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1.发明授权Sulfonylsemicarbazide derivatives and preservative composition for preserving the freshness of flower of cut flowers 失效磺酰氨基脲衍生物和防腐剂组合物，用于保存切花的新鲜度
公开(公告)号：US5723407A
公开(公告)日：1998-03-03
申请号：US596292
申请日：1996-02-13
IPC分类号： A01N3/02 , A01N47/34 , C07C311/61 , C07C311/62 , C07C327/36 , C07C333/28 , C07D213/70 , C07D213/71 , C07D333/34 , C07D333/38 , C07D213/16 , C07D333/10
CPC分类号： C07D213/70 , A01N3/02 , A01N47/34 , C07C311/61 , C07C311/62 , C07C327/36 , C07C333/28 , C07D213/71 , C07D333/34 , C07D333/38
摘要： A sulfonylsemicarbazide derivative of the general formula (I) is effective as a preservative agent for preserving the freshness of a flower, which can prolong the vase life of the flower petals of cut flowers where the flowers can be enjoyed. ##STR1## wherein R.sup.1 represents a (C.sub.3 -C.sub.4)-alkyl group, a substituted or unsubstituted phenyl group, a pyridyl group, a thio-phenyl group or others, R.sup.2 and R.sup.3 each independently represent a hydrogen atom, a lower alkyl group, an alkoxalyl group, an alkoxyalkyl group, a group of the formula --C(X)--X--R.sup.4 where X means an oxygen atom or a sulfur atom and R.sup.4 means an alkyl group, or other, or R.sup.2 and R.sup.3 may form a heterocyclic ring having 4 to 5 carbon atoms or a group of the formula --N.dbd.CR.sup.5 (R.sup.6), as taken with the --N atom to which R.sup.2 and R.sup.3 are attached.
摘要翻译： PCT No.PCT / JP94 / 01358 Sec。 371日期1996年2月13日 102（e）日期1996年2月13日PCT 1994年8月16日PCT公布。 出版物WO95 / 05362 日期：1995年2月23日通式（I）的磺酰基氨基脲衍生物作为防止花的新鲜度的防腐剂是有效的，其可以延长可以享受花朵的切花花瓣的花瓶寿命。 烷基，取代或未取代的苯基，吡啶基，硫代苯基等，R2和R3各自独立地表示氢原子，低级烷基，烷氧基烷基，烷氧基烷基，式 -C（X）-X-R4其中X表示氧原子或硫原子，R 4表示烷基或其它，或者R 2和R 3可以形成具有4至5个碳原子的杂环或式 -N = CR5（R6），与R2和R3所连接的-N原子一起使用。
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2.发明授权Process for preparing optically active [(3-amino-3-carboxy)propyl-1]_phosphinic acid derivatives 失效制备光学活性的[（3-氨基-3-羧基）丙基]次膦酸衍生物的方法
公开(公告)号：US4499027A
公开(公告)日：1985-02-12
申请号：US611686
申请日：1984-05-18
申请人： Nobuto Minowa , Shunzo Fukatsu , Kunitaka Tachibana , Taro Niida , Sadaaki Mase
发明人： Nobuto Minowa , Shunzo Fukatsu , Kunitaka Tachibana , Taro Niida , Sadaaki Mase
摘要： Disclosed is a novel process for optically active [(3-amino-3-carboxy)propyl-1]phosphinic acid derivatives, which comprises reacting a Shiff's base with a derivative of vinylphosphinate in the presence of a base, and subjecting the resulting compound to hydrolysis to form the optically active [(3-amino-3-carboxy)propyl-1]phosphinic acid derivatives as either [L-(3-amino-3-carboxy)propyl-1]phosphinic acid derivatives or [D-(3-amino-3-carboxy)propyl-1]phosphinic acid derivatives.
摘要翻译： 公开了光学活性的[（3-氨基-3-羧基）丙基]次膦酸衍生物的新方法，其包括在碱存在下使希夫碱与乙烯基次膦酸酯的衍生物反应，并将所得化合物 水解形成光学活性的[（3-氨基-3-羧基）丙基]次膦酸衍生物，为[L-（3-氨基-3-羧基）丙基]]次膦酸衍生物或[D-（3 - 氨基-3-羧基）丙基]]次膦酸衍生物。
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公开(公告)号：US4552584A
公开(公告)日：1985-11-12
申请号：US495819
申请日：1983-05-18
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
CPC分类号： A01N57/20
摘要： A known antibiotic, SF-1293 substance and salts thereof have now been found to exhibit high herbicidal effects against a wide variety of herbaceous and woody plants, but they are non-phytotoxic particularly to a useful woody plant, Chamaecyparis obtusa. The herbicidal effects of these SF-1293 substances can be noticeably enhanced by applying in combination with certain known herbicides or compounds having biological activities.
摘要翻译： 现已发现已知的抗生素SF-1293物质及其盐对各种草本植物和木本植物表现出高除草效果，但特别是对有用的木本植物Chamaecyparis obtusa而言是非植物毒性。 通过与某些已知的具有生物活性的除草剂或化合物组合使用，可以显着提高这些SF-1293物质的除草效果。
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公开(公告)号：US4448601A
公开(公告)日：1984-05-15
申请号：US334042
申请日：1981-12-23
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
CPC分类号： A01N57/20
摘要： A known antibiotic, SF-1293 substance and salts thereof have now been found to exhibit high herbicidal effects against a wide variety of herbaceous and woody plants, but they are non-phytotoxic particularly to a useful woody plant, Chamaecyparis obtusa. The herbicidal effects of these SF-1293 substances can be noticeably enhanced by applying in combination with certain known herbicides or compounds having biological activities.
摘要翻译： 现已发现已知的抗生素SF-1293物质及其盐对各种草本植物和木本植物表现出高除草效果，但特别是对有用的木本植物Chamaecyparis obtusa而言是非植物毒性。 通过与某些已知的具有生物活性的除草剂或化合物组合使用，可以显着提高这些SF-1293物质的除草效果。
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5.发明授权Herbicidal compounds, preparation thereof and herbicides containing the same 失效除草化合物，其制备方法和含有它们的除草剂
公开(公告)号：US4226610A
公开(公告)日：1980-10-07
申请号：US27900
申请日：1979-04-06
申请人： Tetsuo Takematsu , Makoto Konnai , Akira Suzuki , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Akira Suzuki , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
CPC分类号： A01N57/20 , C07F9/301 , C07K5/0827
摘要： Novel compounds represented by formula (I) or (II) are provided: ##STR1## They can control annual and perennial weeds, shrubs and aquatic plants more effectively than their mother compounds, or (2-amino-4-methylphosphinobutyryl)alanylalanine and 2-amino-4-methylphosphinobutanoic acid, respectively.
摘要翻译： 提供了由式（I）或（II）表示的新型化合物：其中，（I）
（II）。 它们可以分别比其母体化合物，（2-氨基-4-甲基膦酰基丁酰基）丙氨酸和2-氨基-4-甲基膦酸丁酯更有效地控制一年生和多年生杂草，灌木和水生植物。 -
公开(公告)号：US4455163A
公开(公告)日：1984-06-19
申请号：US263454
申请日：1981-05-15
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
IPC分类号： A01N33/26 , A01N37/32 , A01N39/04 , A01N57/20 , A01P13/00 , C07F9/32 , A01N57/00 , A01N37/38
CPC分类号： A01N57/20
摘要： A known antibiotic, SF-1293 substance and salts thereof have now been found to exhibit high herbicidal effects against a wide variety of herbaceous and woody plants, but they are non-phytotoxic particularly to a useful woody plant, Chamaecyparis obtusa. The herbicidal effects of these SF-1293 substances can be noticeably enhanced by applying in combination with certain known herbicides or compounds having biological activities.
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公开(公告)号：US4382812A
公开(公告)日：1983-05-10
申请号：US68185
申请日：1979-08-20
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
摘要： 2-Amino-4-(hydroxy) (methyl)phosphinoylbutyric acid, which earlier nomenclature referred to as 2-amino-4-methylphosphinobutyric acid or its metal salts, or acid-addition salts thereof are used as perennial weeds and brush controlling agents. The L-isomer is twice effective than the racemic acid. The perennial weeds and brush controlling effect may be obtained by foliar application over a prolonged period and may be surprisingly enhanced by using the compound with a herbicide or synergist selected from the group consisting of choline salt of maleic hydrazide, a phenoxy series herbicide, a benzoic acid series herbicide, 2,3,6-trichlorophenylacetic acid or a salt thereof, (3,5,6-trichloro-2-pyridyl)oxyacetic acid or a salt thereof, N-phosphonomethylglycine or a salt thereof, ethylcarbamoylphosphoric acid or a salt thereof, 2-(1-allyloxyaminobutylidene)-5,5-dimethyl-4-methoxycarbonyl-cyclohexane-1,3-dione, 3-(3,4-dichlorophenyl)-1-methoxy-1-methylurea,3-amino-1,2,4-triazole, choline or a salt thereof, and diethylamine or a salt thereof.
摘要翻译： 2-氨基-4-（羟基）（甲基）膦酰基丁酸，其较早命名称为2-氨基-4-甲基膦酰基丁酸或其金属盐，或其酸加成盐用作多年生杂草和刷控制剂。 L-异构体比外消旋酸有效两倍。 多年生杂草和刷子控制效果可以通过长时间的叶面施用获得，并且可以通过使用化合物与除草剂或增效剂来选择马来酰肼的胆碱盐，苯氧基系列除草剂，苯甲酸 酸系除草剂，2,3,6-三氯苯乙酸或其盐，（3,5,6-三氯-2-吡啶基）氧基乙酸或其盐，N-膦酰甲基甘氨酸或其盐，乙基氨基甲酰基磷酸或其盐 其中，2-（1-烯丙氧基氨基亚丁基）-5,5-二甲基-4-甲氧基羰基 - 环己烷-1,3-二酮，3-（3,4-二氯苯基）-1-甲氧基-1-甲基脲，3-氨基 -1,2,4-三唑，胆碱或其盐，以及二乙胺或其盐。
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公开(公告)号：US4309208A
公开(公告)日：1982-01-05
申请号：US959838
申请日：1978-11-13
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
CPC分类号： A01N57/20
摘要： A known antibiotic, SF-1293 substance and salts thereof have now been found to exhibit high herbicidal effects against a wide variety of herbaceous and woody plants, but they are non-phytotoxic particularly to a useful woody plant, Chamaecyparis obtusa. The herbicidal effects of these SF-1293 substances can be noticeably enhanced by applying in combination with certain known herbicides or compounds having biological activities.
摘要翻译： 现已发现已知的抗生素SF-1293物质及其盐对各种草本植物和木本植物表现出高除草效果，但特别是对有用的木本植物Chamaecyparis obtusa而言是非植物毒性。 通过与某些已知的具有生物活性的除草剂或化合物组合使用，可以显着提高这些SF-1293物质的除草效果。
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公开(公告)号：US4265654A
公开(公告)日：1981-05-05
申请号：US971636
申请日：1978-12-20
申请人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
发明人： Tetsuo Takematsu , Makoto Konnai , Kunitaka Tachibana , Takashi Tsuruoka , Shigeharu Inouye , Tetsuro Watanabe
摘要： 2-Amino-4-methylphosphinobutyric acid or its metal salts, or acid-addition salts thereof are used as perennial weeds and brush controlling agents. The L-isomer is twice effective than the racemic acid. The perennial weeds and brush controlling effect may be obtained by foliar application over a prolonged period.
摘要翻译： 2-氨基-4-甲基膦酰基丁酸或其金属盐或其酸加成盐用作多年生杂草和刷控制剂。 L-异构体比外消旋酸有效两倍。 多年生杂草和刷子控制效果可以通过叶面施用长时间获得。
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公开(公告)号：US06242383B1
公开(公告)日：2001-06-05
申请号：US09486539
申请日：2000-02-29
IPC分类号： A01N4302
CPC分类号： C12P7/62 , A01N37/36 , C07C59/46 , C12P7/42 , A01N2300/00
摘要： An object of the present invention is to provide an agricultural/horticultural preparation having improved photostability, comprising MK 8383 substance. A composition according to the present invention comprises a compound of formula (I): wherein R1 represents hydrogen atom, or a lower alkyl or alkyl carbonyl group, and R2 represents hydroxyl group or a lower alkoxy group, or its salt, and cyclodextrins.
摘要翻译： 本发明的目的是提供具有改善的光稳定性的农业/园艺制剂，其包含MK 8383物质。 根据本发明的组合物包含式（I）化合物：其中R 1表示氢原子，或低级烷基或烷基羰基，R 2表示羟基或低级烷氧基，或其盐和环糊精。
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