公开(公告)号：US5668194A

公开(公告)日：1997-09-16

申请号：US572581

申请日：1995-12-14

申请人： Naotami Ando ,  Toshiyuki Masuda ,  Takanori Hatano ,  Kazuya Nakayama

发明人： Naotami Ando ,  Toshiyuki Masuda ,  Takanori Hatano ,  Kazuya Nakayama

IPC分类号： C08F265/04 ,  C08F265/00 ,  C08F265/06 ,  C08F285/00 ,  C09D151/00 ,  H05K3/28 ,  C08L43/04

CPC分类号： C09D151/003 ,  C08F265/06 ,  C08F285/00 ,  H05K3/285 ,  Y10S525/902

摘要： This invention relates to a room temperature curing composition for use in various coatings for interior and exterior sidings, automotive bodies, household electrical appliances and plastic substrates and particularly for coatings required to have weather resistance and durability. The room temperature curing composition of this invention comprises an emulsion obtained by a multi-stage polymerization of monomers, said emulsion comprising emulsion particles, the core of which is formed by polymerization of (A) a silyl group-containing vinyl monomer, (B) an alkyl or cycloalkyl methacrylate whose alkyl moiety contains not less than 4 carbon atoms, and (C) a non-hydrophilic vinyl monomer other than (B) and the outer shell of which is formed by polymerization of (A), (B), (C) and (D) a hydrophilic vinyl monomer. The room temperature curing composition of this invention features a high stability of silyl groups it contains and a remarkably improved film-forming property even after prolonged storage. Moreover, it is very satisfactory in mechanical stability, water resistance, durability and white enamel gloss.

摘要翻译： 本发明涉及室温固化组合物，其用于室内和外侧各种涂料，汽车车身，家用电器和塑料基材，特别是用于具有耐候性和耐久性的涂层。 本发明的室温固化组合物包含通过单体多阶段聚合获得的乳液，所述乳液包含乳液颗粒，其核心通过（A）含甲硅烷基的乙烯基单体的聚合形成，（B） 烷基部分含有不少于4个碳原子的烷基或环烷基甲基丙烯酸酯，（C）除（B）以外的非亲水性乙烯基单体，其外壳由（A），（B）， （C）和（D）亲水性乙烯基单体。 本发明的室温固化组合物特征在于其含有的甲硅烷基的稳定性高，即使在长时间储存​​后也具有显着改善的成膜性能。 此外，机械稳定性，耐水性，耐久性和白色搪瓷光泽度非常令人满意。

公开(公告)号：US5322890A

公开(公告)日：1994-06-21

申请号：US145530

申请日：1993-11-04

申请人： Naotami Ando ,  Toshiyuki Masuda ,  Takanori Hatano

发明人： Naotami Ando ,  Toshiyuki Masuda ,  Takanori Hatano

IPC分类号： C08F230/08 ,  C08Z43/04

CPC分类号： C08F230/08

摘要： A room temperature cross-linkable aqueous composition which contains an emulsion-polymerized copolymer comprising (I) a reaction product prepared by reacting (A) a monomer having at least one polymerizable double bond and a silyl group represented by the general formula (I): ##STR1## wherein R.sup.1 : monovalent hydrocarbon selected from the group consisting of C.sub.1-10 alkyl, aryl and aralkyl, X: a halogen, alkoxy, hydroxyl, acyloxy, aminoxy, phenoxy, thioalkoxy, or amino, a: 0, 1 or 2, and (B) a basic compound; and (II) a vinyl monomer copolymerizable with said (I) reaction product, and a process for preparing the same. The composition of the present invention has excellent storage stability and excellent room temperature cross-linkability which can be polymerized in stable condition without gelation.

摘要翻译： 一种室温可交联水性组合物，其含有乳液聚合共聚物，其包含（I）通过使（A）具有至少一个可聚合双键的单体和由通式（I）表示的甲硅烷基反应制备的反应产物： （I）其中R 1：选自C 1-10烷基，芳基和芳烷基，X：卤素，烷氧基，羟基，酰氧基，氨氧基，苯氧基，硫代烷氧基或氨基的一价烃，a：0， 1或2，和（B）碱性化合物; 和（II）可与所述（I）反应产物共聚的乙烯基单体及其制备方法。 本发明的组合物具有优异的储存稳定性和优异的室温可交联性，可以在没有凝胶化的条件下稳定地聚合。

公开(公告)号：US5461102A

公开(公告)日：1995-10-24

申请号：US88010

申请日：1993-07-06

申请人： Toshiyuki Masuda ,  Takanori Hatano ,  Naotami Ando

发明人： Toshiyuki Masuda ,  Takanori Hatano ,  Naotami Ando

IPC分类号： C08F2/24 ,  C08F30/08 ,  C08F275/00 ,  C08L13/02

CPC分类号： C08F30/08 ,  C08F275/00

摘要： A monomer mixture (B) containing a vinyl monomer having a functional silyl group of the general formula (ii) is subjected to emulsion polymerization in an aqueous solution of a water-soluble resin (A) having a functional silyl group of the general formula (i) the water-soluble resin [A] is synthesized using, as a polymerization solvent, a water-soluble organic solvent containing a (poly)ethylene glycol monoalkyl ether of the general formula HO--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.3 or a (poly)propylene glycol monoalkyl ether of the general formula HO--(C.sub.3 H.sub.6 O).sub.n --R.sup.4 ; ##STR1## wherein R.sup.1 and R.sup.2 each independently is a monovalent group selected from the class consisting of alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups, X is a group selected from the class consisting of halogen atoms, alkoxy groups, a hydroxy group, acyloxy groups, an aminoxy group, a phenoxy group, thioalkoxy groups and an amino group, a and b each independently is an integer of 0 to 2, R.sup.3 and R.sup.4 each is an alkyl group containing 1 to 10 carbon atoms and n is an integer of 1 to 10 and wherein, when two or more R.sup.1 and/or R.sup.2 or X groups are bound to Si, they respectively may be the same or different.

摘要翻译： 将含有具有通式（ii）的官能甲硅烷基的乙烯基单体的单体混合物（B）在具有通式（II）的官能甲硅烷基的水溶性树脂（A）的水溶液中进行乳液聚合， i）水溶性树脂[A]使用含有通式HO-（CH 2 CH 2 O）n -R 3（（多））乙二醇单烷基醚或（聚 ）通式HO-（C 3 H 6 O）n -R 4的丙二醇单烷基醚; （i）其中R 1和R 2各自独立地是选自由含有1至10个碳原子的烷基，芳基和芳烷基组成的类中的一价基团，X是选自 由卤素原子，烷氧基，羟基，酰氧基，氨氧基，苯氧基，硫代烷氧基和氨基组成的类别，a和b各自独立地为0〜2的整数，R3和R4分别为 含有1至10个碳原子的烷基，n是1至10的整数，并且其中当两个或多个R 1和/或R 2或X基团与Si结合时，它们可以相同或不同。

公开(公告)号：US5969037A

公开(公告)日：1999-10-19

申请号：US325

申请日：1998-02-25

申请人： Takanori Hatano ,  Naotami Ando

发明人： Takanori Hatano ,  Naotami Ando

IPC分类号： C08F285/00 ,  C08F291/00 ,  C08L43/04

CPC分类号： C08F291/00 ,  C08F285/00

摘要： A room temperature curing composition of this invention comprises an emulsion obtained by multi-stage emulsion polymerization of monomers, the emulsion comprising emulsion particles, a core of which comprises (A) 1 to 30% by weight of silyl group-containing vinyl monomer, (B) 70 to 99% by weight of vinyl monomer copolymerizable with component (A), the outermost shell of which comprises (A) 0.1 to 30% by weight of silyl group-containing vinyl monomer and (B) 40 to 99.4% by weight of vinyl monomer copolymerizable with component (A), and (D) 0.5 to 30% by weight of hydrophilic vinyl monomer. The room temperature curing composition of this invention has a stable silyl group, and a much improved film-forming ability after long-term storage and it also shows excellent mechanical stability, water-resistance, durability and white enamel gloss.

摘要翻译： PCT No.PCT / JP96 / 02181 Sec。 371日期：1998年2月25日 102（e）日期1998年2月25日PCT提交1996年8月2日PCT公布。 公开号WO97 / 06193 日本1997年2月20日本发明的室温固化组合物包含通过单体的多阶段乳液聚合获得的乳液，该乳液包含乳液颗粒，其芯包含（A）1至30重量％的甲硅烷基 - （B）70〜99重量％的可与组分（A）共聚的乙烯基单体，其最外层包含（A）0.1-30重量％的含甲硅烷基的乙烯基单体和（B）40 至99.4重量％的可与组分（A）共聚的乙烯基单体，和（D）0.5至30重量％的亲水乙烯基单体。 本发明的室温固化组合物具有稳定的甲硅烷基，长期保存后的成膜能力大大提高，并且还显示优异的机械稳定性，耐水性，耐久性和白色搪瓷光泽。

公开(公告)号：US5390876A

公开(公告)日：1995-02-21

申请号：US154517

申请日：1993-11-19

申请人： Takanori Hatano ,  Takayoshi Ito ,  Noboru Miyazaki ,  Ryuji Umehara ,  Tomoharu Kamo

发明人： Takanori Hatano ,  Takayoshi Ito ,  Noboru Miyazaki ,  Ryuji Umehara ,  Tomoharu Kamo

IPC分类号： F16L3/10 ,  F16L3/00

CPC分类号： F16L3/1075

摘要： A holder including a fastening member, a base member, and a hinged connecting member for interconnecting the fastening member and the base member in a manner that the fastening member can be pivoted for the base member. The fastening member has a mounting block including a through hole. The base member has a mating portion including an insertion opening. The mounting block has engagement means engageable with engagement means provided on a bracket mounted on an automobile body. The engagement means of the bracket is engaged with the engagement means of the mounting block when the bracket is received in the through hole passed through the insertion opening, whereby the fastening member is mounted on the bracket in its closed position.

摘要翻译： 一种夹持器，包括紧固构件，基部构件和铰接连接构件，用于以紧固构件可枢转的方式将基座构件与基座构件互连。 紧固构件具有包括通孔的安装块。 基部构件具有包括插入开口的配合部分。 安装块具有可与设置在安装在汽车车体上的支架上的接合装置接合的接合装置。 当支架被容纳在通过插入口的通孔中时，支架的接合装置与安装块的接合装置接合，由此紧固构件在其关闭位置安装在支架上。

公开(公告)号：US20070282074A1

公开(公告)日：2007-12-06

申请号：US11587552

申请日：2005-04-07

申请人： Takanori Hatano ,  Ryuji Fukuda

发明人： Takanori Hatano ,  Ryuji Fukuda

IPC分类号： C08F6/08

CPC分类号： B60K6/365 ,  B60K1/02 ,  B60K6/445 ,  F16H3/728 ,  F16H37/021 ,  F16H37/084 ,  F16H37/10 ,  F16H2037/025 ,  F16H2037/102 ,  F16H2037/104 ,  Y02T10/6239

摘要： An object of the present invention is to provide a process for producing an isobutylene block copolymer, which process can provide a resin having a low content of a catalyst residue and high transparency. The object can be achieved by a process for producing an isobutylene block copolymer by living cationic polymerization using a Lewis acid, wherein, for removing the Lewis acid from a solution after the polymerization, the solution is charged into and mixed with water in which a nonionic surfactant with an HLB of 10 or less is contained in an amount of 0.01 to 0.5 part by weight based on 100 parts by weight of the isobutylene block copolymer.

摘要翻译： 本发明的目的是提供一种制备异丁烯嵌段共聚物的方法，该方法可提供具有低含量的催化剂残余物和高透明度的树脂。 该目的可以通过使用路易斯酸的活性阳离子聚合制备异丁烯嵌段共聚物的方法来实现，其中，从聚合后的溶液中除去路易斯酸，将该溶液装入和混合，其中非离子表面活性剂 相对于100重量份的异丁烯嵌段共聚物，HLB为10以下的表面活性剂的含量为0.01〜0.5重量份。