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公开(公告)号:US20230077974A1
公开(公告)日:2023-03-16
申请号:US17796229
申请日:2020-12-01
Inventor: Kenji Matsubara , Masanobu Takeuchi
Abstract: A negative electrode active material for aqueous secondary batteries, said negative electrode active material being applied to an aqueous secondary battery that uses an aqueous electrolyte solution containing water and a lithium salt, wherein: the negative electrode active material contains graphite; the graphite has a C—F bond group on the surface; if I688eV is the peak intensity at around 688 eV ascribed to a C—F bond and I284eV is the peak intensity at around 284 eV ascribed to a C—C bond in the XPS spectrum of the graphite as obtained by X-ray photoelectron spectroscopy, the ratio of the peak intensity I688eV to the peak intensity I284eV (namely, the value of I688eV/I284eV ) is from 0.1 to 7; and the BET specific surface area is from 0.5 m2/g to 3.9 m2/g.
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公开(公告)号:US20210135277A1
公开(公告)日:2021-05-06
申请号:US16640116
申请日:2018-09-21
Inventor: Nobuhiko Hojo , Hiroyuki Matsumoto , Kenji Matsubara , Hiroshi Kawada , Atsushi Fukui
IPC: H01M10/0562 , H01M10/0525 , H01M4/505 , H01M4/525
Abstract: An aqueous rechargeable battery includes: a positive electrode including a positive electrode current collector and a positive electrode active material layer provided on a surface of the positive electrode current collector; a negative electrode including a negative electrode current collector and a negative electrode active material layer provided on a surface of the negative electrode current collector; and an aqueous electrolyte solution containing a lithium salt and water. The positive electrode active material layer contains one or more positive electrode active materials and one or more lithium ion-conducting solid electrolytes; and the positive electrode active materials include a lithium transition metal oxide.
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公开(公告)号:US11646446B2
公开(公告)日:2023-05-09
申请号:US16961007
申请日:2018-11-30
Inventor: Kenji Matsubara , Nobuhiko Hojo , Hiroyuki Matsumoto , Takayuki Nakatsutsumi , Kazuhiro Iida , Atsushi Fukui
IPC: H01M4/00 , H01M10/0566 , H01M4/485 , H01M4/66 , H01M10/0525 , H01M10/26
CPC classification number: H01M10/0566 , H01M4/485 , H01M4/661 , H01M10/0525 , H01M10/26 , H01M2300/0002
Abstract: A rechargeable battery including a positive electrode, a negative electrode, and an electrolyte solution is provided. The electrolyte solution contains water and one or more lithium salts, and the lithium salts include lithium fluorophosphate.
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公开(公告)号:US20220173434A1
公开(公告)日:2022-06-02
申请号:US17442031
申请日:2020-01-27
Inventor: Kenji Matsubara , Kazuhiro Iida , Masanobu Takeuchi , Atsushi Fukui
IPC: H01M10/0567 , H01M4/583 , H01M10/0568 , H01M10/0569 , H01M10/0525
Abstract: A secondary battery which comprises a positive electrode, a negative electrode, and an electrolytic solution, wherein the electrolytic solution comprises water, a lithium salt, and an additive, the additive including at least one of alkaline-earth metal salts, dicarboxylic acids, carboxylic anhydrides, and organic carbonates, and the negative electrode comprises a negative active material, the negative active material having a silane coupling agent adherent to the surface thereof.
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公开(公告)号:US20210083324A1
公开(公告)日:2021-03-18
申请号:US16961007
申请日:2018-11-30
Inventor: Kenji Matsubara , Nobuhiko Hojo , Hiroyuki Matsumoto , Takayuki Nakatsutsumi , Kazuhiro Iida , Atsushi Fukui
IPC: H01M10/0566 , H01M10/26 , H01M4/485 , H01M4/66 , H01M10/0525
Abstract: A rechargeable battery including a positive electrode, a negative electrode, and an electrolyte solution is provided. The electrolyte solution contains water and one or more lithium salts, and the lithium salts include lithium fluorophosphate.
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公开(公告)号:US20230058362A1
公开(公告)日:2023-02-23
申请号:US17795680
申请日:2020-12-01
Inventor: Kenji Matsubara , Masanobu Takeuchi
IPC: H01M4/583 , H01M10/0568 , H01M10/0569
Abstract: Provided is a negative electrode active material that is applied in an aqueous secondary battery in which is used an aqueous electrolyte containing water and a lithium salt. The negative electrode active material contains hardly-graphitizable carbon, and the hardly-graphitizable carbon has a C—F bond group on the surface thereof. In an XPS spectrum obtained through X-ray photoelectron spectroscopy, when the peak intensity near 688 eV originating from C—F bonds of the hardly-graphitizable carbon is denoted by I688eV, the peak intensity near 284 eV originating from C—C bonds is denoted by I284eV, a ratio of the peak intensity I688eV to the peak intensity I284eV (value of I688eV/I284eV) is denoted by X, and the BET specific surface area (m2/g) is denoted by Y, the X and Y satisfy Y
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公开(公告)号:US20220359871A1
公开(公告)日:2022-11-10
申请号:US17619707
申请日:2020-06-16
Inventor: Kenji Matsubara , Hiroshi Kawada , Atsushi Fukui , Masanobu Takeuchi
IPC: H01M4/583 , H01M10/0525 , H01M10/0562
Abstract: A secondary battery including a positive electrode, a negative electrode, and an electrolytic solution. The negative electrode includes a carbon material electrochemically capable of absorbing and releasing lithium ions, and a solid electrolyte covering at least part of a surface of the carbon material and having lithium ion conductivity. The solid electrolyte includes a first compound represented by a general formula: LixM1Oy, where 0.5
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公开(公告)号:US20220173399A1
公开(公告)日:2022-06-02
申请号:US17439996
申请日:2020-01-15
Inventor: Kenji Matsubara , Nobuhiko Hojo , Masanobu Takeuchi , Atsushi Fukui
IPC: H01M4/62 , H01M10/0568 , H01M4/587 , H01M4/133 , H01M10/0525
Abstract: A secondary battery according to the present invention is provided with a positive electrode, a negative electrode and an electrolyte solution; the electrolyte solution contains water and a lithium salt; the negative electrode contains a negative electrode active material; a silane coupling agent, which is reductively decomposed at a potential that is higher than the reductive decomposition potential of water, is adhered to the surface of the negative electrode active material; and the silane coupling agent contains fluorine as a constituent element.
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公开(公告)号:US12237509B2
公开(公告)日:2025-02-25
申请号:US17619707
申请日:2020-06-16
Inventor: Kenji Matsubara , Hiroshi Kawada , Atsushi Fukui , Masanobu Takeuchi
IPC: H01M4/583 , H01M4/02 , H01M10/0525 , H01M10/0562
Abstract: A secondary battery including a positive electrode, a negative electrode, and an electrolytic solution. The negative electrode includes a carbon material electrochemically capable of absorbing and releasing lithium ions, and a solid electrolyte covering at least part of a surface of the carbon material and having lithium ion conductivity. The solid electrolyte includes a first compound represented by a general formula: LixM1Oy, where 0.5
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公开(公告)号:US11817561B2
公开(公告)日:2023-11-14
申请号:US17054890
申请日:2019-02-19
Inventor: Kenji Matsubara , Nobuhiko Hojo , Hiroyuki Matsumoto , Atsushi Fukui
IPC: H01M10/36
CPC classification number: H01M10/36 , H01M2300/0002
Abstract: An electrolyte solution according to one aspect of the present disclosure comprises water, a lithium salt, and a polycarboxylic acid having two or more carboxylic acid groups. A secondary battery according to one aspect of the present disclosure comprises a positive electrode, a negative electrode, and the electrolyte solution.
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