摘要:
In a nonaqueous electrolytic secondary battery according to the invention, hexagonal system lithium containing cobalt composite oxide having a crystallite size in a (110) vector direction of 1000 Å or more and having a halogen compound added thereto by burning at time of synthesis is used as a positive electrode active material. By measuring a pH value of a filtrate obtained by dispersing, in water, the lithium containing cobalt composite oxide having the halogen compound added thereto by the burning at time of the synthesis and a crystallite size in the (110) vector direction of 1000 Å or more, a value of 9.6 to 10.1 is obtained. By using the lithium containing cobalt composite oxide as a positive electrode active material, a high temperature cycle property can be enhanced.
摘要:
In a nonaqueous electrolytic secondary battery according to the invention, hexagonal system lithium containing cobalt composite oxide having a crystallite size in a (110) vector direction of 1000 Å or more and having a halogen compound added thereto by burning at time of synthesis is used as a positive electrode active material. By measuring a pH value of a filtrate obtained by dispersing, in water, the lithium containing cobalt composite oxide having the halogen compound added thereto by the burning at time of the synthesis and a crystallite size in the (110) vector direction of 1000 Å or more, a value of 9.6 to 10.1 is obtained. By using the lithium containing cobalt composite oxide as a positive electrode active material, a high temperature cycle property can be enhanced.
摘要:
The present invention improves the cycle characteristics of a non-aqueous electrolyte secondary cell that uses lithium cobalt oxide as a positive electrode active material. To this end, an element different from cobalt such as zirconium and titanium is added to the lithium cobalt oxide, acting as the positive electrode active material. The non-aqueous electrolyte contains a non-aqueous solvent containing diethyl carbonate at 10 to 30 volume percent on a base of 25 degree Celsius and contains an electrolyte salt.
摘要:
The present invention provides a nonaqueous electrolyte secondary cell having a positive electrode comprising mainly of a positive electrode active material, a negative electrode, and a nonaqueous electrolyte. The positive electrode active material is a lithium-containing transition metal composite oxide of a hexagonal crystal system that includes a compound represented by the general formula LiCo1-xMxO2, where M is at least one species selected from the group consisting of V, Cr, Fe, Mn, Ni, Al, and Ti, and x is a decimal number in a range 0
摘要翻译:本发明提供一种具有主要由正极活性物质,负极和非水电解质组成的正极的非水电解质二次电池。 正极活性物质是六方晶系的含锂过渡金属复合氧化物,其包含由通式LiCo 1-x M x O O表示的化合物, 其中M是选自V,Cr,Fe,Mn,Ni,Al和Ti中的至少一种,x是0
摘要:
A positive electrode used in the non-aqueous electrolyte secondary battery of the present invention includes a hexagonal system lithium-containing cobalt composite oxide represented by the general expression ┌LiCo1-XMXO2 (M=Zr, Mg, Al)┘ obtained by synthesizing a lithium compound as a lithium source with a cobalt compound as a cobalt source to which 0.01 mol % or more and 1.0 mol % or less of zirconium is added and magnesium and/or aluminum is added through coprecipitation, as the positive electrode active material, whereby the thermal stability, load performance and charging/discharging cycle performance characteristics of the non-aqueous electrolyte secondary battery are improved without lowering its capacity and charging/discharging efficiency.
摘要:
The present invention improves the cycle characteristics of a non-aqueous electrolyte secondary cell that uses lithium cobalt oxide as a positive electrode active material. To this end, an element different from cobalt such as zirconium and titanium is added to the lithium cobalt oxide, acting as the positive electrode active material. The non-aqueous electrolyte contains a non-aqueous solvent containing diethyl carbonate at 10 to 30 volume percent on a base of 25 degree Celcius and contains an electrolyte salt.
摘要:
A positive electrode used in the non-aqueous electrolyte secondary battery of the present invention includes a hexagonal system lithium-containing cobalt composite oxide represented by the general expression ┌LiCo1-XMXO2 (M=Zr, Mg, Al)┘ obtained by synthesizing a lithium compound as a lithium source with a cobalt compound as a cobalt source to which 0.01 mol % or more and 1.0 mol % or less of zirconium is added and magnesium and/or aluminum is added through coprecipitation, as the positive electrode active material, whereby the thermal stability, load performance and charging/discharging cycle performance characteristics of the non-aqueous electrolyte secondary battery are improved without lowering its capacity and charging/discharging efficiency.
摘要:
A non-aqueous electrolyte secondary battery with excellent cycle characteristics and thermal stability in which the potential of the positive electrode active material ranges from 4.4V to 4.6 V based on lithium, and-charging method therefor are provided, wherein the positive electrode active substance of a non-aqueous electrolyte secondary battery comprises a hexagonal system of lithium-containing transition metal composite oxide formed by adding zirconium, magnesium, and aluminum as foreign elements upon synthesis of lithium cobalt oxide, with zirconium content ranging from 0.01 to 1 mol %, magnesium content ranging from 0.01 to 3 mol %, and aluminum content ranging from 0.01 to 3 mol %, and an Li/Co molar ratio ranging from 1.00 to 1.05.
摘要:
[Problem] To provide a nonaqueous electrolyte secondary battery exhibiting superior stability characteristics and having charge/discharge characteristics exhibiting a high-rate discharge stroke, even when a lithium-nickel-cobalt manganate and a spinel-type lithium manganate are used as the positive electrode active material. [Solution] A mixture having a specific ratio of a tungsten- and zirconium-modified lithium-nickel-cobalt manganate and a spinel-type lithium manganate is used as the positive electrode active material. Furthermore, a nonaqueous electrolyte having a specific ratio of the content of dimethyl carbonate and the content of a cyclic carbonate is used.
摘要:
To improve cycling characteristics by evening out the battery reaction across different areas of a laminated electrode assembly in a non-aqueous electrolyte secondary-cell battery where the laminated electrode assembly, having tape applied to a top layer, an end face, and a bottom layer thereof, is contained in an outer casing, the tape applied to the periphery of the laminated electrode assembly, configured from a stacked plurality of interleaved separators, cathode plates, and anode plates, extends in the stacking direction across the top layer, end face, and bottom layer of the laminated electrode assembly. Each piece of tape is formed of a base material that is one of styrene-butadiene rubber, styrene rubber, or butadiene rubber.