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公开(公告)号：US20150044741A1
公开(公告)日：2015-02-12
申请号：US14376639
申请日：2013-02-08
申请人： PURAC BIOCHEM B.V.
发明人： Agustín Cerdà Baró , Jan Van Breugel , Willem Jacob Groot , André Banier De Haan , Peter Paul Jansen
CPC分类号： C07C51/02 , C07C59/08 , C12P7/56 , C07C53/122 , C07C55/10 , C07C55/14 , C07C57/04 , C07C57/13 , C07C57/145 , C07C57/15 , C07C59/01 , C07C59/195 , C07C59/265 , C07C61/20
摘要： A method for preparing a carboxylic acid by acidification of a liquid feed including a carboxylate salt, which method includes the steps of providing a liquid feed including magnesium carboxylate; providing a gas feed including gaseous hydrogen chloride; and acidifying the carboxylate to carboxylic acid by bringing the liquid feed into contact with the gas feed, thereby forming a liquid effluent including carboxylic acid and magnesium chloride, wherein the gas feed including gaseous hydrogen chloride is derived from a thermal decomposition step wherein an aqueous liquid including magnesium chloride is subjected to a temperature of at least 300° C., thereby decomposing magnesium chloride into magnesium oxide and hydrogen chloride, thus obtaining a solid including magnesium oxide and a gas comprising gaseous hydrogen chloride.
摘要翻译： 一种通过酸化含有羧酸盐的液体原料制备羧酸的方法，该方法包括提供包括羧酸镁的液体进料的步骤; 提供包括气态氯化氢的气体进料; 并通过使液体进料与气体进料接触而将羧酸酯酸化，从而形成包括羧酸和氯化镁的液体流出物，其中包括气态氯化氢的气体进料源自热分解步骤，其中水性液体 包括氯化镁的温度至少为300℃，从而将氯化镁分解成氧化镁和氯化氢，从而得到包含氧化镁和包含气态氯化氢的气体的固体。
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公开(公告)号：US10071948B2
公开(公告)日：2018-09-11
申请号：US15378888
申请日：2016-12-14
申请人： PURAC BIOCHEM B.V.
发明人： André Banier De Haan , Jan Van Breugel , Paulus Loduvicus Johannes Van Der Weide , Peter Paul Jansen , José Maria Vidal Lancis , Agustín Cerdà Baró
CPC分类号： C07C51/02 , C01B7/035 , C01F5/06 , C01F5/10 , C01F5/16 , C01F5/30 , C07C51/42 , C07C51/43 , C07D307/60 , C07D307/68 , C07C55/10
摘要： The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl2); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl2, thereby obtaining a carboxylic acid precipitate and a MgCl2 solution.
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公开(公告)号：US10793501B2
公开(公告)日：2020-10-06
申请号：US15747189
申请日：2016-07-29
申请人： PURAC BIOCHEM B.V.
发明人： Peter Paul Jansen , Jan Van Breugel , Gerard Hendrik Van Bochove , Jose Maria Vidal Lancis , Tanja Dekic Zivkovic
摘要： The invention pertains to a method for providing a succinic acid solution, comprising the steps of —providing a first magnesium succinate containing medium with a magnesium succinate concentration of 18-23 wt. % to a first acidification reactor where it is contacted with hydrogen chloride to form a solution of succinic acid, magnesium chloride and hydrogen chloride, —providing a second magnesium succinate containing medium with a magnesium succinate concentration of 25-50 wt. %, and contacting it in a second acidification reactor with the solution of succinic acid, magnesium chloride and hydrogen chloride withdrawn from the first acidification reactor, to form an aqueous mixture comprising magnesium chloride and succinic acid with a succinic acid concentration of at least 18 wt. %. The method according to the invention makes it possible to obtain a solution comprising succinic acid and magnesium 20 chloride with an increased succinic acid concentration.
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公开(公告)号：US10093608B2
公开(公告)日：2018-10-09
申请号：US15743842
申请日：2016-07-14
申请人： PURAC BIOCHEM B.V.
发明人： Jan Van Breugel , Peter Paul Jansen , Jose Maria Vidal Lancis , Tanja Dekic Zivkovic , Adriaan Dirk Kon
摘要： The invention pertains to a method for preparing succinic acid which comprises providing an aqueous magnesium succinate solution to an acidification step, wherein the magnesium succinate solution is acidified by the addition of hydrogen chloride, thereby obtaining an aqueous solution comprising succinic acid and magnesium chloride and subjecting the aqueous solution comprising succinic acid and magnesium chloride derived from the acidification step to a treatment step with active carbon followed by precipitating succinic acid from an aqueous mixture comprising succinic acid and magnesium chloride resulting from the active carbon treatment step in a precipitation step to form solid succinic acid. It has been found that the method according to the invention leads to succinic acid crystals with better properties than a comparable method wherein no active carbon treatment is used.
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公开(公告)号：US10508069B2
公开(公告)日：2019-12-17
申请号：US16030415
申请日：2018-07-09
申请人： PURAC BIOCHEM B.V.
发明人： André Banier De Haan , Jan Van Breugel , Paulus Loduvicus Johannes Van Der Weide , Peter Paul Jansen , José Maria Vidal Lancis , Agustin Cerdà Baró
IPC分类号： C07C51/02 , C07C51/43 , C07C51/42 , C01B7/03 , C01F5/10 , C01F5/30 , C01F5/06 , C01F5/16 , C07D307/68 , C07D307/60
摘要： The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl2); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl2, thereby obtaining a carboxylic acid precipitate and a MgCl2 solution.
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公开(公告)号：US10017446B2
公开(公告)日：2018-07-10
申请号：US15378830
申请日：2016-12-14
申请人： PURAC BIOCHEM B.V.
发明人： André Banier De Haan , Jan Van Breugel , Paulus Loduvicus Johannes Van Der Weide , Peter Paul Jansen , José Maria Vidal Lancis , Agustín Cerdà Baró
CPC分类号： C07C51/02 , C01B7/035 , C01F5/06 , C01F5/10 , C01F5/16 , C01F5/30 , C07C51/42 , C07C51/43 , C07D307/60 , C07D307/68 , C07C55/10
摘要： The invention provides a method for preparing a carboxylic acid, which method includes the steps of providing magnesium carboxylate, wherein the carboxylic acid corresponding with the carboxylate has a solubility in water at 20° C. of 80 g/100 g water or less; acidifying the magnesium carboxylate with HCl, thereby obtaining a solution comprising carboxylic acid and magnesium chloride (MgCl2); optionally a concentration step, wherein the solution comprising carboxylic acid and MgCl2 is concentrated; precipitating the carboxylic acid from the solution comprising the carboxylic acid and MgCl2, thereby obtaining a carboxylic acid precipitate and a MgCl2 solution.
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公开(公告)号：US09090548B2
公开(公告)日：2015-07-28
申请号：US14376639
申请日：2013-02-08
申请人： PURAC BIOCHEM B.V.
发明人： Agustin Cerdà Baró , Jan Van Breugel , Willem Jacob Groot , André Banier De Haan , Peter Paul Jansen
IPC分类号： C07C51/02 , C07C59/08 , C07C53/122 , C07C55/10 , C07C55/14 , C07C57/04 , C07C57/13 , C07C57/15 , C12P7/56
CPC分类号： C07C51/02 , C07C59/08 , C12P7/56 , C07C53/122 , C07C55/10 , C07C55/14 , C07C57/04 , C07C57/13 , C07C57/145 , C07C57/15 , C07C59/01 , C07C59/195 , C07C59/265 , C07C61/20
摘要： A method for preparing a carboxylic acid by acidification of a liquid feed including a carboxylate salt, which method includes the steps of providing a liquid feed including magnesium carboxylate; providing a gas feed including gaseous hydrogen chloride; and acidifying the carboxylate to carboxylic acid by bringing the liquid feed into contact with the gas feed, thereby forming a liquid effluent including carboxylic acid and magnesium chloride, wherein the gas feed including gaseous hydrogen chloride is derived from a thermal decomposition step wherein an aqueous liquid including magnesium chloride is subjected to a temperature of at least 300° C., thereby decomposing magnesium chloride into magnesium oxide and hydrogen chloride, thus obtaining a solid including magnesium oxide and a gas comprising gaseous hydrogen chloride.
摘要翻译： 一种通过酸化含有羧酸盐的液体原料制备羧酸的方法，该方法包括提供包括羧酸镁的液体进料的步骤; 提供包括气态氯化氢的气体进料; 并通过使液体进料与气体进料接触而将羧酸酯酸化，从而形成包括羧酸和氯化镁的液体流出物，其中包括气态氯化氢的气体进料源自热分解步骤，其中水性液体 包括氯化镁的温度至少为300℃，从而将氯化镁分解成氧化镁和氯化氢，从而得到包含氧化镁和包含气态氯化氢的气体的固体。
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