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公开(公告)号:US20150299585A1
公开(公告)日:2015-10-22
申请号:US14432150
申请日:2012-11-08
Applicant: PETROCHINA COMPANY LIMITED
Inventor: Xuejun ZHANG , Guanjing WU , Pingyi WU , Xiaoliang YUAN , Yuandong HOU , Yin ZHANG , Qinfeng ZHAO , Shuqin WANG , Kunhong LIU
CPC classification number: C10G45/38 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/0009 , B01J37/0203 , B01J37/0207 , C10G45/60
Abstract: The present invention relates to a method for the selective hydrogenation of an unsaturated compound, particularly a method in an unsaturated compound or a mixture containing unsaturated compounds for increase of the light sulphides weight, hydrogenation of a polyunsaturated compound and isomerization of a monounsaturated compound. The method uses a supported catalyst. The supported catalyst contains at least one Group VIB non-noble metal oxide and at least one Group VIII non-noble metal oxide deposited on a carrier; and the catalyst has an optimized acid distribution on the surface of the catalyst, and more preferably has an optimized Group VIII/VIB metal ratio and a Group VIII non-noble metal density per unit of catalyst surface area.
Abstract translation: 本发明涉及不饱和化合物的选择性氢化方法,特别是不饱和化合物或含有不饱和化合物的混合物中的方法,用于增加轻质硫化物重量,多不饱和化合物的氢化和单不饱和化合物的异构化。 该方法使用负载型催化剂。 载体催化剂含有至少一种VIB非贵金属氧化物和沉积在载体上的至少一种第VIII族非贵金属氧化物; 并且催化剂在催化剂表面上具有优化的酸分布,更优选具有优化的VIII / VIB族金属比和每单位催化剂表面积的VIII族非贵金属密度。