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公开(公告)号:US11855255B2
公开(公告)日:2023-12-26
申请号:US17120144
申请日:2020-12-12
Inventor: Yusuke Nishio , Akihiro Sakai , Tetsuya Asano , Masashi Sakaida , Akinobu Miyazaki
IPC: H01M10/0562 , H01M10/0525
CPC classification number: H01M10/0562 , H01M10/0525 , H01M2300/008
Abstract: A halide solid electrolyte material according to the present disclosure is represented by the chemical formula Li6−(4+a)b(Zr1−aMa)bX6, wherein M denotes at least one element selected from the group consisting of Ta and Nb, X denotes at least one halogen element, and two mathematical formulae 0
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公开(公告)号:US11560320B2
公开(公告)日:2023-01-24
申请号:US16915424
申请日:2020-06-29
Inventor: Tetsuya Asano , Akihiro Sakai , Masashi Sakaida , Yusuke Nishio
IPC: H01M10/00 , C01G25/00 , C01F17/36 , C01G9/00 , C01G29/00 , C01G33/00 , C01G35/00 , H01M10/0525 , H01M10/0562
Abstract: A solid electrolyte material contains Li, M, and X. M is at least one selected from metallic elements, and X is at least one selected from the group consisting of Cl, Br, and I. A plurality of atoms of X form a sublattice having a closest packed structure. An average distance between two adjacent atoms of X among the plurality of atoms of X is 1.8% or more larger than a distance between two adjacent atoms of X in a rock-salt structure composed only of Li and X.
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公开(公告)号:US11498850B2
公开(公告)日:2022-11-15
申请号:US16912039
申请日:2020-06-25
Inventor: Tetsuya Asano , Akihiro Sakai , Yusuke Nishio , Masashi Sakaida , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0562 , H01M10/0525 , C01F17/36
Abstract: A solid electrolyte material contains Li; Y; at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Zr, Nb, and Ta; and at least one selected from the group consisting of Cl, Br, and I. An X-ray diffraction pattern of the solid electrolyte material obtained using Cu—Kα radiation as an X-ray source includes peaks in a range of diffraction angles 2θ of 30° or more and 33° or less, in a range of diffraction angles 2θ of 39° or more and 43° or less, and in a range of diffraction angles 2θ of 47° or more and 51° or less.
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公开(公告)号:US11427477B2
公开(公告)日:2022-08-30
申请号:US16911453
申请日:2020-06-25
Inventor: Akihiro Sakai , Tetsuya Asano , Masashi Sakaida , Yusuke Nishio , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0562 , C01F17/36 , H01M4/131 , H01M4/525 , H01M10/0525 , H01M4/02
Abstract: Provided is a solid electrolyte material comprising Li, Y, Br, and I, wherein in an X-ray diffraction pattern in which Cu-Kα is used as a radiation source, peaks are present within all ranges of diffraction angles 2θ of 12.5° to 14.0°, 25.0° to 27.8°, 29.2° to 32.3°, 41.9° to 46.2°, 49.5° to 54.7°, and 51.9° to 57.5°.
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公开(公告)号:US12095027B2
公开(公告)日:2024-09-17
申请号:US16911695
申请日:2020-06-25
Inventor: Akihiro Sakai , Tetsuya Asano , Masashi Sakaida , Yusuke Nishio , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0562 , H01M4/36 , H01M4/525 , H01M4/62 , H01M50/431 , H01M4/02
CPC classification number: H01M10/0562 , H01M4/366 , H01M4/525 , H01M4/62 , H01M50/431 , H01M2004/027 , H01M2004/028 , H01M2300/008
Abstract: Provided is a solid electrolyte material represented by the following composition formula (1):
Li6-3dYdX6 Formula (1)
where
X is two or more kinds of elements selected from the group consisting of Cl, Br, and I; and
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公开(公告)号:US11498849B2
公开(公告)日:2022-11-15
申请号:US16911707
申请日:2020-06-25
Inventor: Tetsuya Asano , Akihiro Sakai , Yusuke Nishio , Masashi Sakaida , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0562 , C01F17/36
Abstract: A solid electrolyte material contains Li, Y, at least one selected from the group consisting of Mg, Ca, Sr, Ba, Zn, Sc, La, Sm, Bi, Zr, Hf, Nb, and Ta, and at least one selected from the group consisting of Cl, Br, and I. An X-ray diffraction pattern of the solid electrolyte material obtained by using Cu-Kα radiation as the X-ray source includes peaks within the range in which the diffraction angle 2θ is 25° or more and 35° or less, and also includes at least one peak within the range in which the diffraction angle 2θ is 43° or more and 51° or less.
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公开(公告)号:US11485646B2
公开(公告)日:2022-11-01
申请号:US16911596
申请日:2020-06-25
Inventor: Tetsuya Asano , Akihiro Sakai , Masashi Sakaida , Yusuke Nishio , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0525 , H01M10/0562 , C01F17/36 , H01M4/02
Abstract: A solid electrolyte material includes a first crystal phase. The first crystal phase has a composition that is deficient in Li as compared with a composition represented by the following composition formula (1). Li3Y1Cl6 formula (1)
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公开(公告)号:US20200328461A1
公开(公告)日:2020-10-15
申请号:US16911725
申请日:2020-06-25
Inventor: Tetsuya Asano , Akihiro Sakai , Masashi Sakaida , Yusuke Nishio , Akinobu Miyazaki , Shinya Hasegawa
IPC: H01M10/0562
Abstract: A solid electrolyte material is represented by the following compositional formula (1): Li3−3δ+aY1+δ−aMaCl6−x−yBrxIy where, M is at least one selected from the group consisting of Mg, Ca, Sr, Ba, and Zn; and −1
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公开(公告)号:US12269752B2
公开(公告)日:2025-04-08
申请号:US17323920
申请日:2021-05-18
Inventor: Takashi Kubo , Yusuke Nishio , Akihiro Sakai , Akinobu Miyazaki
IPC: C01F17/271 , C01F17/36 , H01M10/0525 , H01M10/0562
Abstract: A method for producing a halide includes heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH4)aMX3+a and LiZ. The M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc. The X is at least one element selected from the group consisting of Cl, Br, I, and F. The Z is at least one element selected from the group consisting of Cl, Br, I, and F. Furthermore, 0
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10.
公开(公告)号:US12191445B2
公开(公告)日:2025-01-07
申请号:US17388346
申请日:2021-07-29
Inventor: Yusuke Nishio , Akihiro Sakai , Tetsuya Asano , Masashi Sakaida , Akinobu Miyazaki
IPC: H01M10/0562 , H01M10/0525
Abstract: An electrolyte material is represented by Li4-3a-cbAlaMbFxClyBr4-x-y, wherein M is at least one selected from the group consisting of Mg, Ca, and Zr; c represents a valence of M; and the following five inequalities are satisfied: 0
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