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    Process for the Preparation of Impact Resistant Propylene Polymer Compositions
    4.
    发明申请
    Process for the Preparation of Impact Resistant Propylene Polymer Compositions 有权
    制备耐冲击丙烯聚合物组合物的方法

    公开(公告)号：US20120083576A1

    公开(公告)日：2012-04-05

    申请号：US13376893

    申请日：2010-06-16

    申请人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    发明人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    IPC分类号： C08J3/00 ,  C08L23/24 ,  C08L23/20 ,  C08L23/16 ,  C08L23/12

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6494

    摘要： A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.

    摘要翻译： 一种制备丙烯聚合物组合物的方法，所述组合物在催化剂体系存在下进行，所述催化剂体系包含（a）平均粒度为15-80μm的固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为50-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚，（b） 烷基铝和任选的（c）外电子给体化合物，并包括以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触; （ii）每克固体催化剂组分（a）预聚合至约0.1至约1000g的聚合物的形成量; （iii）聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iv）在连续步骤中，在气相聚合乙烯混合物 其中R是具有1-10个碳原子的烃基的α-烯烃CH 2 = CHR，以制备所述乙烯共聚物。

    Process for the preparation of impact resistant propylene polymer compositions
    7.
    发明授权
    Process for the preparation of impact resistant propylene polymer compositions 有权
    制备耐冲击丙烯聚合物组合物的方法

    公开(公告)号：US09068028B2

    公开(公告)日：2015-06-30

    申请号：US13376893

    申请日：2010-06-16

    申请人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    发明人： Gianni Collina ,  Marco Ciarafoni ,  Ofelia Fusco ,  Benedetta Gaddi ,  Monica Galvan ,  Giampiero Morini ,  Roberto Pantaleoni ,  Francesca Verrocchio

    IPC分类号： C08F10/06 ,  C08F4/651 ,  C08F110/06

    CPC分类号： C08F10/06 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/001 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17 ,  C08F4/6494

    摘要： A process for the preparation of propylene polymer compositions carried out in the presence of a catalyst system comprising (a) a solid catalyst component having average particle size ranging from 15 to 80 μm comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 50 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum alkyl and optionally (c) an external electron donor compound, and comprising the following steps: (i) contacting the catalyst components (a), (b) and optionally (c); (ii) pre-polymerizing up to forming amounts of polymer from about 0.1 up to about 1000 g per gram of solid catalyst component (a); (iii) polymerizing propylene producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25° C. and (iv) in a successive step, carried out in gas-phase, polymerizing mixtures of ethylene with α-olefins CH2═CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce the said ethylene copolymer.

    摘要翻译： 一种制备丙烯聚合物组合物的方法，所述组合物在催化剂体系存在下进行，所述催化剂体系包含（a）平均粒度为15-80μm的固体催化剂组分，其包含卤化镁，至少具有Ti- 卤素键和至少两种电子给体化合物，其中一种以相对于供体总量为50-90％摩尔量存在，选自琥珀酸盐，另一种选自1,3-二醚，（b） 烷基铝和任选的（c）外电子给体化合物，并包括以下步骤：（i）使催化剂组分（a），（b）和任选的（c）接触; （ii）每克固体催化剂组分（a）预聚合至约0.1至约1000g的聚合物的形成量; （iii）聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iv）在连续步骤中，在气相聚合乙烯混合物 其中R是具有1-10个碳原子的烃基的α-烯烃CH 2 = CHR，以制备所述乙烯共聚物。

    Polyolefin compositions
    9.
    发明授权
    Polyolefin compositions 有权
    聚烯烃组合物

    公开(公告)号：US08569418B2

    公开(公告)日：2013-10-29

    申请号：US13378952

    申请日：2010-06-23

    申请人： Monica Galvan ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Angelo Ferraro

    发明人： Monica Galvan ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Angelo Ferraro

    IPC分类号： C08L23/04 ,  C08L23/10 ,  C08F8/00

    CPC分类号： C08J5/18 ,  C08J2323/10 ,  C08L23/0807 ,  C08L23/0815 ,  C08L23/10 ,  C08L2666/06

    摘要： Polyolefin compositions particularly suitable for cast film, exhibiting heat sealability, retortability, low haze and stiffness, comprising: 1) 75-85% of a propylene homopolymer or copolymer of propylene with ethylene and/or one or more C4-C10 α-olefin(s), the homopolymer or copolymer having melting temperature equal to or higher than 150° C., 2) 15-25% of a copolymer of ethylene with one or more C4-C10 α-olefin(s) containing from 20 to 30% of said C4-C10 α-olefin(s); said composition having MFR (at 230° C., 2.16 kg) of from 5-10 g/10 min, the total content of ethylene of from 10 to 20%, the total content of C4-C10 α-olefin(s) of from 2 to 8%, the ratio XStot/XSm of the total fraction soluble in Xylene at room temperature to the fraction soluble in Xylene at room temperature of the matrix component (1) of from 5 to 15, and the value of the intrinsic viscosity of the total fraction soluble in Xylene at room temperature (XSIVtot) of 1.5 dl/g or less.

    摘要翻译： 特别适用于流延膜的聚烯烃组合物，具有热封性，蒸煮性，低雾度和刚度，包括：1）75-85％的丙烯均聚物或丙烯与乙烯和/或一种或多种C 4 -C 10α-烯烃的共聚物 s），熔融温度等于或高于150℃的均聚物或共聚物，2）乙烯与一种或多种含有20-30％（重量）的C 4 -C 10α-烯烃的共聚物的15-25％ 的所述C 4 -C 10α-烯烃; 所述组合物的MFR（在230℃，2.16kg）为5-10g / 10min，乙烯的总含量为10至20％，C 4 -C 10α-烯烃的总含量为 2〜8％，室温下可溶于二甲苯的总馏分的比例XStot / XSm与基体成分（1）的室温下可溶于二甲苯的馏分的比例为5〜15，特性粘度 在室温下可溶于二甲苯的总馏分（XSIVtot）为1.5dl / g以下。

    Polyolefin Compositions
    10.
    发明申请
    Polyolefin Compositions 有权
    聚烯烃组合物

    公开(公告)号：US20120136121A1

    公开(公告)日：2012-05-31

    申请号：US13378952

    申请日：2010-06-23

    申请人： Monica Galvan ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Angelo Ferraro

    发明人： Monica Galvan ,  Marco Ciarafoni ,  Roberto Pantaleoni ,  Angelo Ferraro

    IPC分类号： C08L23/04

    CPC分类号： C08J5/18 ,  C08J2323/10 ,  C08L23/0807 ,  C08L23/0815 ,  C08L23/10 ,  C08L2666/06

    摘要： Polyolefin compositions particularly suitable for cast film, exhibiting heat sealability, retortability, low haze and stiffness, comprising: 1) 75-85% of a propylene homopolymer or copolymer of propylene with ethylene and/or one or more C4-C10 α-olefin(s), the homopolymer or copolymer having melting temperature equal to or higher than 150° C., 2) 15-25% of a copolymer of ethylene with one or more C4-C10 α-olefin(s) containing from 20 to 30% of said C4-C10 α-olefin(s); said composition having MFR (at 230° C., 2.16 kg) of from 5-10 g/10 min, the total content of ethylene of from 10 to 20%, the total content of C4-C10 α-olefin(s) of from 2 to 8%, the ratio XStot/XSm of the total fraction soluble in Xylene at room temperature to the fraction soluble in Xylene at room temperature of the matrix component (1) of from 5 to 15, and the value of the intrinsic viscosity of the total fraction soluble in Xylene at room temperature (XSIVtot) of 1.5 dl/g or less.

    摘要翻译： 特别适用于流延膜的聚烯烃组合物，具有热封性，蒸煮性，低雾度和刚度，包括：1）75-85％的丙烯均聚物或丙烯与乙烯和/或一种或多种C 4 -C 10α-烯烃的共聚物 s），熔融温度等于或高于150℃的均聚物或共聚物，2）乙烯与一种或多种含有20至30重量％的C 4 -C 10α-烯烃的共聚物的15-25％ 的所述C 4 -C 10α-烯烃; 所述组合物的MFR（在230℃，2.16kg）为5-10g / 10min，乙烯的总含量为10至20％，C 4 -C 10α-烯烃的总含量为 2〜8％，室温下可溶于二甲苯的总馏分的比例XStot / XSm与基体成分（1）的室温下可溶于二甲苯的馏分的比例为5〜15，特性粘度 在室温下可溶于二甲苯的总馏分（XSIVtot）为1.5dl / g以下。