公开(公告)号：US20060084747A1

公开(公告)日：2006-04-20

申请号：US11245200

申请日：2005-10-07

申请人： Motoki Asahara ,  Toshiki Nishino

发明人： Motoki Asahara ,  Toshiki Nishino

IPC分类号： C08K3/34 ,  C08K3/40

CPC分类号： C08G63/78 ,  C08G63/065 ,  C08G63/19 ,  C08G63/605

摘要： The present invention provides a method for manufacturing a wholly aromatic liquid-crystalline polyester resin comprising the steps of: 1) acylating the hydroxy group of major monomer components selected from the group consisting of aromatic hydroxycarboxylic acid, aromatic diol and aromatic dicarboxylic acid, with an acylating agent, provided that said major monomer components comprise at least one of aromatic hydroxycarboxylic acid and aromatic diol; and 2) polycondensing said major monomer components of which hydroxy group is acylated, wherein, the polycondensation reaction is carried out in the presence of a metal dihydrogen phosphate in an amount of 1-5000 ppm based on the total monomer components, and a liquid-crystalline polyester resin manufactured by the method and a composition comprising said resin.

摘要翻译： 本发明提供一种全芳香族液晶聚酯树脂的制造方法，包括以下步骤：1）将选自芳族羟基羧酸，芳族二醇和芳族二羧酸的主要单体成分的羟基与 所述主要单体组分包含芳族羟基羧酸和芳族二醇中的至少一种; 和2）缩聚其羟基被酰化的所述主要单体成分，其中缩聚反应在磷酸金属盐存在下以基于总单体组分的1-5000ppm的量存在下进行， 通过该方法制造的结晶性聚酯树脂和包含所述树脂的组合物。

公开(公告)号：US07335318B2

公开(公告)日：2008-02-26

申请号：US11245200

申请日：2005-10-07

申请人： Motoki Asahara ,  Toshiki Nishino

发明人： Motoki Asahara ,  Toshiki Nishino

IPC分类号： C09K19/52 ,  C09K19/20 ,  C09K19/38 ,  C08G63/181 ,  C08G63/191 ,  C08L67/00

CPC分类号： C08G63/78 ,  C08G63/065 ,  C08G63/19 ,  C08G63/605

摘要： The present invention provides a method for manufacturing a wholly aromatic liquid-crystalline polyester resin comprising the steps of: 1) acylating the hydroxy group of major monomer components selected from the group consisting of aromatic hydroxycarboxylic acid, aromatic diol and aromatic dicarboxylic acid, with an acylating agent, provided that said major monomer components comprise at least one of aromatic hydroxycarboxylic acid and aromatic diol; and 2) polycondensing said major monomer components of which hydroxy group is acylated, wherein, the polycondensation reaction is carried out in the presence of a metal dihydrogen phosphate in an amount of 1-5000 ppm based on the total monomer components, and a liquid-crystalline polyester resin manufactured by the method and a composition comprising said resin.

摘要翻译： 本发明提供一种全芳香族液晶聚酯树脂的制造方法，包括以下步骤：1）将选自芳族羟基羧酸，芳族二醇和芳族二羧酸的主要单体成分的羟基与 所述主要单体组分包含芳族羟基羧酸和芳族二醇中的至少一种; 和2）缩聚其羟基被酰化的所述主要单体成分，其中缩聚反应在磷酸金属盐存在下以基于总单体组分的1-5000ppm的量存在下进行， 通过该方法制造的结晶性聚酯树脂和包含所述树脂的组合物。