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    RECOVERY OF PHENOL LIGANDS DURING THE PRODUCTION OF ISOPULEGOL
    2.
    发明申请
    RECOVERY OF PHENOL LIGANDS DURING THE PRODUCTION OF ISOPULEGOL 有权
    在生产ISOPULEGOL期间恢复苯酚配体

    公开(公告)号：US20100016642A1

    公开(公告)日：2010-01-21

    申请号：US12439325

    申请日：2007-08-31

    Applicant: Gunnar Heydrich ,  Gabriele Gralla ,  Klaus Ebel ,  Marko Friedrich

    Inventor： Gunnar Heydrich ,  Gabriele Gralla ,  Klaus Ebel ,  Marko Friedrich

    IPC: C07C35/17 ,  C07C35/12

    CPC classification number: C07C29/80 ,  B01J31/0214 ,  B01J31/143 ,  B01J31/4015 ,  C07B2200/07 ,  C07C29/172 ,  C07C29/56 ,  C07C35/12 ,  C07C35/17 ,  C07C2601/14 ,  Y02P20/584

    Abstract: The present invention relates to a method of working up an aluminum-containing reaction product from the production of isopulegol by cyclization of citronellal in the presence of complex compounds, comprising at least one ligand of the formula (I), where R1, R2, R3 are chosen from hydrogen, halogen, nitro, C1-C8-alkyl, C1-C8-alkoxy, di(C1-C4-alkyl)amino and aryl; R4, R5 are chosen from halogen, nitro, C1-C8-alkyl, C1-C8-alkoxy, di(C1-C4-alkyl)amino, aryl or heteroaryl; in which a) the reaction product is subjected to distillative separation to obtain an isopulegol-enriched top product and an isopulegol-depleted bottom product and b) the ligand of the formula (I) is separated off from the bottom product. Moreover, the invention relates to a method of producing isopulegol, and to a method of producing menthol.

    Abstract translation: 本发明涉及一种通过在复合化合物存在下环绕香茅醛来制备含铝反应产物的方法，所述复合化合物包含至少一种式（I）的配体，其中R1，R2，R3 选自氢，卤素，硝基，C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基，二（C 1 -C 4 - 烷基）氨基和芳基; R4，R5选自卤素，硝基，C1-C8-烷基，C1-C8-烷氧基，二（C1-C4-烷基）氨基，芳基或杂芳基; 其中a）将反应产物进行蒸馏分离，以获得富含异头翁醇的顶部产物和异胡列胆素的底部产物，和b）将式（I）的配体与底部产物分离。 此外，本发明涉及一种生产异胡母醇的方法和一种制备薄荷醇的方法。

    Polymer incarcerated lewis acid metal catalyst
    4.
    发明申请
    Polymer incarcerated lewis acid metal catalyst 有权
    聚合物监控路威酸金属催化剂

    公开(公告)号：US20070191624A1

    公开(公告)日：2007-08-16

    申请号：US10591829

    申请日：2005-03-08

    Applicant: Shu Kobayashi ,  Ryo Akiyama ,  Nobuyuki Kawai ,  Masahiro Takeuchi

    Inventor： Shu Kobayashi ,  Ryo Akiyama ,  Nobuyuki Kawai ,  Masahiro Takeuchi

    IPC: C07C253/10 ,  C07C209/20 ,  B01J31/00

    CPC classification number: C07C67/347 ,  B01J13/14 ,  B01J31/165 ,  B01J31/2239 ,  B01J31/226 ,  B01J31/4015 ,  B01J2231/326 ,  B01J2231/346 ,  B01J2231/348 ,  B01J2231/4205 ,  B01J2231/44 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/35 ,  B01J2531/37 ,  B01J2531/38 ,  B01J2531/842 ,  B01J2540/22 ,  C07C45/46 ,  C07C45/511 ,  C07C45/72 ,  C07C45/73 ,  C07C49/245 ,  C07C49/573 ,  C07C49/76 ,  C07C49/83 ,  C07C67/00 ,  C07C227/12 ,  C07C327/22 ,  C07C2601/08 ,  C07C2602/08 ,  C07C2602/10 ,  Y02P20/584 ,  C07C69/732 ,  C07C69/738 ,  C07C69/757 ,  C07C229/34

    Abstract: The objective is to incarcerate a Lewis acid metal in a polymer and to make this catalyst recoverable while maintaining its function as a Lewis acid metal catalyst. The present invention is a polymer-incarcerated Lewis acid metal catalyst in which a Lewis acid metal is incarcerated in a crosslinked polymer and the crosslinked polymer is crosslinked using the crosslinking groups contained in a crosslinkable polymer. The polymer incarcerated Lewis acid metal catalyst is characterized by the crosslinkable polymer containing at least one type of monomer unit containing hydrophobic substituents and hydrophilic substituents containing crosslinking groups, and the hydrophobic substituents contain aromatic substituents. This crosslinkable polymer preferably comprises at least one type of monomer unit containing hydrophobic substituents and hydrophilic substituents containing crosslinking groups and a monomer unit containing hydrophobic substituents. This catalyst can be obtained by subjecting a polymer micelle incarcerated Lewis acid metal obtained by mixing an organic solution containing a crosslinkable polymer and a Lewis acid metal with a bad solvent to a crosslinking reaction. This catalyst is useful as a catalyst in aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions.

    Abstract translation: 目的是监测聚合物中的路易斯酸金属，并使该催化剂可恢复，同时保持其作为路易斯酸金属催化剂的功能。 本发明是一种聚合物 - 监控的路易斯酸金属催化剂，其中路易斯酸金属在交联聚合物中被监控，交联聚合物使用可交联聚合物中所含的交联基团进行交联。 聚合物监控的路易斯酸金属催化剂的特征在于含有至少一种含有疏水取代基的单体单元和含有交联基团的亲​​水取代基的交联聚合物，疏水性取代基含有芳族取代基。 该可交联聚合物优选包含至少一种含有疏水取代基的单体单元和含有交联基团的亲​​水取代基和含有疏水取代基的单体单元。 该催化剂可以通过将通过将含有可交联聚合物的有机溶液和路易斯酸金属得到的聚合物胶束监控的路易斯酸金属与不良溶剂进行交联反应来获得。 该催化剂可用作醛醇反应，硅烷醇化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和Friedel Crafts反应中的催化剂。

    Method of reaction with soluble metallic catalyst and anion-exchange resin, method of recovering the soluble metallic catalyst, and method of reuse
    5.
    发明授权
    Method of reaction with soluble metallic catalyst and anion-exchange resin, method of recovering the soluble metallic catalyst, and method of reuse 失效
    与可溶性金属催化剂和阴离子交换树脂反应的方法，回收可溶性金属催化剂的方法和再利用方法

    公开(公告)号：US06958413B2

    公开(公告)日：2005-10-25

    申请号：US10104054

    申请日：2002-03-25

    Applicant: Takafumi Kubo

    Inventor： Takafumi Kubo

    IPC: B01J31/04 ,  B01J31/08 ,  B01J31/34 ,  B01J31/40 ,  B01J38/74 ,  C07B61/00 ,  C07C67/26 ,  C07C67/24

    CPC classification number: C07C67/26 ,  B01J31/04 ,  B01J31/08 ,  B01J31/4015 ,  B01J31/403 ,  B01J38/74 ,  C07B61/00 ,  Y02P20/584 ,  C07C69/16 ,  C07C69/26 ,  C07C69/54 ,  C07C69/28

    Abstract: The invention provides a method of liquid-phase reaction using a soluble metallic catalyst in which the soluble metallic catalyst is caused to coexist with an anion-exchange resin during the reaction and the reaction is conducted under such conditions that 50% or more of the soluble metallic catalyst is adsorbed onto the anion-exchange resin. The anion-exchange resin having the soluble metallic catalyst adsorbed thereon is separated from the liquid reaction mixture to thereby recover the soluble metallic catalyst and reuse it in a liquid-phase reaction. The soluble metallic catalyst is efficiently used, recovered, and reused with great ease at low cost in various liquid-phase reactions using the soluble metallic catalyst.

    Abstract translation: 本发明提供了一种使用可溶性金属催化剂的液相反应方法，其中可溶性金属催化剂在反应期间与阴离子交换树脂共存，并且反应在50％或更多的可溶性 金属催化剂被吸附在阴离子交换树脂上。 将其上吸附有可溶性金属催化剂的阴离子交换树脂与液体反应混合物分离，从而回收可溶性金属催化剂，并将其再次用于液相反应。 可溶性金属催化剂在使用可溶性金属催化剂的各种液相反应中以低成本很容易地被有效地使用，回收和再利用。

    Method for separation of reaction products from catalysts
    6.
    发明授权
    Method for separation of reaction products from catalysts 失效
    反应产物与催化剂分离的方法

    公开(公告)号：US06939993B2

    公开(公告)日：2005-09-06

    申请号：US10415667

    申请日：2001-10-25

    Applicant: Michihiro Sugahara

    Inventor： Michihiro Sugahara

    IPC: B01J31/02 ,  B01J31/40 ,  B01J38/00 ,  B01J38/56 ,  C07B63/00 ,  C07C45/32 ,  C07C45/34 ,  C07C45/80 ,  C07C49/447 ,  C07C45/00 ,  C07C27/26 ,  C07C43/11 ,  C07D207/40 ,  C07D209/04

    CPC classification number: B01J31/0247 ,  B01J31/40 ,  B01J31/4015 ,  B01J2531/845 ,  C07C45/34 ,  C07C45/80 ,  Y02P20/584 ,  C07C49/653 ,  C07C49/637

    Abstract: Method for separating reaction product from imide compound catalyst represented by Formula (1) or derivative thereof in reaction mixture obtained by reaction in presence of imide compound catalyst: wherein R1 and R2 are each, for example, a hydrogen atom or an alkyl group, where R1 and R2 may be combined to form a double bond, an aromatic ring, or a non-aromatic ring, and X is an oxygen atom or a hydroxyl group. The method includes an extraction process using two organic solvents separable from each other to thereby separate the reaction product into one organic solvent layer and the imide compound catalyst component into the other organic solvent layer. The disclosed method efficiently and simply separates the reaction product from the catalyst component.

    Abstract translation: 在通过在酰亚胺化合物催化剂存在下反应获得的反应混合物中分离由式（1）表示的酰亚胺化合物催化剂或其衍生物的反应产物的方法：其中R 1和R 2 各自为例如氢原子或烷基，其中R 1和R 2可以结合形成双键，芳环或 非芳香环，X为氧原子或羟基。 该方法包括使用两个可分离的有机溶剂的提取方法，从而将反应产物分离成一个有机溶剂层和酰亚胺化合物催化剂组分到另一个有机溶剂层中。 所公开的方法有效且简单地将反应产物与催化剂组分分离。

    Lewis acid catalyst composition
    8.
    发明申请
    Lewis acid catalyst composition 失效
    路易斯酸催化剂组合物

    公开(公告)号：US20040242411A1

    公开(公告)日：2004-12-02

    申请号：US10491532

    申请日：2004-04-02

    Inventor： Joji Nishikido ,  akihiro Yoshida ,  Masanori Ikeda

    IPC: B01J031/00

    CPC classification number: B01J31/0224 ,  B01J31/0252 ,  B01J31/0271 ,  B01J31/122 ,  B01J31/4015 ,  B01J2231/12 ,  B01J2231/326 ,  B01J2231/40 ,  B01J2231/70 ,  C07C45/46 ,  C07C45/69 ,  C07D313/04 ,  Y02P20/584 ,  C07C49/84 ,  C07C49/543

    Abstract: A Lewis acid catalyst composition comprising a specific mixed medium and a Lewis acid catalyst, wherein the Lewis acid catalyst is at least one compound selected from the group consisting of compounds respectively represented by the following formulae (1) and (2): null(Rf1SO2)(Rf2SO2)NnullnMnullnull(1), and null(Rf1SO2)(Rf2SO2)(Rf3SO2)CnullnMnullnull(2). A method for continuously performing a reaction which proceeds in the presence of the above-mentioned Lewis acid catalyst by using a specific mixed medium and the above-mentioned Lewis acid catalyst. A novel Lewis acid catalyst.

    Abstract translation: 包含特定混合介质和路易斯酸催化剂的路易斯酸催化剂组合物，其中所述路易斯酸催化剂是选自分别由下式（1）和（2）表示的化合物中的至少一种化合物：[（Rf SO 2）（Rf 2 SO 2）N] nM（1）和[（Rf 1 SO 2）（R f 2 SO 2）（R f 3 SO 2）C] nM（2）。 在上述路易斯酸催化剂存在下，通过使用特定的混合介质和上述路易斯酸催化剂连续进行反应的方法。 一种新型路易斯酸催化剂。

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