Abstract:
The positive electrode active material includes secondary particles formed by aggregation of a plurality of primary particles that contain a lithium transition metal composite oxide having a layered structure and containing lithium and nickel. The secondary particles have a smoothness greater than 0.73, and a circularity greater than 0.83. The secondary particles contain cobalt and have a first region at a depth of 150 nm from a surface of the respective secondary particle and a second region at a depth of 10 nm or less from the surface of the respective secondary particle, and a ratio of a number of moles of cobalt to a total number of moles of metal elements other than lithium in the second region is larger than a ratio of a number of moles of cobalt to a total number of moles of metal elements other than lithium in the first region.
Abstract:
Provided is a positive electrode for an all-solid-state lithium ion secondary battery which can reduce the internal resistance of the all-solid-state lithium ion secondary battery. The positive electrode includes an active material layer containing a positive electrode active material and a solid electrolyte material. The positive electrode active material contains secondary particles comprising an aggregate of a plurality of primary particles containing a lithium transition metal composite oxide. A smoothness of the secondary particles is more than 0.73, and a degree of circularity of the secondary particles is more than 0.83.
Abstract:
The present invention provides a positive-electrode active material for non-aqueous secondary battery comprising a sodium transition metal composite oxide represented by Formula: NaxFe1-yMyO2, wherein 0.4≤x≤0.7, 0.25≤y
Abstract:
Provided is a method for producing a positive electrode for a nonaqueous electrolyte secondary battery, the method including obtaining a positive electrode active material having a volume-average particle size in a range of 1 m to 8 m and a specific surface area that is 1.4 m2/g or more from: particles containing a lithium transition metal composite oxide; and an aluminum compound having a volume-average particle size in a range of 1 nm to less than 500 nm, and obtaining a positive electrode active material layer by dispersing the positive electrode active material, a conduction aid, and a binder in a solvent to obtain a dispersion, applying the dispersion to the current collector, drying the dispersion, and subsequently compression-molding the dispersion and the current collector to have a density in a range of more than 2.6 g/cm3 and less than 2.8 g/cm3.
Abstract:
A method of producing a positive electrode for a non-aqueous electrolyte secondary battery, includes: providing a lithium transition metal composite oxide having a layered structure, having a ratio D50/DSEM of 1 or more and 4 or less, and having a certain content of nickel and a certain content of cobalt; bringing the lithium transition metal composite oxide into contact with a cobalt compound to obtain an adhered material; heat-treating the adhered material at a temperature higher than 700° C. and lower than 1100° C. to obtain a heat-treated product; obtaining a positive electrode composition containing the heat-treated product, a conductive auxiliary agent, and a binder; and applying and pressurizing the positive electrode composition onto a collector to form an active material layer having a density of 2.7 g/cm3 or more and 3.9 g/cm3 or less on the collector.
Abstract:
The present invention provides a positive-electrode active material for non-aqueous secondary battery comprising a sodium transition metal composite oxide represented by Formula: NaxFe1-yMyO2, wherein 0.4≦x≦0.7, 0.25≦y
Abstract translation:本发明提供一种非水二次电池用正极活性物质,其包含由式NaxFe1-yMyO2表示的钠过渡金属复合氧化物,其中,0.4≤n1E; x&lt; l1; 0.7,0.25&nlE; y <1.0,M为 至少一种选自锰,钴和镍的元素,钠过渡金属复合氧化物具有基本上由P63 / mmc组成的晶体结构。