摘要:
A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure in the casing comprising a plurality of plates in spaced apart relation, a lithium anode comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum salt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted.
摘要翻译:一种用于输送高电流脉冲的固体阴极液体有机电解质锂电池,包括壳体,壳体中的阴极结构,包括间隔开的多个板,锂阳极,其包括插入在阴极板之间的多个阳极部分, 包括在壳体中的锂盐和有机溶剂的组合的水性液体有机电解质可操作地接触阳极和阴极,提供给阳极的电连接和提供给阴极的电连接。 根据本发明的一个方面,阴极包括作为活性材料Ag x V 2 O y,其中x在约0.5至约2.0的范围内,y在约4.5至约6.0的范围内,这有利地具有高体积容量和高速率能力, 本发明的电池提供高容量的结果,在各种放电水平下显示出良好的电流脉冲特性,并且具有倾斜的放电,从而能够预测寿命的终止。
摘要:
A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure inthe casing comprising a plurality of plates in spaced apart relation, a lithium anond comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum dalt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag.sub.x V.sub.2 O.sub.y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted. In accordance with another aspect of the present invention, the anode comprises a continuous elongated lithium element enclosed within a separator and folded into a plurality of sections interposed between the cathode plates, each of which individually is enclosed within separator material thereby enhancing the reliability of the cell. The cell of the present invention finds advantageous use as a power source for an implantable cardiac defibrillator.
摘要翻译:一种用于输送高电流脉冲的固体阴极液体有机电解质锂电池,包括壳体,壳体中的阴极结构,包括间隔开的多个板,包含插入在阴极板之间的多个阳极部分的锂阳极, 包含硅酸盐和有机溶剂的组合的含水液体有机电解质在壳体中可操作地接触阳极和阴极,提供给阳极的电连接和提供给阴极的电连接。 根据本发明的一个方面,阴极包括作为活性材料Ag x V 2 O y,其中x在约0.5至约2.0的范围内,y在约4.5至约6.0的范围内,这有利地具有高体积容量和高速率能力, 本发明的电池提供高容量的结果,在各种放电水平下显示出良好的电流脉冲特性,并且具有倾斜的放电,从而能够预测寿命的终止。 根据本发明的另一方面,阳极包括一个连续细长的锂元素,其包围在隔板内并折叠成插入在阴极板之间的多个部分,每个部分分别被封闭在隔板材料内,从而提高了可靠性 细胞。 本发明的细胞作为可植入心脏除颤器的动力源有优势的使用。
摘要:
Battery-powered implantable medical devices require a suitable method for indicating end-of-service of the power source so that there is ample time for elective replacement of the device and/or power source. The present invention utilizes mixed cathode materials preferably comprising a major portion of a fluorinated carbon and a minor portion of a metal-containing material. This mixed cathode formulation is characterized by two, discretely different operating voltages, the second of which may be used as an end-of-life indicator.
摘要:
A fabric separator woven from synthetic halogenated polymeric fibers for use in an electrochemical cell comprising a Group IA, IIA and IIIB metal anode and a depolarizer/catholyte or a solid cathode/electrolyte system, is described. The separator is resistant to the highly oxidizing components present in the cell, is tear resistant and has a reduced thickness to minimize the diminishing effect of the separator on the volumetric amount of active components in the cell. The separator can be used by itself or as a laminate with a microporous film, preferably made of a fluoropolymeric fiber.
摘要:
A cell construction that makes use of unbalanced electrode components or portions comprising one of the electrodes of an electrochemical cell to provide an end-of-life indication, is described. The unbalanced electrode components can have dissimilar physical dimensions or dissimilar percent loading of electrode active material. This renders the one dissimilar electrode component having the lesser physical dimension, i.e., lesser surface area or thickness, or lesser quantity of electrode active material electrochemically unreactive prior to the other electrode component during the course of cell discharge. Upon the early exhaustion or unreactiveness of the one dissimilar electrode component, the total cell interelectrode working capacity is reduced by a predetermined factor. The remaining functional electrode component provides the cell with sufficient capacity for electrical discharge at a predetermined lower energy level.
摘要:
An electrochemical cell is provided having a metallic anode comprising a lithium-aluminum alloy, a solid cathode of electronically conductive material and an ionic conductive non-aqueous electrolyte solution operatively associated and in direct contact with the anode and cathode. The metallic anode comprises a lithium-aluminum alloy wherein aluminum comprises from about 0% to about 50% by weight of the alloy. The solid cathode comprises a fluorinated carbon such as poly carbon monofluoride, a metal oxide or a metal oxide bronze. The non-aqueous electrolyte solution comprises a first component consisting of a high boiling aprotic solvent or combinations thereof, and a second component consisting of at least one lithium salt. The electrochemical cell demonstrates an energy density of about 0.6WH/CC and exhibits consistent performance predictability over an operational range of from about -20.degree. C. to about 180.degree. C.