Nitrogen-containing heterocyclic compound and method for producing same
    2.
    发明授权
    Nitrogen-containing heterocyclic compound and method for producing same 有权
    含氮杂环化合物及其制造方法

    公开(公告)号:US08809544B2

    公开(公告)日:2014-08-19

    申请号:US14175904

    申请日:2014-02-07

    CPC分类号: C07D213/89 C07D213/75

    摘要: There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), R1 and R2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R3 represents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; R4 represents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.)

    摘要翻译: 提供了可用作农药等的合成中间体的含氮杂环化合物,例如由式(1)表示的取代的氨基 - 吡啶-N-氧化物化合物; 和含氮杂环化合物的制造方法。 (式(1)中,R 1和R 2各自表示氢原子或未取代或取代的烷基; R 3表示氢原子,未取代或取代的烷基羰基等; R 4表示未取代或取代的烷基羰基,未取代的 或取代的芳基羰基等; A表示羟基,硫醇基等; m表示1〜4的整数中的任一个; k表示0〜3的整数中的任一个; k + m< 1l; 4。 )

    Process for producing organolithium compound and process for producing substituted aromatic compound
    4.
    发明授权
    Process for producing organolithium compound and process for producing substituted aromatic compound 有权
    制备有机锂化合物的方法和制备取代的芳族化合物的方法

    公开(公告)号:US09133098B2

    公开(公告)日:2015-09-15

    申请号:US14506076

    申请日:2014-10-03

    发明人: Hiroki Inoue

    摘要: A method for producing an organolithium compound includes the step of reacting an aromatic compound or a halogenated unsaturated aliphatic compound and a lithiating agent in the presence of a coordinating compound containing three or more elements having a coordinating ability in a molecule, at least one thereof being a nitrogen element, or a coordinating compound containing three or more oxygen elements having a coordinating ability in a molecule, at least one of the groups containing the oxygen elements having a coordinating ability being a tertiary alkoxy group, at a temperature of −40° C. to 40° C.

    摘要翻译: 有机锂化合物的制造方法包括使芳香族化合物或卤化不饱和脂肪族化合物与锂化剂在含有分子中具有配位能力的三种以上的配位化合物的存在下反应的工序,其中至少一个为 氮元素或含有三个或更多个在分子中具有配位能力的氧元素的配位化合物,至少一个含有具有叔烷氧基的配位能力的氧元素的基团在-40℃的温度下 至40℃

    Nitrogen-containing heterocyclic compound and method for producing same
    7.
    发明授权
    Nitrogen-containing heterocyclic compound and method for producing same 有权
    含氮杂环化合物及其制造方法

    公开(公告)号:US08962849B2

    公开(公告)日:2015-02-24

    申请号:US14175879

    申请日:2014-02-07

    CPC分类号: C07D213/89 C07D213/75

    摘要: There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), R1 and R2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R3 represents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; R4 represents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.).

    摘要翻译: 提供了可用作农药等的合成中间体的含氮杂环化合物,例如由式(1)表示的取代的氨基 - 吡啶-N-氧化物化合物; 和含氮杂环化合物的制造方法。 (式(1)中,R 1和R 2各自表示氢原子或未取代或取代的烷基; R 3表示氢原子,未取代或取代的烷基羰基等; R 4表示未取代或取代的烷基羰基,未取代的 或取代的芳基羰基等; A表示羟基,硫醇基等; m表示1〜4的整数中的任一个; k表示0〜3的整数中的任一个; k + m< 1l; 4。 )。

    Nitrogen-containing heterocyclic compound and method for producing same

    公开(公告)号:US08981107B2

    公开(公告)日:2015-03-17

    申请号:US14175535

    申请日:2014-02-07

    CPC分类号: C07D213/89 C07D213/75

    摘要: There are provided a nitrogen-containing heterocyclic compound such as a substituted amino-pyridine-N-oxide compound represented by formula (1), which is useful as a synthetic intermediate for an agrochemical and the like; and a method for producing the nitrogen-containing heterocyclic compound. (In formula (1), R1 and R2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R3 represents a hydrogen atom, an unsubstituted or substituted alkylcarbonyl group or the like; R4 represents an unsubstituted or substituted alkylcarbonyl group, an unsubstituted or substituted arylcarbonyl group or the like; A represents a hydroxyl group, a thiol group or the like; m represents any one of integers of 1 to 4; k represents any one of integers of 0 to 3; and k+m≦4.)

    PROCESS FOR PRODUCING ORGANOLITHIUM COMPOUND AND PROCESS FOR PRODUCING SUBSTITUTED AROMATIC COMPOUND
    10.
    发明申请
    PROCESS FOR PRODUCING ORGANOLITHIUM COMPOUND AND PROCESS FOR PRODUCING SUBSTITUTED AROMATIC COMPOUND 审中-公开
    生产有机化合物的方法和生产取代的芳族化合物的方法

    公开(公告)号:US20150025276A1

    公开(公告)日:2015-01-22

    申请号:US14506076

    申请日:2014-10-03

    发明人: Hiroki Inoue

    IPC分类号: C07C217/08 C07C211/14

    摘要: A method for producing an organolithium compound includes the step of reacting an aromatic compound or a halogenated unsaturated aliphatic compound and a lithiating agent in the presence of a coordinating compound containing three or more elements having a coordinating ability in a molecule, at least one thereof being a nitrogen element, or a coordinating compound containing three or more oxygen elements having a coordinating ability in a molecule, at least one of the groups containing the oxygen elements having a coordinating ability being a tertiary alkoxy group, at a temperature of −40° C. to 40° C.

    摘要翻译: 有机锂化合物的制造方法包括使芳香族化合物或卤化不饱和脂肪族化合物与锂化剂在含有分子中具有配位能力的三种以上的配位化合物的存在下反应的工序,其中至少一个为 氮元素或含有三个或更多个在分子中具有配位能力的氧元素的配位化合物,至少一个含有具有叔烷氧基的配位能力的氧元素的基团在-40℃的温度下 至40℃