Abstract:
Positive-working imageable elements can be imaged and developed to prepare imaged elements such as lithographic printing plates. The imageable elements including an imageable layer that has one or more alkaline soluble polymeric binders and a developability-enhancing compound that is represented by Structure (DEC) or (DEC1) described herein that are organic compounds having at least one amino group and at least one carboxylic acid group in each molecule.
Abstract:
Positive-working imageable elements having improved sensitivity, high resolution, and solvent resistance are prepared using a water-insoluble polymeric binder comprising vinyl acetal recurring units that have pendant hydroxyaryl groups, and recurring units comprising carboxylic acid aryl ester groups that are substituted with a cyclic imide group. These imageable elements can be imaged and developed to provide various types of elements including lithographic printing plates.
Abstract:
A method of making imaged elements such as lithographic printing plates is achieved by imagewise exposing a positive-working imageable element using energy of less than 300 mJ/cm2 to provide exposed and non-exposed regions. The imaged element is developed using an alkaline, silicate-free solution containing a carbonate to remove predominantly only the exposed regions to provide an image. The imageable element comprises a substrate and a radiation absorbing compound, and has an imageable layer on the substrate that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant nitro-substituted phenolic groups.
Abstract translation:通过使用小于300mJ / cm 2的能量的正性可成像元件成像曝光以提供曝光和未曝光区域,来实现诸如平版印刷版之类的成像元件的方法。 成像元件使用含有碳酸盐的碱性无硅酸盐溶液显影,主要仅去除曝光区域以提供图像。 可成像元件包括基材和辐射吸收化合物,并且在基材上具有可显影性增强化合物和聚(乙烯醇缩醛)的可成像层,其中至少25摩尔%的重复单元包括硝基取代的侧基 酚类。
Abstract:
A method of making imaged elements such as lithographic printing plates is achieved by imagewise exposing a positive-working imageable element using energy of less than 300 mJ/cm2 to provide exposed and non-exposed regions. The imaged element is developed using an alkaline, silicate-free solution containing a carbonate to remove predominantly only the exposed regions to provide an image. The imageable element comprises a substrate and a radiation absorbing compound, and has an imageable layer on the substrate that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant nitro-substituted phenolic groups.
Abstract translation:通过使用小于300mJ / cm 2的能量的正性可成像元件成像曝光以提供曝光和未曝光区域,来实现诸如平版印刷版之类的成像元件的方法。 成像元件使用含有碳酸盐的碱性无硅酸盐溶液显影,主要仅去除曝光区域以提供图像。 可成像元件包括基材和辐射吸收化合物,并且在基材上具有可显影性增强化合物和聚(乙烯醇缩醛)的可成像层,其中至少25摩尔%的重复单元包括硝基取代的侧基 酚类。
Abstract:
Positive-working imageable elements can be imaged and developed to prepare imaged elements such as lithographic printing plates. The imageable elements including an imageable layer that has one or more alkaline soluble polymeric binders and a developability-enhancing compound that is represented by Structure (DEC) or (DEC1) described herein that are organic compounds having at least one amino group and at least one carboxylic acid group in each molecule.
Abstract:
Positive-working imageable elements having improved sensitivity, high resolution, and solvent resistance are prepared using a water-insoluble polymeric binder comprising vinyl acetal recurring units that have pendant hydroxyaryl groups, and recurring units comprising carboxylic acid aryl ester groups that are substituted with a cyclic imide group. These imageable elements can be imaged and developed to provide various types of elements including lithographic printing plates.
Abstract:
Positive-working imageable elements can be imaged and processed using a processing solution that comprises at least 0.03 N of an organic amine or a mixture thereof, whose conjugated acids have a pKa greater than 9 and a boiling point greater than 150° C. The imageable element is a single-layer, infrared radiation-sensitive positive-working imageable element comprising a substrate and an infrared radiation absorbing compound. It also has an imageable layer that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant phenol, naphthol, or anthracenol groups that are substituted with one or more electron-withdrawing groups.
Abstract:
A method of making imaged elements such as lithographic printing plates is achieved by imagewise exposing an infrared radiation-sensitive positive-working imageable element to provide exposed and non-exposed regions. The imaged element is developed using a single processing solution having a pH of from about 9 to about 11.5 and containing carbonate ion and at least 1 weight % of one or more anionic surfactants, to remove predominantly only the exposed regions to provide an image and to provide a protective coating on the imaged surface. The imageable element comprises a substrate and a radiation absorbing compound, and has an imageable layer on the substrate that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant nitro-substituted phenolic groups.
Abstract:
Positive-working imageable elements can be imaged and processed using a processing solution that comprises at least 0.03 N of an organic amine or a mixture thereof, whose conjugated acids have a pKa greater than 9 and a boiling point greater than 150° C. The imageable element is a single-layer, infrared radiation-sensitive positive-working imageable element comprising a substrate and an infrared radiation absorbing compound. It also has an imageable layer that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant phenol, naphthol, or anthracenol groups that are substituted with one or more electron-withdrawing groups.
Abstract:
A method of making imaged elements such as lithographic printing plates is achieved by imagewise exposing an infrared radiation-sensitive positive-working imageable element to provide exposed and non-exposed regions. The imaged element is developed using a single processing solution having a pH of from about 9 to about 11.5 and containing carbonate ion and at least 1 weight % of one or more anionic surfactants, to remove predominantly only the exposed regions to provide an image and to provide a protective coating on the imaged surface. The imageable element comprises a substrate and a radiation absorbing compound, and has an imageable layer on the substrate that comprises a developability-enhancing compound and a poly(vinyl acetal) in which at least 25 mol % of its recurring units comprise pendant nitro-substituted phenolic groups.