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公开(公告)号:US12062779B2
公开(公告)日:2024-08-13
申请号:US17441527
申请日:2020-02-17
Inventor: Junichi Sakamoto , Yuji Tani , Nobuhiko Hojo
IPC: H01M4/36 , H01M4/38 , H01M4/587 , H01M10/0525 , H01M4/02
CPC classification number: H01M4/364 , H01M4/386 , H01M4/587 , H01M10/0525 , H01M2004/021 , H01M2004/027
Abstract: A non-aqueous electrolyte secondary battery with a negative electrode active material including a carbon material, and a silicon-containing material in which Si particles are dispersed in a lithium ion conductive phase. The negative electrode material mixture layer having a thickness T0 includes a first region on the negative electrode surface side having a thickness of T1, and a second region on the negative electrode current collector side, and the ratio T1/T0 is 1/20 to 19/20. The ratio of a mass ratio MS1 of the silicon-containing material in the first region to a mass ratio MS2 of the silicon-containing material in the second region is not less than 0 and less than 1. An open circuit potential of the negative electrode in a fully charged condition is higher than 0 mV and 70 mV or lower relative to lithium metal.
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公开(公告)号:US20220344699A1
公开(公告)日:2022-10-27
申请号:US17764716
申请日:2020-07-21
Inventor: Nobuhiko Hojo , Yuji Tani
IPC: H01M10/0525 , H01M10/0569 , H01M10/0587
Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a lithium ion conductive nonaqueous electrolyte, wherein the negative electrode contains graphite, an open circuit potential of the negative electrode in a fully charged state is 70 mV or less relative to lithium metal, the nonaqueous electrolyte contains a solvent, a cation, and an anion, the solvent contains a fluorine-containing cyclic carbonic acid ester, the cation includes lithium ions, and the anion includes an oxalate complex anion.
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公开(公告)号:US20200176818A1
公开(公告)日:2020-06-04
申请号:US16639384
申请日:2018-09-11
Inventor: Satoshi Nishitani , Yuji Tani , Masaki Deguchi
IPC: H01M10/0568 , H01M10/0525 , H01M4/131 , H01M10/0569 , H01M4/485 , H01M10/0567
Abstract: A non-aqueous electrolyte secondary battery, including a positive electrode, a separator, a negative electrode facing the positive electrode with the separator interposed therebetween, and an electrolytic solution including a solvent and an electrolyte. The negative electrode includes a negative electrode material containing a lithium silicate phase and silicon particles dispersed in the lithium silicate phase. The silicon particles are contained in the negative electrode material in an amount of 30 mass % or more, relative to a total mass of the lithium silicate phase and the silicon particles. The electrolytic solution contains an ester compound C of an alcohol compound A and a carboxylic acid compound B, and contains at least one of the alcohol compound A and the carboxylic acid compound B in an amount of 15 ppm or more, relative to a mass of the electrolytic solution.
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公开(公告)号:US20190181495A1
公开(公告)日:2019-06-13
申请号:US16322721
申请日:2017-05-19
Inventor: Yuji Tani , Hajime Nishino , Yasuhiro Sugaya , Satoshi Nishitani
IPC: H01M10/0525 , H01M4/38 , H01M10/0568 , H01M10/058
Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte having permeated the positive electrode, the negative electrode and the separator. The nonaqueous electrolyte includes a lithium salt and a nonaqueous solvent in which the lithium salt is dissolved. The lithium salt concentration in the nonaqueous electrolyte present within the positive electrode is higher than the lithium salt concentration in the nonaqueous electrolyte present within the negative electrode.
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公开(公告)号:US12087942B2
公开(公告)日:2024-09-10
申请号:US17442058
申请日:2020-03-23
Inventor: Yuji Tani , Junichi Sakamoto , Nobuhiko Hojo
IPC: H01M4/38 , H01M4/02 , H01M4/133 , H01M4/134 , H01M4/36 , H01M4/48 , H01M4/485 , H01M4/587 , H01M10/0525 , H01M10/42
CPC classification number: H01M4/386 , H01M4/133 , H01M4/134 , H01M4/364 , H01M4/483 , H01M4/485 , H01M4/587 , H01M10/0525 , H01M2004/027 , H01M2010/4292
Abstract: A non-aqueous electrolyte secondary battery, wherein a negative electrode includes a negative electrode mixture layer having a thickness T and a negative electrode current collector, the negative electrode active material includes carbon and Si-containing materials, wherein when the negative electrode mixture layer is divided into a first region having a thickness of T/2 on the surface side of the negative electrode and a second region having a thickness of T/2 on the negative electrode collector side, a mass ratio of the first to the second composite material contained in the first region is >1, a mass ratio of the first composite to the second composite material contained in the second region is
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公开(公告)号:US20230378438A1
公开(公告)日:2023-11-23
申请号:US18027282
申请日:2021-09-14
Inventor: Yuji Tani , Yuji Goshima , Fumiharu Niina
CPC classification number: H01M4/364 , H01M4/133 , H01M4/137 , H01M2004/027
Abstract: This nonaqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, and a nonaqueous electrolyte. The negative electrode includes a negative electrode core and a negative electrode mixture layer formed on at least one surface of the negative electrode core. The ratio (E1/E2) of the charging expansion rate (E1) to the discharge expansion rate (E2) of the negative electrode is at least 1.05 and less than 1.15. The content of silicon material with respect to the mass of a negative electrode active material in the negative electrode mixture layer is 3-12 mass %. Graphite, a first silicon material (SiO), and a second silicon material (LSX) are preferably included as the negative electrode active material in the negative electrode mixture layer.
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公开(公告)号:US20220173381A1
公开(公告)日:2022-06-02
申请号:US17441527
申请日:2020-02-17
Inventor: Junichi Sakamoto , Yuji Tani , Nobuhiko Hojo
IPC: H01M4/36 , H01M4/587 , H01M4/38 , H01M10/0525
Abstract: A non-aqueous electrolyte secondary battery with a negative electrode active material including a carbon material, and a silicon-containing material in which Si particles are dispersed in a lithium ion conductive phase. The negative electrode material mixture layer having a thickness T0 includes a first region on the negative electrode surface side having a thickness of T1, and a second region on the negative electrode current collector side, and the ratio T1/T0 is 1/20 to 19/20. The ratio of a mass ratio MS1 of the silicon-containing material in the first region to a mass ratio MS2 of the silicon-containing material in the second region is not less than 0 and less than 1. An open circuit potential of the negative electrode in a fully charged condition is higher than 0 mV and 70 mV or lower relative to lithium metal.
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公开(公告)号:US20250015338A1
公开(公告)日:2025-01-09
申请号:US18711307
申请日:2022-10-14
Inventor: Yuji Tani , Yosuke Sato
Abstract: A negative electrode of this lithium ion secondary battery comprises a negative electrode collector and a negative electrode mixture layer that is formed on the surface of the negative electrode collector; the thickness of the negative electrode collector is 4 μm to 12 μm; the 1% proof stress of the negative electrode collector is 300 MPa to 700 MPa; the negative electrode mixture laver contains a carbon-based material and a silicon-based material, which serve as negative electrode active materials; the discharge capacity of the negative electrode active materials is 400 mAh/g to 750 mAh/g the carbon-based material contains a carbon-based material A and a carbon-based material B, which have different particle fracture strengths from each other; the particle fracture strength of the carbon-based material A is 5 MPa to 15 MPa; and the particle fracture strength of the carbon-based material B is 25 MPa to 40 MPa.
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公开(公告)号:US20220173389A1
公开(公告)日:2022-06-02
申请号:US17442058
申请日:2020-03-23
Inventor: Yuji Tani , Junichi Sakamoto , Nobuhiko Hojo
IPC: H01M4/38 , H01M4/134 , H01M4/133 , H01M4/36 , H01M10/0525
Abstract: A non-aqueous electrolyte secondary battery, wherein a negative electrode includes a negative electrode mixture layer having a thickness T and a negative electrode current collector, the negative electrode active material includes carbon and Si-containing materials, wherein when the negative electrode mixture layer is divided into a first region having a thickness of T/2 on the surface side of the negative electrode and a second region having a thickness of T/2 on the negative electrode collector side, a mass ratio of the first to the second composite material contained in the first region is >1, a mass ratio of the first composite to the second composite material contained in the second region is
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公开(公告)号:US20200176771A1
公开(公告)日:2020-06-04
申请号:US16639377
申请日:2018-09-11
Inventor: Yuji Tani , Satoshi Nishitani , Masaki Deguchi
IPC: H01M4/525 , H01M10/0569 , H01M10/052 , H01M10/0567 , H01M4/02
Abstract: A non-aqueous electrolyte secondary battery including a positive electrode, a separator, a negative electrode facing the positive electrode with the separator interposed therebetween, and an electrolytic solution containing a solvent and an electrolyte. The positive electrode includes a positive electrode material containing a lithium-nickel composite oxide represented by LiaNibM1−bO2, where M represents at least one selected from the group consisting of Na, Mg, Sc, Y, Mn, Fe, Co, Ni, Cu, Zn, Al, Cr, Pb, Sb and B, 0.95≤a≤1.2, and 0.8≤b≤1. The electrolytic solution contains an ester compound C of an alcohol compound A and a carboxylic acid compound B, and contains at least one of the alcohol compound A and the carboxylic acid compound B in an amount of 15 ppm or more, relative to a mass of the electrolytic solution.
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