公开(公告)号：US4514490A

公开(公告)日：1985-04-30

申请号：US530437

申请日：1983-09-08

申请人： Nobuo Seto ,  Takayoshi Kamio ,  Kozo Aoki

发明人： Nobuo Seto ,  Takayoshi Kamio ,  Kozo Aoki

IPC分类号： G03C7/32 ,  C07D231/22 ,  C07D405/12 ,  C07D405/14 ,  C07D487/04 ,  C07D521/00 ,  G03C7/38 ,  G03C7/384 ,  G03C1/46

CPC分类号： C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D405/12 ,  C07D405/14 ,  C07D487/04 ,  G03C7/384

摘要： A color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing therein a coupler represented by the following general formula (I):Q-B (I)wherein Q represents a coupler residue capable of forming a magenta color image upon the coupling reaction with an oxidation product of a developing agent; and B represents a group containing an unsubstituted or substituted methylenedioxybenzene group.The magenta coupler containing a methylenedioxybenzene group is useful in preventing the formation of yellow stain due to light irradiation in unexposed areas of a color photographic light-sensitive material after color development processing. Color images formed from the coupler are resistant to fading even if the color images obtained after color development processing are irradiated with light.

摘要翻译： 一种彩色摄影感光材料，包括其上具有卤化银乳剂层的载体，其中含有由以下通式（I）表示的成色剂：QB（I）其中Q表示能够形成品红色图像的成色剂残留物 与显影剂的氧化产物偶联反应; B表示含有未取代或取代的亚甲二氧基苯基的基团。 含有亚甲二氧基苯基的品红色成色剂可用于防止在显色处理后的彩色照相感光材料的未曝光区域中由于光照射而形成黄色斑点。 即使在彩色显影处理之后获得的彩色图像被照射，耦合器形成的彩色图像也能抗衰减。

公开(公告)号：US06444020B1

公开(公告)日：2002-09-03

申请号：US09551230

申请日：2000-04-17

申请人： Nobuo Seto ,  Takayoshi Kamio

发明人： Nobuo Seto ,  Takayoshi Kamio

IPC分类号： C09D1102

CPC分类号： C09D11/328 ,  C09B43/32 ,  C09B69/00

摘要： Disclosed are an azo dye having the following formula (1), an ink-jet ink comprising the aforesaid azo dye, an ink-jet recording method using the aforesaid ink-jet ink, and a thermal transfer recording material comprising the aforesaid azo dye: wherein Z represents an atomic group which forms, together with a nitrogen atom, a five-, six- or seven-membered ring, R1 represents a hydrogen atom, an oxy radical, an aliphatic group, an aliphatic oxy group, an acyl group, an aliphatic oxycarbonyl group, an aryloxycarbonyl group or an acyloxy group, R2, R3, R4 and R5, which may be the same or different, each represents an alkyl group, or R2 and R3 and/or R4 and R5 may be combined with each other to form a ring, and Dye represents a dye moiety group necessary for forming an azo dye.

摘要翻译： 公开了具有下式（1）的偶氮染料，包含上述偶氮染料的喷墨油墨，使用上述喷墨油墨的喷墨记录方法和包含上述偶氮染料的热转印记录材料： 其中Z表示与氮原子一起形成五元，六元或七元环的原子团，R 1表示氢原子，氧基，脂族基，脂族氧基，酰基， 脂族氧基羰基，芳氧基羰基或酰氧基，可以相同或不同的R 2，R 3，R 4和R 5各自表示烷基，或者R 2和R 3和/或R 4和R 5可以与每个 另外形成环，染料表示形成偶氮染料所需的染料部分基团。

公开(公告)号：US6010819A

公开(公告)日：2000-01-04

申请号：US138670

申请日：1998-08-24

申请人： Hiroshi Arakatsu ,  Nobuo Seto ,  Yoshisada Nakamura ,  Hironori Hiyoshi ,  Hiroyuki Watanabe ,  Takayoshi Kamio

发明人： Hiroshi Arakatsu ,  Nobuo Seto ,  Yoshisada Nakamura ,  Hironori Hiyoshi ,  Hiroyuki Watanabe ,  Takayoshi Kamio

IPC分类号： C09B29/46 ,  G03C7/392 ,  G03C8/40 ,  G03C8/26 ,  G03C7/46 ,  G03C8/10

CPC分类号： G03C8/408 ,  G03C7/39248

摘要： A method for improving light fastness of an image, which comprises releasing or forming an image forming dye or a precursor thereof corresponding or counter-corresponding to silver development and allowing an image formed by transferring said image forming dye or precursor thereof to coexist with a compound represented by general formula (I) in an image forming material ##STR1## The symbols in formula (I) are defined in the description. Also disclosed is an image forming material for use in the method.

摘要翻译： 一种用于提高图像的耐光性的方法，包括释放或形成与银显影相对应或对应于银显影的图像形成染料或其前体，并允许通过转印所述成像染料或其前体形成的图像与化合物共存 在图像形成材料中由通式（I）表示在说明书中定义式（I）中的符号。 还公开了用于该方法的成像材料。

公开(公告)号：US06399712B1

公开(公告)日：2002-06-04

申请号：US09522611

申请日：2000-03-10

申请人： Nobuo Seto ,  Takayoshi Kamio

发明人： Nobuo Seto ,  Takayoshi Kamio

IPC分类号： C08F800

CPC分类号： C08F226/06 ,  C08F212/14 ,  C08F220/34 ,  C08F246/00

摘要： A polymer compound is provided comprising at least one of the monomer units represented by the following formula (A) or formula (B): wherein R11 and R21 each represents a hydrogen atom, an oxy radical group, an alkyl group, an alkenyl group, an alkoxy group or an acyl group; R12 and R22 each represents a hydrogen atom or an alkyl group; Y1 and Y2 each represents ←CONR4—, ←COO— or ←CH(OH)CH2O—; X− represents a chlorine ion, a bromine ion, an iodine ion or a hydroxy ion; Z represents an atom group which together with the nitrogen atom forms a 5- to 7-membered heteroring; R13 and R23 each represents a hydrogen atom, a methyl group, an ethyl group or a halogen atom; R4 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and ← represents a bond to the main chain side of the polymer.

摘要翻译： 提供了包含由下式（A）或式（B）表示的单体单元中的至少一种的高分子化合物：其中R 11和R 21各自表示氢原子，氧自由基，烷基，烯基， 烷氧基或酰基; R 12和R 22各自表示氢原子或烷基; Y1和Y2各自表示←CONR4-，←COO-或←CH（OH）CH2O-; X-表示氯离子，溴离子，碘离子或羟基离子; Z表示与氮原子一起形成5-至7-元杂环的原子基团; R 13和R 23各自表示氢原子，甲基，乙基或卤素原子; R4表示氢原子或碳原子数1〜4的烷基。 ←表示与聚合物的主链侧的键。

公开(公告)号：US06232469B1

公开(公告)日：2001-05-15

申请号：US09400301

申请日：1999-09-21

申请人： Nobuo Seto ,  Takayoshi Kamio

发明人： Nobuo Seto ,  Takayoshi Kamio

IPC分类号： C07D21158

CPC分类号： C09K15/30 ,  B41M5/5227 ,  C07D211/58 ,  C07D211/94

摘要： A novel 4-acylamino-2,2,6,6-tetramethylpiperidine derivatives and antioxidants comprising the same. The 4-acylamino-2,2,6,6-tetramethylpiperidine derivatives are represented by formula (A): wherein R1 represents a hydrogen atom, a hydroxyl group, an oxyradical group, an aliphatic group, an acyl group, an aliphatic oxy group or an acyloxy group; and R2 represents an aliphatic group having at least 3 carbon atoms and at least two hydroxyl groups.

摘要翻译： 一种新的4-酰基氨基-2,2,6,6-四甲基哌啶衍生物和包含其的抗氧化剂。4-酰基氨基-2,2,6,6-四甲基哌啶衍生物由式（A）表示：其中R1表示氢 原子，羟基，氧自由基，脂族基，酰基，脂族氧基或酰氧基; 并且R 2表示具有至少3个碳原子和至少两个羟基的脂族基团。

公开(公告)号：US5731140A

公开(公告)日：1998-03-24

申请号：US742152

申请日：1996-10-31

申请人： Takayoshi Kamio ,  Nobuo Seto ,  Hironori Hiyoshi

发明人： Takayoshi Kamio ,  Nobuo Seto ,  Hironori Hiyoshi

IPC分类号： C07D231/38 ,  C09B29/00 ,  C09B29/12 ,  G03C8/10 ,  G03C8/40 ,  G03C8/20 ,  G03C8/22

CPC分类号： C09B29/0037 ,  G03C8/10

摘要： A pyrazolylazophenol dye exhibiting excellent spectral characteristics and having high fastness to light, heat, air or chemicals, and a color light-sensitive material containing an image forming compound comprising the dye, which releases a magenta dye exhibiting excellent spectral characteristics and having high fastness to light, heat, air or chemicals.

摘要翻译： 具有优异的光谱特性并且对光，热，空气或化学品具有高耐牢度的吡唑基偶氮染料和含有包含染料的成像化合物的彩色感光材料，其释放出具有优异光谱特性并具有高坚牢度的品红染料 光，热，空气或化学品。

公开(公告)号：US4587210A

公开(公告)日：1986-05-06

申请号：US595195

申请日：1984-03-30

申请人： Michio Ono ,  Masakazu Morigaki ,  Takayoshi Kamio ,  Kozo Aoki ,  Kazuhiko Furuya

发明人： Michio Ono ,  Masakazu Morigaki ,  Takayoshi Kamio ,  Kozo Aoki ,  Kazuhiko Furuya

IPC分类号： G03C7/26 ,  G03C7/392 ,  G03C1/08 ,  G03C7/32

CPC分类号： G03C7/39216

摘要： A color photographic silver halide light-sensitive material is described, characterized by containing at least one of the compounds represented by the general formula (I) and their precursors. ##STR1## wherein R represents ##STR2## (wherein R.sub.1 and R.sub.2 are each a hydrogen atom or an alkyl group and may combine with R.sub.3 to form a ring having 5 to 10 carbon atoms, provided that R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, R.sub.3 is a substituted or unsubstituted aryl group, and n is an integer of 1 to 4), and R' has 1 to 20 carbon atoms and represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituent defined by R as defined above). This light-sensitive material provides color images which are stabilized, i.e., freed of fading and the discoloration of the white ground.

摘要翻译： 描述了彩色照相卤化银感光材料，其特征在于含有至少一种由通式（I）表示的化合物及其前体。 式（I）其中R表示（其中R 1和R 2各自为氢原子或烷基，并且可以与R 3结合形成具有5至10个碳原子的环，条件是R 1和R 2不为 氢原子，R3为取代或未取代的芳基，n为1〜4的整数），R'为碳原子数1〜20，表示取代或未取代的烷基，取代或未取代的环烷基 基团，取代或未取代的芳基或由如上定义的R定义的取代基）。 该感光材料提供稳定的彩色图像，即，消除白色地面的褪色和变色。

公开(公告)号：US4579813A

公开(公告)日：1986-04-01

申请号：US645148

申请日：1984-08-28

申请人： Kozo Aoki ,  Takayoshi Kamio ,  Toshiyuki Watanabe

发明人： Kozo Aoki ,  Takayoshi Kamio ,  Toshiyuki Watanabe

IPC分类号： G03C7/34 ,  C07C67/00 ,  C07C239/00 ,  C07C275/40 ,  G03C7/305 ,  G03C1/46

CPC分类号： G03C7/30523

摘要： A silver halide color photographic material comprising a support having thereon at least a silver halide emulsion layer is described, wherein the photographic material contains a cyan dye-forming coupler represented by formula (I) ##STR1## wherein R represents an unsubstituted or substituted alkyl, aryl, or heterocylic ring group; B represents --O-- or --NR.sub.1 --, wherein R.sub.1 represents a hydrogen atom or an unsubstituted or substituted alkyl or aryl group; Z represents an unsubstituted or substituted aryl group or an alkyl or aralkyl group substituted by a carboxy group or a hydroxy group; A represents a substituted aryl group, or a substituted or unsubstituted heterocyclic ring group; and m represents 0 or 1, provided that when m is 0 the substituent is not an alkoxy group, a halogen atom or a cyano group.

摘要翻译： 描述了包含其上至少具有卤化银乳剂层的载体的卤化银彩色照相材料，其中照相材料含有由式（I）表示的青色染料形成成色剂，其中R表示未取代或未取代的 取代的烷基，芳基或杂环基团; B表示-O-或-NR1-，其中R1表示氢原子或未取代或取代的烷基或芳基; Z表示未取代或取代的芳基或被羧基或羟基取代的烷基或芳烷基; A表示取代的芳基或取代或未取代的杂环基; m表示0或1，条件是当m为0时，取代基不是烷氧基，卤素原子或氰基。

公开(公告)号：US4477558A

公开(公告)日：1984-10-16

申请号：US487494

申请日：1983-04-21

申请人： Akira Ogawa ,  Kozo Aoki ,  Takayoshi Kamio

发明人： Akira Ogawa ,  Kozo Aoki ,  Takayoshi Kamio

IPC分类号： C09B53/00 ,  G03C7/34 ,  G03C7/16

CPC分类号： G03C7/346

摘要： A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, the color photographic light-sensitive material containing a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a heterocyclic group; X represents a hydrogen atom or a group capable of being released upon an oxidative coupling reaction with a developing agent; R.sup.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group.The cyan dye forming coupler represented by the general formula (I) has a good solubility in an organic solvent having a high boiling point and a high dye forming rate even in a color developing solution which does not contain benzyl alcohol and provides a cyan color image having a high maximum density and excellent fastness to light. Further, a decrease in optical density of the cyan color image is not substantially observed even when the color photographic light-sensitive material is processed with a bleaching solution which has a weak oxidation power or a bleaching solution which is exhausted.

摘要翻译： 一种卤化银彩色照相感光材料，其包含其上具有至少一个卤化银乳剂层的载体，所述彩色照相感光材料含有由以下通式（I）表示的形成青色染料的成色剂： ）其中R表示取代或未取代的烷基，取代或未取代的芳基或杂环基; X表示氢原子或与显影剂进行氧化偶联反应时能够释放的基团; R1表示取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂环基。 由通式（I）表示的青色染料形成成色剂即使在不含苄醇的显色溶液中也具有高沸点和高染料形成速率的有机溶剂中的良好溶解性并提供青色图像 具有高的最大密度和优异的耐光牢度。 此外，即使当用具有弱氧化功能的漂白溶液或耗尽的漂白溶液处理彩色照相感光材料时，也基本上不观察到青色图像的光密度的降低。

公开(公告)号：US06458194B1

公开(公告)日：2002-10-01

申请号：US09676226

申请日：2000-09-29

申请人： Hisashi Mikoshiba ,  Takayoshi Kamio

发明人： Hisashi Mikoshiba ,  Takayoshi Kamio

IPC分类号： C09D1100

CPC分类号： B41M5/388 ,  C09B29/0092 ,  C09B29/3647 ,  C09D11/328

摘要： A dye compound excellent in transfer property and color fastness against light, a yellow dye excellent in light absorption property, a yellow dye compound for thermal transfer dye donating material excellent in solubility and a dye compound which can be synthesized with ease from readily-available source materials are provided. A dye compound of the present invention is expressed by the general formula (1): or a salt thereof, wherein R1, R2, R3 and R4 independently represent a hydrogen atom or a substituent.

摘要翻译： 对光的转印性和色牢度优异的染料化合物，光吸收性优异的黄色染料，溶解度优异的热转印染料赋予材料的黄色染料化合物和易于得到的源可以合成的染料化合物 提供材料。 本发明的染料化合物由通式（1）表示：或其盐，其中R 1，R 2，R 3和R 4独立地表示氢原子或取代基。