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19 条记录 (耗时 0.028 秒)

    Polybutadiene composition and process for producing same
    1.
    发明授权
    Polybutadiene composition and process for producing same 失效
    聚丁二烯组合物及其制备方法

    公开(公告)号：US5468822A

    公开(公告)日：1995-11-21

    申请号：US193806

    申请日：1994-02-08

    申请人： Nohiro Tsujimoto ,  Kenichi Hongyo ,  Yoshisuke Baba ,  Michinori Suzuki ,  Kazuhiro Akikawa

    发明人： Nohiro Tsujimoto ,  Kenichi Hongyo ,  Yoshisuke Baba ,  Michinori Suzuki ,  Kazuhiro Akikawa

    IPC分类号： C08F2/18 ,  C08F36/06 ,  C08F136/06 ,  C08L9/00

    CPC分类号： C08F36/06 ,  C08F136/06 ,  C08L9/00 ,  C08L2205/02 ,  Y10T428/2982

    摘要： A 1,2-polybutadiene composition having an excellent reinforcing effect for rubber and synthetic resin materials including at least two polybutadiene components different in melting point from each other and each having, as a main structure, a 1,2-polybutadiene structure, produced by polymerizing a 1,3-butadiene-containing monomer in a water-containing polymerization system in the presence of a catalyst comprising a transition metal compound, an organic compound of one of the Group I to III metals, and one of carbon disulfide, phenyl isothiocyanate, and xanthic acid compounds, while adding a melting point-regulating agent comprising at least one of ketones, aldehydes, alcohols, esters, nitriles, sulfoxides, amides, and phosphoric acid esters in one or two or more separate adding operations or a continuous adding operation.

    摘要翻译： 一种对橡胶和合成树脂材料具有优异的增强效果的1,2-聚丁二烯组合物，其包括彼此不同熔点的至少两种聚丁二烯组分，并且各自具有作为主要结构的1,2-聚丁二烯结构，其由 在包含过渡金属化合物，第I至III族金属之一的有机化合物和二硫化碳之一，异硫氰酸苯酯的催化剂存在下，在含水聚合体系中聚合含1,3-丁二烯的单体 和黄原酸化合物，同时在一个或两个或更多个单独的添加操作中添加包含酮，醛，醇，酯，腈，亚砜，酰胺和磷酸酯中的至少一种的熔点调节剂，或连续添加 操作。

    Aqueous suspension polymerization of 1,3-butadiene to produce syndiotactic-1,2-polybutadiene
    2.
    发明授权
    Aqueous suspension polymerization of 1,3-butadiene to produce syndiotactic-1,2-polybutadiene 失效
    1,3-丁二烯的水悬浮聚合产生间规-1,2-聚丁二烯

    公开(公告)号：US5346971A

    公开(公告)日：1994-09-13

    申请号：US59293

    申请日：1993-05-11

    申请人： Kenichi Hongyo ,  Michinori Suzuki ,  Kazuhiro Akikawa

    发明人： Kenichi Hongyo ,  Michinori Suzuki ,  Kazuhiro Akikawa

    IPC分类号： C08F2/18 ,  C08F136/06

    CPC分类号： C08F136/06

    摘要： A process for producing polybutadiene essentially consisted of syndiotactic-1,2-polybutadiene in an aqueous medium includes a step off polymerizing diene essentially consisted of 1,3-butadiene in the presence of: (A) a catalyst composition including (a) a transition metal compound, and (b) an organometallic compound which includes a metal selected from the elements consisting off groups 1, 2, 12, and 13 of Periodic Table; (B) an initiator comprising at least one component selected from a group consisting of carbon disulfide, an isothiocyanate compound, and a xanthogenic compound; and (C) an inert organic liquid having a density of at least 1.10, thereby resultant particles of syndiotactic-1,2-polybutadiene have a diameter up to 2 min.

    摘要翻译： 在水性介质中基本上由间同立构1,2-聚丁二烯组成的聚丁二烯的制备方法包括：在（A）催化剂组合物的存在下，基本上由1,3-丁二烯组成的聚合二烯基聚合二烯：（a） 金属化合物，和（b）有机金属化合物，其包含选自元素周期表第1,2,12族和13族元素的金属; （B）包含至少一种选自二硫化碳，异硫氰酸酯化合物和致黄色化合物的组分的引发剂; 和（C）密度为至少1.10的惰性有机液体，从而得到间同立构1,2-聚丁二烯的颗粒直径达2分钟。

    Process of production of 3,4,3',4'-substituted biphenyl compound
    3.
    发明授权
    Process of production of 3,4,3',4'-substituted biphenyl compound 失效
    制备3,4,3'，4'-取代的联苯二酚化合物的方法

    公开(公告)号：US5243067A

    公开(公告)日：1993-09-07

    申请号：US655361

    申请日：1991-02-20

    申请人： Akinori Shiotani ,  Michinori Suzuki ,  Fumio Matsuo

    发明人： Akinori Shiotani ,  Michinori Suzuki ,  Fumio Matsuo

    IPC分类号： B01J31/04 ,  B01J31/22 ,  B01J31/28 ,  C07B61/00 ,  C07C51/09 ,  C07C51/353 ,  C07C51/60 ,  C07C51/62 ,  C07C63/331 ,  C07C69/76

    CPC分类号： C07C63/331 ,  C07C51/09

    摘要： A 3,4,3',4'-substituted biphenyl compound represented by the general formula (II): ##STR1## wherein, one of R.sup.1 and R.sup.2 is a -CH.sub.3 group and the one other is a --COOR.sup.5 group, --COOH group, or --COCl group, and one of R.sup.3 and R.sup.4 is a -CH.sub.3 group and the other one is a --COOR.sup.5 group, --COOH group, or --COCl group, is produced by the steps of oxidatively coupling an o-toluic acid alkyl ester in the presence of a catalyst containing a mixture of palladium salts with 1,10-phenanthroline or .alpha.,.alpha.'-bipyridine, a chelating product of a palladium salt with 1,10-phenanthroline, or a chelating products of a palladium salt with .alpha.,.alpha.'-bipyridine, in an atmosphere containing molecular oxygen, to selectively produce a 3,4,3,',4'-substituted dimethyl biphenyl dicarboxylic acid dialkyl esters having a biphenyl ring structure; optionally converting this dialkyl ester compound to a corresponding dimethyl biphenyl dicarboxylic acid, and then optionally further converting this to a corresponding dimethyl biphenyl dicarboxylic acid dichloride.

    摘要翻译： PCT No.PCT / JP90 / 00537 371日期1991年2月20日 102（e）日期1991年2月20日PCT 1990年4月25日PCT PCT。 出版物WO91 / 02713 1991年3月7日。由通式（II）表示的3,4,3'，4'-取代的联苯化合物：其中，R 1和R 2中的一个是-CH 3基团， 另一个是-COOR 5基团，-COOH基团或-COCl基团，R3和R4之一是-CH3基团，另一个是-COOR5基团，-COOH基团或-COCl基团，由 在含有钯盐与1,10-菲咯啉或α，α'-联吡啶，钯盐与1,10-菲咯啉的螯合产物的混合物的催化剂存在下，将邻甲苯甲酸烷基酯氧化偶联的步骤， 菲咯啉或钯盐与α，α'-联吡啶在含有分子氧的气氛中的螯合产物，以选择性地制备具有联苯的3,4,3'，4'-取代的二甲基联苯二羧酸二烷基酯 环结构; 任选地将该二烷基酯化合物转化成相应的二甲基联苯二羧酸，然后任选进一步将其转化为相应的二甲基联苯二羧酸二氯化物。

    Process for producing conjugated diene polymer
    4.
    发明授权
    Process for producing conjugated diene polymer 有权
    共轭二烯聚合物的制造方法

    公开(公告)号：US08304503B2

    公开(公告)日：2012-11-06

    申请号：US13133547

    申请日：2009-12-25

    申请人： Michinori Suzuki ,  Koji Shiba ,  Masato Murakami

    发明人： Michinori Suzuki ,  Koji Shiba ,  Masato Murakami

    IPC分类号： C08F4/44 ,  C08F136/06

    CPC分类号： C08F36/04 ,  C08F4/545

    摘要： Disclosed is a process for producing a conjugated diene polymer having a very high content of cis-1,4 structures by using an yttrium compound-containing catalyst that is relatively easy to handle and has a high activity. Specifically disclosed is a process for producing a conjugated diene polymer containing cis-1,4 structures at a ratio of 99% or higher, which is characterized by polymerizing a conjugated diene in the presence of a catalyst produced from (A) a specific yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound.

    摘要翻译： 公开了通过使用相对容易处理并具有高活性的含钇化合物的催化剂制备具有非常高含量顺式-1,4结构的共轭二烯聚合物的方法。 具体公开了一种以99％以上的比例制造含顺式-1,4-结构的共轭二烯系聚合物的方法，其特征在于，在（A）特定的钇化合物 ，（B）由非配位阴离子和阳离子组成的离子化合物，和（C）有机铝化合物。

    Polybutadiene and process for producing the same
    5.
    发明授权
    Polybutadiene and process for producing the same 有权

    公开(公告)号：US06664347B2

    公开(公告)日：2003-12-16

    申请号：US10234391

    申请日：2002-09-05

    申请人： Michinori Suzuki ,  Masato Murakami

    发明人： Michinori Suzuki ,  Masato Murakami

    IPC分类号： C08F406

    CPC分类号： C08C19/26

    摘要： Modified polybutadiene having a high-cis and low-trans structure with a moderate 1,2-structure content and exhibiting improved characteristics such as cold flow properties, which is obtained by modifying starting polybutadiene having a Tcp/ML1+4 ratio (Tcp: 5% toluene solution viscosity at 25° C.ML1+4: Mooney viscosity at 100° C.) of 2.5 or more in the presence of a transition metal catalyst.

    Catalyst for producing conjugated diene polymer
    9.
    发明授权
    Catalyst for producing conjugated diene polymer 失效
    用于制备共轭二烯聚合物的催化剂

    公开(公告)号：US6071845A

    公开(公告)日：2000-06-06

    申请号：US761697

    申请日：1996-12-06

    申请人： Nobuhiro Tsujimoto ,  Michinori Suzuki ,  Kei Tsukahara ,  Shigeru Ikai ,  Koji Imaoka ,  Yoshiyuki Kai ,  Jun Yamashita

    发明人： Nobuhiro Tsujimoto ,  Michinori Suzuki ,  Kei Tsukahara ,  Shigeru Ikai ,  Koji Imaoka ,  Yoshiyuki Kai ,  Jun Yamashita

    IPC分类号： C07F17/00 ,  C08F4/625 ,  C08F4/639 ,  C08F4/6392 ,  C08F4/68 ,  C08F10/00 ,  C08F36/04

    CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F36/04 ,  C08F4/68 ,  C08F4/63908 ,  C08F4/63912 ,  C08F4/6392 ,  Y10S526/943

    摘要： A catalyst obtained by contacting (A) a compound of a transition metal of the group V of the Periodic Table represented by formula (I):R.sub.n M(O).sub.m X.sub.p .cndot.L.sub.a (I)wherein M represents a transition metal of the group V of the Periodic Table; R represents a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group or a substituted fluorenyl group; O represents an oxygen atom; X represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group, an aryloxy group or an amido group; L represents a Lewis basic compound; n, m, and p each represent an integer selected to make a combination of (n=1, m=1, p=2), (n=1, m=0, p=3), (n=2, m=0, p=1) or (n=1, m=0, p=2); and a represents 0, 1 or 2, and (B) at least one of (B1) an ionic compound comprising a non-coordinating anion and a cation and (B2) an aluminoxane, provided that the component (B) is an ionic compound comprising a non-coordinating anion and a cation (B1) when the combination of n, m, and p of the component (A) is (n=2, m=0, p=1) or (n=1, m=0, p=2).

    摘要翻译： 通过使（A）由式（I）表示的周期表的第V族的过渡金属的化合物：RnM（O）m X pLa（I）与M表示第V族的过渡金属 周期表; R表示环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基或取代的芴基; O表示氧原子; X表示氢原子，卤素原子，碳原子数1〜20的烃基，烷氧基，芳氧基或酰胺基; L代表路易斯碱性化合物; n，m和p各自表示选择以使（n = 1，m = 1，p = 2），（n = 1，m = 0，p = 3），（n = = 0，p = 1）或（n = 1，m = 0，p = 2）; 和（B）包含非配位阴离子和阳离子的离子化合物和（B2）铝氧烷中的至少一种，（B）组分（B）是离子化合物 当组分（A）的n，m和p的组合为（n = 2，m = 0，p = 1）或（n = 1，m = 1）时，包含非配位阴离子和阳离子（B1） 0，p = 2）。