Trivalent antimony catalyst
    1.
    发明授权
    Trivalent antimony catalyst 失效
    三价锑催化剂

    公开(公告)号:US3935170A

    公开(公告)日:1976-01-27

    申请号:US546794

    申请日:1975-02-03

    摘要: A novel antimony catalyst for polyester condensation reactions is described comprising trivalent antimony having its valences occupied by dianion radicals of 1,2-diols and anion radicals or organic carboxylic acids. The molar ratio of antimony to dianion radical of 1,2-diol to anion radical of organic carboxylic acid is 1:1:1. The antimony compound is prepared by reacting a mixture of a 1,2-diol and a trivalent antimony reactant represented by the formula; ##EQU1## wherein Sb is antimony, R.sub.1 is an anion radical of an organic carboxylic acid; and R.sub.2 is selected from the group consisting of anions of alcohols, anions of organic carboxylic acids and mixtures thereof.

    摘要翻译: 描述了一种用于聚酯缩合反应的新型锑催化剂,其包含其价态被1,2-二醇和阴离子基团或有机羧酸的二阴离子占据的三价锑。 1,2-二醇与有机羧酸阴离子自由基的锑与二阴离子自由基的摩尔比为1:1:1。 锑化合物通过使1,2-二醇和由式表示的三价锑反应物的混合物反应来制备; R2是Sb,其中Sb是锑,R1是有机羧酸的阴离子基团; 并且R 2选自醇阴离子,有机羧酸的阴离子及其混合物。