Abstract:
The present invention provides a cathode mixture that can be suitably used in a cathode mixture layer of an all-solid-state lithium-sulfur battery having an excellent charge/discharge capacity and a method of producing the cathode mixture, by maximally utilizing excellent physical properties of sulfur. The present invention relates to a positive electrode mixture for composite all-solid-state lithium-sulfur batteries, the positive electrode mixture containing sulfur or its discharge product (A); phosphorus pentasulfide (B); conductive carbon (C); and lithium halide (D) at a weight ratio of A:B:C:D of 40-60:15-35:5-20:16-30, wherein a peak at 50 ppm in 31P-MAS NMR has a relative intensity of 40% or less.
Abstract:
The present invention aims to maximize the advantageous physical properties of sulfur and provide a cathode mixture that can be suitably used in a cathode mixture layer of an all-solid-state sodium-sulfur battery in which charge/discharge capacity can be ensured even during operation at normal temperature. The present invention also aims to provide an all-solid-state sodium-sulfur battery including a cathode mixture layer containing the cathode mixture. The present invention relates to a cathode mixture for use in a cathode mixture layer of an all-solid-state sodium-sulfur battery, the cathode mixture including the following components (A) to (C): (A) an ion-conductive material containing phosphorus at a weight ratio of 0.2 to 0.55; (B) sulfur and/or its discharge product; and (C) a conductive material, the component (C) containing a conductive material (C1) having a specific surface area of 1000 m2/g or more.
Abstract:
The present invention aims to maximize the advantageous physical properties of sulfur and provide a cathode mixture that can be suitably used in a cathode mixture layer of an all-solid-state lithium-sulfur battery having excellent charge/discharge capacity. The present invention also aims to provide an all-solid-state lithium-sulfur battery including a cathode mixture layer containing the cathode mixture. The present invention relates to a cathode mixture for use in a cathode mixture layer of an all-solid-state lithium-sulfur battery, the cathode mixture containing the following components (A) to (D): (A) sulfur and/or its discharge product; (B) elemental phosphorus and/or PxSy where x and y independently represent an integer that gives a stoichiometric ratio; (C) an ion-conductive material; and (D) a conductive material.
Abstract:
The present invention aims to maximize the advantageous physical properties of sulfur and provide a cathode mixture that can be suitably used in a cathode mixture layer of an all-solid-state lithium sulfur battery exhibiting excellent charge/discharge capacity. The present invention also aims to provide an all-solid-state lithium sulfur battery including a cathode mixture layer containing the cathode mixture. The present invention provides a cathode mixture for use in a cathode mixture layer of an all-solid-state lithium sulfur battery, the cathode mixture containing: (A) an ion-conductive material containing phosphorus at a weight ratio of 0.2 to 0.55; (B) sulfur and/or its discharge product (B); and (C) a conductive material, the amount of the component (B) being 40% by weight or more of the total amount of the components (A), (B), and (C).