公开(公告)号：US3635923A

公开(公告)日：1972-01-18

申请号：US3635923D

申请日：1969-12-05

Applicant: PHILLIPS PETROLEUM CO

Inventor： SELMAN CHARLES M

IPC: C08F2/36 ,  C08F4/46 ,  C08F36/04 ,  C08F297/04 ,  C08F1/28 ,  C08F7/04 ,  C08F15/04

CPC classification number: C08F297/04 ,  C08F2/36 ,  C08F36/04 ,  C08F4/48

Abstract: THE MOLECULAR WEIGHT AND MOLECULAR WEIGHT DISTRIBUION OF HOMOPOLYMERS AND COPOLYMERS OF CONJUGATED DIENES AND/OR MONOVINYL-SUBSTITUTED AROMATIC HYDROCARBONS IS INCREDED AND THE COLD FLOW OF RUBBERY POLYMERS OF SAID MONOMERS IS DECREASED BY EMPLOYMENT OF SULFITE ESTER TREATING AGENTS.

公开(公告)号：US3887643A

公开(公告)日：1975-06-03

申请号：US35500273

申请日：1973-04-27

Applicant: PHILLIPS PETROLEUM CO

Inventor： SELMAN CHARLES M

IPC: C07D201/14 ,  C07F1/00 ,  C08C19/44 ,  C08G69/00 ,  C08G41/04

CPC classification number: C08C19/44 ,  C07D201/14 ,  C07F1/005 ,  C08G69/00

Abstract: Diene-lactam block polymers are produced from a metal salt of a lactam, a halogen-substituted isocyanate, a lithium-containing polymer and a lactam.

Abstract translation: 二烯内酰胺嵌段聚合物由内酰胺，卤素取代的异氰酸酯，含锂聚合物和内酰胺的金属盐制备。

公开(公告)号：US3879366A

公开(公告)日：1975-04-22

申请号：US35345373

申请日：1973-04-23

Applicant: PHILLIPS PETROLEUM CO

Inventor： SELMAN CHARLES M

IPC: C08C19/44 ,  C08F36/04 ,  C08F19/08

CPC classification number: C08F36/04 ,  C08C19/44 ,  C08F4/488 ,  C08F4/54

Abstract: In the preparation of conjugated diene polymers with multilithium initiators followed by termination with polyfunctional reagents, broader molecular weight distribution is obtained by modifying the polymerization reaction with a magnesium, calcium, strontium, or barium halide or hydrocarbylmetal halide.

Abstract translation: 在制备具有多重引发剂的共轭二烯聚合物随后用多官能试剂终止时，通过用镁，钙，锶或卤化钡或烃基金属卤化物改性聚合反应来获得较宽的分子量分布。