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1.发明授权
公开(公告)号：US5345000A
公开(公告)日：1994-09-06
申请号：US26126
申请日：1993-03-03
申请人： Nobuo Moriya , Keiji Shimoda , Sachio Asaoka , Takao Kameda , Kouji Sakashita , Tetsuo Maejima , Makoto Yasui , Hiroaki Nishijima , Nobuhiro Onda , Takeshi Kouzaki
发明人： Nobuo Moriya , Keiji Shimoda , Sachio Asaoka , Takao Kameda , Kouji Sakashita , Tetsuo Maejima , Makoto Yasui , Hiroaki Nishijima , Nobuhiro Onda , Takeshi Kouzaki
CPC分类号： B01D3/141 , C07C37/685 , C07C37/84
摘要： High purity, crystalline adduct of bisphenol A and phenol is produced multi-stage crystallization of a phenolic slurry of bisphenol A with a crystal separation and washing step being interposed between each of the two stages. Each of the crystallization stage includes a series of crystallization towers operated at decreasing temperatures. The crystallization of the slurry is performed by continuously discharging a portion of the slurry from each of the crystallization towers, introducing the discharged slurry into one or more coolers and then recycling the cooled slurry to the tower. Another portion of the slurry in each crystallization slurry is continuously discharged, heated for dissolving fine crystals of the adduct and then recycled to the crystallization tower so that large crystals are grown in each of the crystallization steps. An apparatus having a plurality of coolers and suitable for effecting the above crystallization is also disclosed.
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公开(公告)号：US5382711A
公开(公告)日：1995-01-17
申请号：US229349
申请日：1994-04-18
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005 % by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译： 通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。 结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。 当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。 用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。 苯酚的蒸发适宜地通过二阶段汽提进行，其中在第二阶段中使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。
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公开(公告)号：US5371304A
公开(公告)日：1994-12-06
申请号：US228871
申请日：1994-04-18
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukudome , Ryuichi Inaba , Takashi Imazeki , Karou Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukudome , Ryuichi Inaba , Takashi Imazeki , Karou Shimogawara
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译： 通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。 结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。 当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。 用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。 苯酚的蒸发适宜地通过两步蒸汽汽提进行，其中在第一阶段中使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。
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公开(公告)号：US5382712A
公开(公告)日：1995-01-17
申请号：US229348
申请日：1994-04-18
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译： 通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。 结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。 当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。 用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。 苯酚的蒸发适宜地通过二级蒸汽汽提进行，其中在第二阶段使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。
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公开(公告)号：US5324867A
公开(公告)日：1994-06-28
申请号：US912487
申请日：1992-07-13
申请人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
发明人： Sachio Asaoka , Tetsuo Maejima , Kouji Sakashita , Noriyuki Yoneda , Makoto Yasui , Nobuhiro Onda , Tsuneo Watanabe , Nobuo Moriya , Akio Shindo , Hiroaki Nishijima , Athumi Kukidome , Ryuichi Inaba , Takashi Imazeki , Kaoru Shimogawara
CPC分类号： C07C37/70 , C07C37/685 , C07C37/84
摘要： High quality bisphenol A is produced from a neutral crystalline adduct of bisphenol A and phenol by fusing the adduct in an atmosphere having a maximum oxygen content of 0.005% by volume, followed by evaporation of liberated phenol. The crystalline adduct may be mixed with an aliphatic carboxylic acid before the fusion to reduce the coloring of the product. When an acidic crystalline adduct is used, the use of a strong alkali salt of an aliphatic carboxylic acid is suitably used. Interior surfaces of the apparatuses for carrying out the fusion and evaporation are desirably washed with an organic solvent to remove oxygen therefrom. The evaporation of phenol is suitably performed by two stage steam stripping wherein a used stripping gas obtained in the second stage is employed as a stripping gas in the first stage while steam is used as the stripping gas in the second stage.
摘要翻译： 通过在最大氧含量为0.005体积％的气氛中将加合物熔合，然后蒸发释放的苯酚，由双酚A和苯酚的中性结晶加合物制备高品质双酚A。 结晶加合物可以在融合之前与脂族羧酸混合以减少产物的着色。 当使用酸性结晶加合物时，适合使用强酸性脂肪族羧酸碱金属盐。 用于进行熔化和蒸发的装置的内表面理想地用有机溶剂洗涤以从其中除去氧。 苯酚的蒸发适宜地通过二级蒸汽汽提进行，其中在第二阶段使用在第一阶段中获得的使用的汽提气体作为第一阶段的汽提气体，同时在第二阶段使用蒸汽作为汽提气体。
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6.发明授权
公开(公告)号：US5368827A
公开(公告)日：1994-11-29
申请号：US967373
申请日：1992-10-28
申请人： Nobuo Moriya , Keiji Shimoda , Kouji Sakashita , Hiroaki Nishijima , Nobuhiro Onda , Takeshi Kouzaki
发明人： Nobuo Moriya , Keiji Shimoda , Kouji Sakashita , Hiroaki Nishijima , Nobuhiro Onda , Takeshi Kouzaki
CPC分类号： B01D3/141 , C07C37/685 , C07C37/84
摘要： High purity, crystalline adduct of bisphenol A and phenol is produced multi-stage crystallization of a phenolic slurry of bisphenol A with a crystal separation and washing step being interposed between each of the two stages. Each of the crystallization stage includes a series of crystallization towers operated at decreasing temperatures. The crystallization of the slurry is performed by continuously discharging a portion of the slurry from each of the crystallization towers, introducing the discharged slurry into one or more coolers and then recycling the cooled slurry to the tower. Another portion of the slurry in each crystallization slurry is continuously discharged, heated for dissolving fine crystals of the adduct and then recycled to the crystallization tower so that large crystals are grown in each of the crystallization steps. An apparatus having a plurality of coolers and suitable for effecting the above crystallization is also disclosed.
摘要翻译： 双酚A和苯酚的高纯度结晶加合物产生双酚A的酚浆料的多阶段结晶，在两个阶段之间插入晶体分离和洗涤步骤。 每个结晶阶段包括在降低的温度下运行的一系列结晶塔。 浆料的结晶通过从每个结晶塔连续排出一部分浆料，将排出的浆料引入一个或多个冷却器中，然后将冷却的浆料再循环到塔中来进行。 每个结晶浆料中的浆料的另一部分被连续排出，加热以溶解加合物的微细晶体，然后再循环至结晶塔，使得在每个结晶步骤中生长大的晶体。 还公开了一种具有多个冷却器并适于实现上述结晶的设备。
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公开(公告)号：US5371302A
公开(公告)日：1994-12-06
申请号：US45204
申请日：1993-04-13
申请人： Hiroshi Yanai , Tadayoshi Matsuo , Masanori Nagase , Tsohikazu Maruyama , Toshihiko Furukawa , Katsuhiko Sakura , Yoshiaki Matsui , Takamasa Minami , Nobuo Moriya , Sachio Asaoka , Kouji Sakashita , Nobuyuki Suda , Keiji Shimoda , Susumu Yamamoto , Makoto Nomura
发明人： Hiroshi Yanai , Tadayoshi Matsuo , Masanori Nagase , Tsohikazu Maruyama , Toshihiko Furukawa , Katsuhiko Sakura , Yoshiaki Matsui , Takamasa Minami , Nobuo Moriya , Sachio Asaoka , Kouji Sakashita , Nobuyuki Suda , Keiji Shimoda , Susumu Yamamoto , Makoto Nomura
CPC分类号： C07C37/88
摘要： The invention relates to a process for preparing prilled bisphenol A by granulation which comprises adding compounds soluble in molten bisphenol A, not affecting adversely the melt color of bisphenol A to any significant extent, and have a melting point of 60.degree. C. or more to bisphenol A and granulating and also to a process which comprises adding the reaction mother liquor or cyrstallization mother liquor produced in the manufacturing step of bisphenol A to bisphenol A or the adduct of bispheol A and phenol or a mixture of bispheol A and phenol, removing the phenol, and granulating. The processes yield prilled bispheol A which have high strength and resist powdering.
摘要翻译： 本发明涉及一种通过造粒制备造粒双酚A的方法，其包括将可溶于熔融双酚A的化合物加入到任何显着程度上不会对双酚A的熔融颜色产生不利影响，并且熔点为60℃以上至 双酚A和造粒，还涉及一种方法，其包括将在双酚A的制备步骤中生产的反应母液或固化母液加入双酚A或双酚A和苯酚或双酚A和苯酚的混合物的加合物中，除去 苯酚和造粒。 该方法产生具有高强度和抗粉化的颗粒状双酚A。
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公开(公告)号：US5300699A
公开(公告)日：1994-04-05
申请号：US45206
申请日：1993-04-13
申请人： Toshihiko Furukawa , Katsuhiko Sakura , Kiyoshi Hashimoto , Nobuaki Egashira , Nobuo Moriya , Sachio Asaoka , Nobuyuki Suda , Susumu Yamamoto
发明人： Toshihiko Furukawa , Katsuhiko Sakura , Kiyoshi Hashimoto , Nobuaki Egashira , Nobuo Moriya , Sachio Asaoka , Nobuyuki Suda , Susumu Yamamoto
摘要： This invention relates to a process for preparing bisphenol A of good heat stability by heat-treating bisphenol A containing a very small amount of impurities in a molten state at 185.degree. to 220.degree. C. for 5 to 60 minutes in an oxygen-free atmosphere and the process yields bisphenol A of good heat stability which shows reduced coloration when heated. Bisphenol A prepared by this process has excellent properties relating to color and is particularly suitable as raw material for the manufacture of polycarbonates where the requirement for color is strict.
摘要翻译： 本发明涉及一种制备具有良好热稳定性的双酚A的方法，该方法是在无氧气氛中在185摄氏度至220摄氏度的熔融状态下热处理含有极少量杂质的双酚A 5至60分钟 并且该方法产生具有良好热稳定性的双酚A，其在加热时显示降低的着色。 通过该方法制备的双酚A具有与颜色相关的优异性质，并且特别适合作为用于制造颜色要求严格的聚碳酸酯的原料。
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公开(公告)号：US06307332B1
公开(公告)日：2001-10-23
申请号：US09525880
申请日：2000-03-15
IPC分类号： H05B3702
CPC分类号： H05B37/03
摘要： A light source having a lamp for generating light generates a lamp on signal at an output terminal thereof when the lamp is lit. A lamp life meter is connected to the light source for detecting the time that the lamp has been lit. The lamp life meter includes a housing having at least one contact terminal adapted to be coupled to the output terminal of the light source, a clock generator located in the housing and generating clock signals, a counter located in the housing and counting the clock signals whenever the clock on signal indicates that the lamp is on and a display mounted in the housing for displaying an indication of the time the lamp has been turned on.
摘要翻译： 具有用于产生光的灯的光源在灯点亮时在其输出端产生灯开启信号。 灯寿命计连接到光源，用于检测灯已经点亮的时间。 灯寿命计包括壳体，其具有适于耦合到光源的输出端的至少一个接触端子，位于壳体中并产生时钟信号的时钟发生器，位于壳体中的计数器，并且每时钟计数时钟信号 时钟接通信号表示灯已亮起，并且显示器安装在外壳中，用于显示灯已经开启的时间的指示。
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公开(公告)号：US5876469A
公开(公告)日：1999-03-02
申请号：US748723
申请日：1996-11-14
申请人： Nobuo Moriya , Takao Kawai , Hiroshi Yagi , Ryosuke Shimizu , Yasumasa Morita
发明人： Nobuo Moriya , Takao Kawai , Hiroshi Yagi , Ryosuke Shimizu , Yasumasa Morita
CPC分类号： H01M8/0631 , B01J8/067 , C01B3/384 , B01J2208/00212 , C01B2203/0233 , C01B2203/066 , C01B2203/0805 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0833 , C01B2203/0844 , C01B2203/0866 , C01B2203/1041 , C01B2203/1241 , C01B2203/80 , Y02P20/128
摘要： A reformed gas composed mainly of hydrogen and carbon monoxide to be used for a fuel cell is produced by using a multi-tubular reformer provided with bayonet type double-wall catalyst tubes and feeding hydrocarbon gas such as natural gas and steam to the reformer. Porous media of a ceramic material are arranged in such a manner in a shell side flue gas inlet part of the interior of the reformer as to envelop the leading end parts of the catalyst tubes. The transfer of heat from the flue gas to the catalyst tubes is enhanced because the porous media accumulate the heat from the flue gas and radiate the accumulated heat in the direction of the walls of the outer tubes of the catalyst tubes. The otherwise possible uneven transfer of heat to the catalyst tubes is prevented because the wall effect and the channelling of the flue gas are repressed. This invention, therefore, permits effective utilization of the thermal energy of the flue gas for the reforming reaction and enables the reformer to be stably operated.
摘要翻译： 通过使用设置有卡口式双壁催化剂管的多管重整器，并将碳氢化合物气体如天然气和蒸汽加入到重整器中，生产主要用于燃料电池的氢和一氧化碳的重整气体。 陶瓷材料的多孔介质以这种方式设置在重整器内部的壳侧烟道气入口部分中，以包封催化剂管的前端部分。 由于多孔介质积聚来自烟道气的热量并且在催化剂管的外管的壁的方向上辐射累积的热量，所以将热量从烟道气传递到催化剂管被增强。 否则可能不均匀地传递热量到催化剂管，因为壁效应和烟气的通道被压制。 因此，本发明允许有效利用用于重整反应的烟道气的热能，并使重整器稳定地工作。
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