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1.发明授权Photographic light-sensitive materials containing couplers that release diffusible dyes and DIR compounds 失效含有释放扩散染料和DIR化合物的成色剂的照相感光材料
公开(公告)号：US4975359A
公开(公告)日：1990-12-04
申请号：US349457
申请日：1989-05-09
CPC分类号： G03C7/32 , G03C7/3225
摘要： A silver halide color photographic light-sensitive material is described, containing: (1) a non-diffusing coupler forming a dye on reacting with an oxidation product of a color developing agent, said dye having diffusibiity of the extent that it exhibits controlled smearing; and (2) a DIR compound releasing a diffusing development inhibitor or its precursor through a coupling reaction. This light-sensitive material is improved in both granularity and sharpness, and has high sensitivity.
摘要翻译： 描述了一种卤化银彩色照相感光材料，其包含：（1）与彩色显影剂的氧化产物反应形成染料的非扩散偶合剂，所述染料具有显示受控涂抹程度的扩散性; 和（2）通过偶联反应释放扩散显影抑制剂或其前体的DIR化合物。 这种感光材料的粒度和锐度均提高，灵敏度高。
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公开(公告)号：US4477563A
公开(公告)日：1984-10-16
申请号：US526314
申请日：1983-08-25
IPC分类号： G03C7/00 , C07C205/57 , C07D235/28 , C07D249/18 , C07D249/20 , C07D257/04 , C07D277/74 , C07D403/04 , C07D403/12 , C07D487/04 , G03C7/26 , G03C7/305 , G03C7/32
CPC分类号： G03C7/305 , C07C205/57 , C07D249/18 , C07D257/04 , G03C7/30541 , Y10S430/158
摘要： A silver halide color photographic light-sensitive material is described comprising a support having thereon a silver halide emulsion layer containing a coupler having, at the coupling active position, a group which provides a compound having a development inhibiting property when the group is released from the coupling device position of the coupler upon the color development reaction and which is decomposed to a compound which does not substantially influence the photographic properties when the compound diffuses into a color developing solution.The silver halide color photographic light-sensitive material containing a novel class of development inhibitor releasing couplers provides color images of good sharpness and improved color reproduction without causing contamination of the processing solution.
摘要翻译： 描述了一种卤化银彩色摄影感光材料，其包括其上具有卤化银乳剂层的载体，所述卤化银乳剂层含有偶联剂，所述成色剂在偶合活性位置是当基团从所述偶联剂释放时提供具有显影抑制性质的化合物的基团 耦合器在显色反应中的耦合器件位置，并且当化合物扩散到显色溶液中时分解成基本上不影响照相特性的化合物。 含有新型显影抑制剂释放成色剂的卤化银彩色照相感光材料提供了良好的清晰度和改善的色彩再现的彩色图像，而不会引起处理溶液的污染。
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公开(公告)号：USH789H
公开(公告)日：1990-06-05
申请号：US180874
申请日：1988-04-13
申请人： Shinji Ueda , Kei Sakanoue , Seiji Ichijima , Hidetoshi Kobayashi
发明人： Shinji Ueda , Kei Sakanoue , Seiji Ichijima , Hidetoshi Kobayashi
CPC分类号： G03C7/44
摘要： A novel method for processing a silver halide color photographic material. The process comprises imagewise exposing a silver halide color photographic light-sensitive material to light, color-developing the light-sensitive material, and then desilvering the light-sensitive material, wherein: (a) said silver halide color photographic light-sensitive material contains a compound which reacts with an oxidation product of anaromatic primary amine color developing agent to form a bleaching accelerator, (b) the desilvering step is conducted with a processing solution containing a ferric complex salt of an organic acid, and (c) the total amount of replenisher of the processing solution to be used in the desilvering step satisfies either the following conditions (i) or (ii):(i) the total amount of replenisher is 1,000 ml or less per m.sup.2 of the light-sensitive material if the coated amount of silver per m.sup.2 of the light-sensitive material is 2.0 g or more;(ii) the total amount of replenisher is 400 ml or less per m.sup.2 of the light-sensitive material if the coated amount of silver per m.sup.2 of the light-sensitive material is less than 2.0 g.
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公开(公告)号：US4959299A
公开(公告)日：1990-09-25
申请号：US164655
申请日：1988-03-07
申请人： Kei Sakanoue , Hidetoshi Kobayashi , Seiji Ichijima , Shinji Ueda
发明人： Kei Sakanoue , Hidetoshi Kobayashi , Seiji Ichijima , Shinji Ueda
CPC分类号： G03C7/30594 , Y10S430/156 , Y10S430/158
摘要： A silver halide color photographic material is disclosed comprising at least one silver halide emulsion layer on a support, wherein at least one type of development inhibitor releasing type coupler is present which, by means of a coupling reaction with the oxidized form of a primary aromatic amine developing agent, releases a precursor of a compound, the precursor inhibiting the development of silver halide which subsequently, by means of an electron transfer reaction via an ethylenic conjugated chain, releases a compound which inhibits the development of silver halide, and at least one type of bleach accelerating agent releasing type coupler is present which, by means of a coupling reaction with the oxidized form of primary aromatic amine developing agent, releases a bleach accelerating agent or a precursor thereof.
摘要翻译： 公开了一种卤化银彩色照相材料，其在载体上包含至少一个卤化银乳剂层，其中存在至少一种类型的显影抑制剂释放型成色剂，其通过与氧化形式的伯芳族胺的偶联反应 显影剂，释放化合物的前体，抑制卤化银显影的前体，其随后通过乙烯共轭链的电子转移反应释放抑制卤化银显影的化合物，并且至少一种类型 存在漂白促进剂释放型成色剂，其通过与氧化形式的伯芳族胺显影剂的偶联反应释放漂白促进剂或其前体。
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公开(公告)号：US4729944A
公开(公告)日：1988-03-08
申请号：US802603
申请日：1985-11-25
CPC分类号： G03C7/26 , G03C7/3003 , G03C1/0051
摘要： A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, wherein the photographic light-sensitive material has a layer containing both a non-diffusible coupler which forms a properly smearing diffusible dye upon reaction with the oxidation product of a color developing agent and a silver halide emulsion in which a diameter corresponding to the projected area of grains that takes 40% or more of the projected area of whole silver halide grains is 1.5 .mu.m or more.The silver halide photographic light-sensitive material has improved graininess as well as has high sensitivity.
摘要翻译： 一种卤化银照相感光材料，其包括其上具有至少一个卤化银乳剂层的载体，其中所述照相感光材料具有含有与所述氧化反应形成适当涂抹的可扩散染料的不扩散成色剂的层 彩色显影剂和卤化银乳剂的产物，其中对应于占整个卤化银颗粒的投影面积的40％或更多的颗粒的投影面积的直径为1.5μm或更大。 卤化银照相感光材料具有改善的颗粒度并且具有高灵敏度。
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公开(公告)号：US5049474A
公开(公告)日：1991-09-17
申请号：US196392
申请日：1988-05-20
申请人： Seiji Ichijima , Kei Sakanoue
发明人： Seiji Ichijima , Kei Sakanoue
CPC分类号： G03C7/30547 , Y10S430/159
摘要： A novel color light-sensitive material is provided, which comprises a support having theron at least a light-sensitive silver halide, an image-forming coupler, and a compound represented by formula (I):PWR--Time).sub.t Z [I]wherein PWR represents a group which undergoes reduction to release --Time).sub.t Z; Time represents a group which releases Z through a reaction after being released as --Time).sub.t Z; t represents an integer of 0 or 1; and Z represents a group which becomes a slightly mobile dye or a precursor thereof after being released from --Time).sub.t Z.
摘要翻译： 提供了一种新型的彩色感光材料，其包括具有至少一种感光卤化银，图像形成成色剂和由式（I）表示的化合物的载体：PWR-Time）tZ [I]，其中 PWR表示经过减少释放的组 - 时间）tZ; 时间表示在被释放为时间后通过反应释放Z的组）tZ; t表示0或1的整数; Z表示在从-Time开始释放后成为轻微移动的染料或其前体的基团）。
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7.发明授权Color photographic material with color forming ligand compounds and a method of processing 失效彩色照相材料与配色剂配位化合物及其加工方法
公开(公告)号：US4764454A
公开(公告)日：1988-08-16
申请号：US943127
申请日：1986-12-18
申请人： Seiji Ichijima , Kei Sakanoue
发明人： Seiji Ichijima , Kei Sakanoue
CPC分类号： C07D403/14 , G03C7/305 , G03C7/3212
摘要： A novel silver halide color photographic material is provided comprising a compound of the general formula (I):LIG-A-LVG (I)wherein A represents a group which reacts with an oxidation product of a developing agent to cleave the bond to LVG; LVG represents a coupling-off group; and LIG represents a group which reacts with metal ions to form a complex compound.A novel method of processing the instant silver halide color photographic material is provided including a processing step using a processing solution of an iron (II) ion concentration of 1.times.10.sup.-6 to 1 mol/l. In the processing step, the potential of a bath having a bleaching capacity containing an aminopolycarboxylic acid-iron (III) complex salt is 150 mV or less.
摘要翻译： 提供一种新型的卤化银彩色照相材料，其包含通式（I）的化合物：LIG-A-LVG（I）其中A表示与显影剂的氧化产物反应以将键键合到LVG的基团; LVG代表耦合离子基团; LIG表示与金属离子反应形成络合物的基团。 提供了一种处理本发明的卤化银彩色照相材料的新方法，其包括使用1×10-6至1mol / l的铁（II）离子浓度的处理溶液的处理步骤。 在处理步骤中，含有氨基多羧酸 - 铁（III）络盐的漂白能力的浴的电位为150mV以下。
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公开(公告)号：US4842994A
公开(公告)日：1989-06-27
申请号：US119615
申请日：1987-11-12
申请人： Kei Sakanoue , Seiji Ichijima
发明人： Kei Sakanoue , Seiji Ichijima
CPC分类号： G03C7/30552 , Y10S430/156 , Y10S430/158 , Y10S430/159
摘要： A silver halide photographic material is described, comprising a support having provided thereon at least one silver halide photographic emulsion layer and comprising a bleach accelerator-releasing coupler, wherein said bleach accelerator-releasing coupler is represented by formula (I)A--(TIME).sub.n --S--X--(Y).sub.m --(Z)l]a (I)wherein A represents a coupler residual group; TIME represents a timing group; n represents 0 or 1; X represents a cyclic aliphatic group or a saturated heterocyclic group; Y represents an aliphatic group having from 1 to 8 carbon atoms which may contain a group of --O--, a group of --S--, a group of --COO--, a group of --CO--, a group of ##STR1## a group of ##STR2## a group of --SO.sub.2 --or a group of ##STR3## in its chain; m represents an integer of from 0 to 3, and when m represents 2 or more, the two or more Y groups may be the same or different; Z represents a group of --OH, a group of --COOM, a group of --SO.sub.3 M or a group of ##STR4## l represents an integer of from 1 to 3, and when l represents 2 or more, the two or more Z groups may be the same or different; a represents 1 or 2, and when a represents 2, the two (Y)m--(Z)l groups may be the same or different; R.sub.1, R.sub.2, and R.sub.3 each represents a hydrogen atom, or an aliphatic group having from 1 to 4 carbon atoms; and M represents an alkali metal ion, an ammonium ion, or a hydrogen atom.The bleach accelerator-releasing coupler used in the present invention maintains its good bleach accelerating effect under running conditions. The silver halide photographic material enables rapid processing because of its high silver bleaching speed.A method for processing the silver halide photographic material is also described, wherein the photographic material is not subjected to, between the color developing step and the bleach-fixing step, to a water washing step.
摘要翻译： 描述了一种卤化银照相材料，其包括其上提供有至少一个卤化银照相乳剂层并且包含漂白促进剂释放成色剂的载体，其中所述漂白促进剂释放成色剂由式（I）A-（TIME）表示， nSX-（Y）m-（Z）l] a（I）其中A表示成色剂残基; TIME代表一个时间组; n表示0或1; X表示环状脂族基或饱和杂环基; Y表示具有1至8个碳原子的脂族基团，其可以含有-O-，一个-S-，一组-COO-，-CO-基团，一组
a 一组 一组-SO2或一组 在其链中; m表示0〜3的整数，当m表示2以上时，两个以上的Y基可以相同或不同， Z表示-OH基团，-COOM基团，-SO 3 M基团或者表示1〜3的整数，当l表示2以上时，可以使用两个以上的Z基团 可能相同或不同; a表示1或2，当a表示2时，两个（Y）m - （Z）1基可以相同或不同; R1，R2和R3各自表示氢原子或具有1至4个碳原子的脂族基团; M表示碱金属离子，铵离子或氢原子。 用于本发明的漂白促进剂释放成色剂在运行条件下保持良好的漂白剂加速效果。 卤化银照相材料由于其高的银漂白速度而能够快速加工。 还描述了用于处理卤化银照相材料的方法，其中照相材料在显色步骤和漂白剂固定步骤之间不经受水洗步骤。 -
公开(公告)号：US4880726A
公开(公告)日：1989-11-14
申请号：US270712
申请日：1988-11-14
申请人： Keisuke Shiba , Seiji Ichijima , Kei Sakanoue , Seiichi Taguchi
发明人： Keisuke Shiba , Seiji Ichijima , Kei Sakanoue , Seiichi Taguchi
IPC分类号： G03C7/30
CPC分类号： G03C7/3041 , G03C7/3003
摘要： A method of forming a color image wherein a color print original is printed on a printing color photographic material and the thus printed material is then subjected to color development to give a color print, which is characterized in that a band stop filter having a half width of the spectral transmittance curve of said filter in a wavelength range outside the region of the maximum spectral sensitivity wavelength (.lambda.max).+-.20 nm of at least one light-sensitive layer of the printing color photographic material is provided between the light source to be used in said printing step and the light-sensitive layer of said printing color photographic material, and in that a compound of a general formula (I):(C.sub.p).X (I)wherein C.sub.p represents a coupler residue capable of coupling with the oxidation product of a color developing agent to form a substantially colorless compound or a coupler residue which is coupled during a color development step to form a compound capable of being dissolved or diffused out of the layer of the photographic material; and X represents a group which is in the coupling position of the coupler and which may react with the oxidation product of a developing agent or which may react therewith to be released from the coupler, is incorporated into the light-sensitive layer of the said printing color photographic material or a taking color photographic material from which the said color print original is obtained, or into the interlayer existing between the light-sensitive layers of the said material.By the present method, excellent color prints can be obtained in short printing times, having reduced interlayer color mixing. pr
摘要翻译： 一种形成彩色图像的方法，其中将彩色印刷原稿印刷在印刷彩色照相材料上，然后将这样印刷的材料进行着色显影以得到彩色印刷品，其特征在于，具有半宽度 在打印彩色照相材料的至少一个感光层的最大光谱灵敏度波长（λmax）+/- 20nm的区域外的波长范围内的所述滤光器的光谱透射率曲线被提供在光源 用于所述印刷步骤和所述印刷彩色照相材料的感光层，以及通式（I）：（Cp）.X（I）的化合物，其中Cp表示能够偶合的成色剂残基 与彩色显影剂的氧化产物形成基本上无色的化合物或成色剂残留物，其在显色步骤中偶联以形成能够溶解的化合物 或从照相材料层中扩散或扩散; X表示处于耦合器的耦合位置并可与显影剂的氧化产物反应或与反应物从耦合器释放的基团并入所述印刷的光敏层中的基团 获得所述彩色印刷原稿的彩色照相材料或获取彩色照相材料，或者存在于所述材料的感光层之间的夹层中。 通过本方法，可以在短的打印时间内获得优异的彩色打印，具有减少的层间色混合。
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公开(公告)号：US4886736A
公开(公告)日：1989-12-12
申请号：US065194
申请日：1987-06-12
申请人： Koki Nakamura , Kei Sakanoue , Seiji Ichijima
发明人： Koki Nakamura , Kei Sakanoue , Seiji Ichijima
CPC分类号： G03C7/305 , Y10S430/156 , Y10S430/159
摘要： A silver halide color photographic material comprising (1) at least one coupler and (2) at least one compound represented by formula (I) ##STR1## wherein EAG represents a group capable of accepting an electron from a reducing substance; R.sup.1 and R.sup.2 each represents a chemical bond or a divalent substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when linked with (Time).sub.t PUG; or R.sup.1 and R.sup.2 each represents a substituent, or R.sup.1 and R.sup.2 are linked together to form a cyclic structure when not linked with (Time).sub.t PUG; Time represents a group capable of releasing PUG, which is released by the cleavage of the single bond between the oxygen atom and the nitrogen atom in the compound; t represents 0 or 1; PUG represents a photographically useful group; and the dotted lines mean that at least one of them forms a chemical bond, and a method for forming an image using the material.
摘要翻译： 一种卤化银彩色照相材料，其包含（1）至少一种成色剂和（2）至少一种由式（I）表示的化合物，其中EAG表示能够从还原物质接受电子的基团; R1和R2各自表示化学键或二价取代基，或者当与（Time）tPUG连接时，R 1和R 2连接在一起形成环状结构; 或者R 1和R 2各自表示取代基，或者当不与（时间）tPUG连接时，R 1和R 2连接在一起形成环状结构; 时间表示能够释放PUG的基团，其通过化合物中氧原子和氮原子之间的单键的切割而释放; t表示0或1; PUG代表一个摄影有用的组; 并且虚线意味着它们中的至少一个形成化学键，以及使用该材料形成图像的方法。
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