涤方法，其特征在于，在洗涤液的水硬度开始下降后，洗涤液的pH开始增加的条件下进行洗涤; 一种洗涤剂组合物，其特征在于含有能够延迟施用洗涤液的碱化效果的颗粒，其中在洗涤液的水硬度开始降低之后，洗涤液的pH开始增加; 以及包含涂覆有机材料的碱化剂或有机和无机材料的洗涤剂组合物，所述碱化剂占所述洗涤剂组合物中的全部碱化剂的70重量％以上。 在本发明的洗涤方法和洗涤剂组合物中，由于在洗涤液的水硬度开始下降后，在洗涤液的pH开始增加的条件下进行洗涤，即使在低表面活性剂 在洗涤液中的浓度。

公开(公告)号：USRE38411E1

公开(公告)日：2004-02-03

申请号：US09970688

申请日：2001-10-05

申请人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D308

CPC分类号： C11D3/128 ,  C11D3/126 ,  C11D3/1273 ,  C11D3/33 ,  C11D3/361 ,  C11D3/364 ,  C11D3/365 ,  C11D3/3761 ,  C11D11/0017

摘要： A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5° DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.

公开(公告)号：US6114297A

公开(公告)日：2000-09-05

申请号：US142433

申请日：1998-09-09

申请人： Shu Yamaguchi ,  Hitoshi Tanimoto ,  Masaki Tsumadori

发明人： Shu Yamaguchi ,  Hitoshi Tanimoto ,  Masaki Tsumadori

IPC分类号： C11D1/14 ,  C11D1/22 ,  C11D1/37 ,  C11D1/66 ,  C11D1/83 ,  C11D3/08 ,  C11D3/12 ,  C11D17/06 ,  C11D17/00

CPC分类号： C11D1/37 ,  C11D1/83 ,  C11D17/065 ,  C11D3/08 ,  C11D3/1273 ,  C11D1/146 ,  C11D1/22 ,  C11D1/66

摘要： The detergent composition for clothes washing includes (I) surfactant components including:A) one or more sulfonate-type anionic surfactants; and B) at least one of nonionic surfactants and sulfate-type anionic surfactants, wherein a weight ratio of Component B to Component A is B/A=1/10 to 2/1; and(II) components including:C) one or more alkali metal silicates; and D) one or more metal ion capturing agents other than component C), wherein a weight ratio of Component C to Component D is C/D=1/15 to 5/1. Here, a total amount of the components (I) is from 20 to 50% by weight, and a total amount of the components (II) is from 30 to 80% by weight, and the detergent composition has a bulk density of 0.6 g/cc or more.

摘要翻译： PCT No.PCT / JP97 / 00750 Sec。 371 1998年9月9日第 102（e）1998年9月9日PCT 1997年3月10日PCT公布。 公开号WO97 / 33969 日本1997年9月18日洗涤用洗涤剂组合物包括（I）表面活性剂组分，包括：A）一种或多种磺酸盐型阴离子表面活性剂; 和B）至少一种非离子表面活性剂和硫酸盐型阴离子表面活性剂，其中组分B与组分A的重量比为B / A = 1/10〜2/1; 和（II）组分，包括：C）一种或多种碱金属硅酸盐; 和D）组分C）以外的一种或多种金属离子捕获剂，其中组分C与组分D的重量比为C / D = 1/15〜5/1。 这里，组分（I）的总量为20至50重量％，组分（II）的总量为30至80重量％，洗涤剂组合物的堆积密度为0.6g / cc或更多。

公开(公告)号：US5961662A

公开(公告)日：1999-10-05

申请号：US793870

申请日：1997-03-11

申请人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Noriaki Ushio ,  Akiko Ishikura ,  Katsuhiko Kasai ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D3/08 ,  C11D3/12 ,  C11D3/33 ,  C11D3/36 ,  C11D3/37

CPC分类号： C11D3/365 ,  C11D3/08 ,  C11D3/126 ,  C11D3/1273 ,  C11D3/128 ,  C11D3/33 ,  C11D3/361 ,  C11D3/364 ,  C11D3/3761

摘要： A washing method is described which has excellent washing power and a low surfactant concentration. The described clothes washing method comprises the use of a phosphorus-free clothes detergent composition comprising (a) one or more surfactants, (b) one or more alkali metal silicates, and (c) one or more metal ion capturing agents other than the alkali metal silicate (b). The above detergent composition is added to water in an amount sufficient to produce a washing liquid having the following washing conditions (1) a pH of not less than 10.60; (2) containing a material having an ion capturing capacity in an amount sufficient for theoretically changing the water hardness of said water to be not more than 0.5.degree. DH; and (3) having a surfactant concentration of from 0.07 to 0.17 g/L.

摘要翻译： PCT No.PCT / JP95 / 01750 Sec。 371日期1997年3月10日 102（e）1997年3月10日PCT PCT 1995年9月1日PCT公布。 公开号WO96 / 08552 日期：1996年3月21日描述了具有优异洗涤力和低表面活性剂浓度的洗涤方法。 所描述的衣物洗涤方法包括使用无磷衣物洗涤剂组合物，其包含（a）一种或多种表面活性剂，（b）一种或多种碱金属硅酸盐，和（c）除碱之外的一种或多种金属离子捕获剂 金属硅酸盐（b）。 将上述洗涤剂组合物以足以产生具有以下洗涤条件的洗涤液的量加入到水中（1）pH不小于10.60; （2）含有足以使所述水的理论上将所述水的硬度变化为0.5℃以下的离子捕捉能力的材料; 和（3）表面活性剂浓度为0.07至0.17g / L。

公开(公告)号：US06214787B1

公开(公告)日：2001-04-10

申请号：US09142555

申请日：1998-09-11

申请人： Shu Yamaguchi ,  Shigeru Tamura ,  Futoshi Teranishi ,  Noriaki Ushio ,  Masaki Tsumadori ,  Hiroyuki Yamashita

发明人： Shu Yamaguchi ,  Shigeru Tamura ,  Futoshi Teranishi ,  Noriaki Ushio ,  Masaki Tsumadori ,  Hiroyuki Yamashita

IPC分类号： C11D308

CPC分类号： C11D3/046 ,  C11D3/08 ,  C11D3/1273 ,  C11D17/065

摘要： The granular detergent composition for clothes washing including a surfactant, a metal ion capturing agent, a crystalline alkali metal silicate, and an acidic ingredient, wherein the granular detergent composition includes at least two different granules: a first granule containing the crystalline alkali metal silicate, and a second granule, which is an acidic granule, containing the acidic ingredient. In the granular detergent composition, the crystalline alkali metal silicate and the acidic ingredient are being present in different granules, and the granular detergent composition shows alkaline property in distilled water at 25° C. and has a bulk density of 650 g/L or more. Since each of an acidic ingredient and a crystalline alkali metal silicate is included in a different granule, the initial rise in the pH at initial washing can be adjusted, so that a further improved detergency against the sebum dirt stains is exhibited.

摘要翻译： 包含表面活性剂，金属离子捕获剂，结晶性碱金属硅酸盐和酸性成分的衣物用洗涤剂组合物，其中所述颗粒状洗涤剂组合物包含至少两种不同的颗粒：含有结晶性碱金属硅酸盐的第一颗粒， 和含有酸性成分的酸性颗粒的第二颗粒。 在颗粒状洗涤剂组合物中，结晶性碱金属硅酸盐和酸性成分存在于不同的颗粒中，粒状洗涤剂组合物在25℃的蒸馏水中显示碱性，堆积密度为650g / L以上 由于酸性成分和结晶性碱金属硅酸盐中的每一种都包含在不同的颗粒中，因此可以调节初始洗涤时的pH的初始上升，从而显示出对皮脂污垢的去污力的进一步改善。

公开(公告)号：US6159919A

公开(公告)日：2000-12-12

申请号：US633698

申请日：1996-04-19

申请人： Shu Yamaguchi ,  Nobuyosi Yamaguchi ,  Muneo Aoyagi ,  Noriaki Ushio ,  Shigeru Tamura ,  Masaki Tsumadori

发明人： Shu Yamaguchi ,  Nobuyosi Yamaguchi ,  Muneo Aoyagi ,  Noriaki Ushio ,  Shigeru Tamura ,  Masaki Tsumadori

IPC分类号： C11D3/12 ,  C11D3/39 ,  C11D3/395

CPC分类号： C11D3/3907 ,  C11D3/1246 ,  C11D3/3942

摘要： The bleaching detergent composition in a form of granules or powders containing an organic peracid precursor which produces an organic peracid upon reaction with hydrogen peroxide in water, the organic peracid having an alkyl group with 7 to 19 carbon atoms, and a hydrogen peroxide releasing material, wherein the bleaching detergent composition comprises the following components a) to c): a) one or more surfactants; b) one or more crystalline alkali metal silicates; and c) one or more agents for capturing metal ions other than the crystalline alkali metal silicates b), wherein a total amount of the above a), b), and c) components in the bleaching detergent composition occupies from 70 to 99% by weight, and wherein the weight ratio of component b) to component a) is b/a=90/10 to 45/55, and the weight ratio of component b) to component c) is b/c=7/93 to 75/25, and wherein the weight ratio of the organic peracid precursor to nonionic surfactants used as component a) is from 10/90 to 70/30.

摘要翻译： 漂白洗涤剂组合物为颗粒或粉末形式，其含有有机过酸前体，其与水中的过氧化氢反应产生有机过酸，具有7至19个碳原子的烷基的有机过酸和过氧化氢释放物质， 其中所述漂白洗涤剂组合物包含以下组分a）至c）：a）一种或多种表面活性剂; b）一种或多种结晶碱金属硅酸盐; 和c）一种或多种用于捕获除结晶性碱金属硅酸盐b）之外的金属离子的试剂，其中漂白洗涤剂组合物中上述a），b）和c）组分的总量占70-99％ 成分b）与成分a）的重量比为b / a = 90/10〜45/55，成分b）与成分c）的重量比为b / c = 7/93〜75 / 25，其中有机过酸前体与用作组分a）的非离子表面活性剂的重量比为10/90至70/30。

公开(公告)号：US06521585B1

公开(公告)日：2003-02-18

申请号：US09068476

申请日：1998-05-06

申请人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

发明人： Hiroyuki Yamashita ,  Shu Yamaguchi ,  Teruo Kubota ,  Katsuhiko Kasai ,  Shigeru Tamura ,  Masaki Tsumadori

IPC分类号： C11D1100

CPC分类号： C11D3/08 ,  C11D1/04 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/72 ,  C11D1/83 ,  C11D3/1273 ,  C11D3/128 ,  C11D11/0082 ,  C11D11/04 ,  C11D17/065

摘要： Detergent formulations incorporating crystalline alkali metal silicate granules provide enhanced performance in removing sebum dirt stains at low dosages of detergent in the wash. The detergent formulations are prepared by combining an alkali metal silicate having a high pH value with a nonionic surfactant and an acid precursor of an anionic surfactant capable of having a lamellar orientation. The formulation is granulated by tumbling in an agitating mixer while increasing the bulk density at elevated temperatures to yield alkali metal silicate granules having a bulk density of from 0.6 to 1.2 g/ml.

摘要翻译： 掺入结晶碱金属硅酸盐颗粒的洗涤剂配方提供了在洗涤剂中低剂量洗涤剂中除去皮脂污垢的增强性能。 洗涤剂配方通过将具有高pH值的碱金属硅酸盐与非离子表面活性剂和能够具有层状取向性的阴离子表面活性剂的酸前体组合来制备。 通过在搅拌混合器中翻转而将制剂造粒，同时在升高的温度下增加堆积密度，得到体积密度为0.6至1.2g / ml的碱金属硅酸盐颗粒。