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公开(公告)号:US20160265085A1
公开(公告)日:2016-09-15
申请号:US15031746
申请日:2014-10-23
Applicant: NEMASKA LITHIUM INC.
Inventor: Guy BOURASSA , Gary PEARSE , Stephen Charles MACKIE , Mykolas GLADKOVAS , Peter SYMONS , David J. GENDERS , Jean-Frangois MAGNAN , Geneviève CLAYTON
CPC classification number: C22B26/12 , B01D61/422 , B01D61/445 , B01D2311/2684 , C01B2203/0283 , C01D7/07 , C22B3/44 , C22B4/02 , C25B1/14 , C25B1/16 , C25B9/08 , C25B9/18 , Y02E60/366
Abstract: There are provided processes comprising submitting an aqueous composition comprising lithium sulphate and/or bisulfate to an electrolysis or an electrodialysis for converting at least a portion of said sulphate into lithium hydroxide. During electrolysis or electrodialysis, the aqueous composition is at least substantially maintained at a pH having a value of about 1 to about 4; and converting said lithium hydroxide into lithium carbonate. Alternatively, lithium sulfate and/or lithium bisulfate can be submitted to a first electromembrane process that comprises a two-compartment membrane process for conversion of lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting said first lithium-reduced aqueous stream to a second electromembrane process comprising a three-compartment membrane process to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream.
Abstract translation: 提供的方法包括将包含硫酸锂和/或硫酸氢盐的含水组合物递送到电解或电渗析中,以将至少一部分所述硫酸盐转化为氢氧化锂。 在电解或电渗析期间,水性组合物至少基本上保持在pH为约1至约4的pH; 并将所述氢氧化锂转化为碳酸锂。 或者,硫酸锂和/或硫酸氢锂可以进行第一电子过程,其包括用于将硫酸锂和/或硫酸氢锂转化为氢氧化锂的双室膜工艺,并获得第一锂还原水流和 第一个富含氢氧化锂的水流; 以及将所述第一锂还原水流提交到包括三室膜方法的第二电解方法中,以制备至少另一部分氢氧化锂并获得第二锂还原水流和第二富含氢氧化锂的水流。
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公开(公告)号:US20160258071A1
公开(公告)日:2016-09-08
申请号:US15031589
申请日:2014-10-23
Applicant: NEMASKA LITHIUM INC.
Inventor: Jean-François MAGNAN , Guy BOURASSA , Gary PEARSE , Peter SYMONS , David J. GENDERS , Geneviève CLAYTON
CPC classification number: C25B1/16 , B01D61/422 , B01D2311/2684 , C25B9/08 , C25B9/18
Abstract: There are provided processes for preparing lithium hydroxide. The processes comprise submitting an aqueous composition comprising lithium sulfate and/or lithium bisulfate to a first electromembrane process that comprises a two-compartment membrane process under suitable conditions for conversion of the lithium sulfate and/or lithium bisulfate to lithium hydroxide, and obtaining a first lithium-reduced aqueous stream and a first lithium hydroxide-enriched aqueous stream; and submitting the first lithium-reduced aqueous stream to a second electromembrane process that comprises a three-compartment membrane process under suitable conditions to prepare at least a further portion of lithium hydroxide and obtaining a second lithium-reduced aqueous stream and a second lithium-hydroxide enriched aqueous stream. There are also provided systems for preparing lithium hydroxide.
Abstract translation: 提供了制备氢氧化锂的方法。 所述方法包括将包含硫酸锂和/或硫酸氢锂的水性组合物提交到第一电子过程中,所述第一电子过程包括在用于将硫酸锂和/或硫酸氢锂转化为氢氧化锂的合适条件下的双室膜工艺,并获得第一 锂还原水流和第一富含氢氧化锂的水流; 以及将第一锂还原的水流提供到第二电磁过程,其在合适的条件下包括三室膜工艺以制备至少另一部分氢氧化锂并获得第二锂还原水流和第二氢氧化锂 富集水流。 还提供了制备氢氧化锂的系统。
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公开(公告)号:US20160032471A1
公开(公告)日:2016-02-04
申请号:US14776922
申请日:2014-03-17
Applicant: NEMASKA LITHIUM INC.
Inventor: Jean-François MAGNAN , Guy BOURASSA , Gary PEARSE , Peter SYMONS , David J. GENDERS , Daniel BAR , Marie-Eve LANGEVIN
CPC classification number: C25B15/02 , B01D61/44 , B01D61/445 , C25B1/00 , C25B1/16 , C25B9/08 , C25B13/02 , Y02E60/366
Abstract: There are provided processes for preparing lithium hydroxide that comprise submitting an aqueous composition comprising a lithium compound to an electrolysis or an electrodialysis under conditions suitable for converting at least a portion of the lithium compound into lithium hydroxide. For example, the lithium compound can be lithium sulphate and the aqueous composition can be at least substantially maintained at a pH having a value of about 1 to about 4.
Abstract translation: 提供了制备氢氧化锂的方法,其包括将包含锂化合物的水性组合物在适于将至少一部分锂化合物转化为氢氧化锂的条件下进行电解或电渗析。 例如,锂化合物可以是硫酸锂,并且水性组合物可以至少基本上保持在具有约1至约4的值的pH。
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