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    Compositions and inks containing disazo dyes
    1.
    发明授权
    Compositions and inks containing disazo dyes 失效
    含有双偶氮染料的组合物和油墨

    公开(公告)号：US07481522B2

    公开(公告)日：2009-01-27

    申请号：US10516496

    申请日：2003-06-05

    Applicant: Alan Dickinson ,  Neil James Thompson ,  Paul Wight ,  Peter Gregory ,  Philip John Double ,  Roy Bradbury

    Inventor： Alan Dickinson ,  Neil James Thompson ,  Paul Wight ,  Peter Gregory ,  Philip John Double ,  Roy Bradbury

    IPC: G01D11/00

    CPC classification number: C09D11/30

    Abstract: A process for printing an image on a substrate including applying thereto a composition including a liquid medium and a compound of Formula (1) A-N═N-L-N═N-A wherein: each A independently is optionally substituted aryl or heteroaryl; and L is an optionally substituted, optionally metallised 1,8-dihydroxynaphthylene group; provided that: (i) at most one of the groups represented by A has a hydroxy substituent ortho to the —N═N— groups shown in Formula (1); and (ii) Formula (1) is not: Also claimed are compositions for printing, compounds and processes for making the compounds.

    Abstract translation: 一种在基材上印刷图像的方法，包括向其施涂包含液体介质和式（1）A-N-N-L-N-N-A的化合物的组合物，其中：每个A独立地为任选取代的芳基或杂芳基; 并且L是任选取代的任选金属化的1,8-二羟基萘基; 条件是：（i）由A表示的至多一个基团具有与式（1）所示的-N-N-基邻位的羟基取代基; 和（ii）式（1）不是：还要求的是用于印刷的组合物，化合物和制备该化合物的方法。

    Ink and toner compositions containing a mixture of bis-azo dyes
    4.
    发明授权
    Ink and toner compositions containing a mixture of bis-azo dyes 失效
    含有双偶氮染料混合物的油墨和调色剂组合物

    公开(公告)号：US5779780A

    公开(公告)日：1998-07-14

    申请号：US825920

    申请日：1997-04-02

    Applicant: Peter Gregory ,  John Anthony Taylor

    Inventor： Peter Gregory ,  John Anthony Taylor

    IPC: C09B62/09 ,  C09B67/22 ,  C09D11/00 ,  D06P5/30 ,  G03G9/09 ,  C09D11/02

    CPC classification number: C09D11/328 ,  C09B62/09 ,  C09B67/0058 ,  D06P5/30 ,  G03G9/091

    Abstract: An ink composition comprising a medium comprising at least one of a low melting point solid, an organic solvent and a mixture of water and one or more water-soluble organic solvent(s); and a mixture of a first, second, third and fourth dye, each of which is of Formula (1) or a salt thereof: ##STR1## wherein: X is a labile or non labile atom or group; A and B are each independently an optionally substituted phenylene group; one or R.sup.1 and R.sup.2 is H and the other is sulpho; one of R.sup.3 and R.sup.4 is H and the other is sulpho; R.sup.5 and R.sup.6 are each independently C.sub.1-4 -alkyl. Also claimed is an ink jet printing process using the inks, a process for ink jet printing textile materials using the inks and a toner containing a mixture of a first, second, third and fourth dyes of the Formula (1).

    Abstract translation: 一种油墨组合物，其包含包含低熔点固体，有机溶剂和水与一种或多种水溶性有机溶剂的混合物中的至少一种的介质; （1）的第一种，第二种，第三种和第四种染料的混合物或其盐：其中：X是不稳定或非不稳定的原子或基团; A和B各自独立地为任选取代的亚苯基; 一个或R1和R2是H，另一个是磺基; R3和R4之一是H，另一个是磺基; R 5和R 6各自独立地为C 1-4 - 烷基。 还要求保护的是使用油墨的喷墨印刷方法，使用该油墨的喷墨印花纺织品的方法和含有式（1）的第一，第二，第三和第四染料的混合物的调色剂。

    Disazo Compound
    5.
    发明授权
    Disazo Compound 失效
    二唑类化合物

    公开(公告)号：US5756693A

    公开(公告)日：1998-05-26

    申请号：US737613

    申请日：1997-01-30

    Applicant: Ronald Wynford Kenyon ,  Peter Gregory

    Inventor： Ronald Wynford Kenyon ,  Peter Gregory

    IPC: B41J2/01 ,  C09B31/08 ,  C09D11/00

    CPC classification number: C09D11/328 ,  C09B31/08

    Abstract: A compound of the Formula (1) and salts thereof: ##STR1## wherein: A is optionally substituted phenyl or optionally substituted naphthyl; R.sup.1 is NR.sup.4 R.sup.5 ; R.sup.2 is H, halo, --COOH, --SO.sub.2 0H, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio; R.sup.3, R.sup.4 & R.sup.5 are each independently H or optionally substituted alkyl; T is H or sulpho; and B is H, optionally substituted alkyl or optionally substituted phenyl; provided that the compound does not contain a piperazinyl group. The compound is suitable for use as a black colorant in ink jet printing inks especially for printing on plain paper.

    Abstract translation: PCT No.PCT / GB95 / 01110 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1995年5月17日PCT公布。 公开号WO95 / 31505 日期：1995年11月23日一种式（1）化合物及其盐：其中：A为任选取代的苯基或任选取代的萘基; R1为NR4R5; R 2是H，卤素，-COOH，-SO 2 OH，任选取代的烷基，任选取代的烷氧基或任选取代的烷硫基; R 3，R 4和R 5各自独立地为H或任选取代的烷基; T是H或磺基; 且B为H，任选取代的烷基或任选取代的苯基; 条件是该化合物不含哌嗪基。 该化合物适合用作喷墨印刷油墨中的黑色着色剂，特别用于在普通纸上印刷。

    Poly-substituted phthalocyanines
    6.
    发明授权
    Poly-substituted phthalocyanines 失效
    聚取代酞菁

    公开(公告)号：US5730759A

    公开(公告)日：1998-03-24

    申请号：US548171

    申请日：1995-10-25

    Applicant: Dean Thetford ,  Peter Gregory

    Inventor： Dean Thetford ,  Peter Gregory

    IPC: A61K31/40 ,  A61K31/409 ,  A61K31/555 ,  A61K41/00 ,  A61K51/00 ,  A61P35/00 ,  C07D487/22 ,  C09B47/04 ,  C09B47/067 ,  C09B47/18 ,  C11D3/00 ,  C11D3/16 ,  C11D3/39 ,  C11D3/395 ,  C11D7/54 ,  C11D11/00 ,  D06L3/02 ,  D06L3/04

    CPC classification number: C07D487/22 ,  A61K31/40 ,  C09B47/045 ,  C09B47/0675 ,  C09B47/18 ,  C11D11/0017 ,  C11D3/0063 ,  C11D3/168 ,  C11D3/3932

    Abstract: The use of substituted phthalocyaines for removing stains from fabrics which comprises treating the stained fabrics with an aqueous composition comprising a phthalocyanine in which at least one of the peripheral carbon atoms in the 1-16 position of the phthalocyanine nucleus (M.sub.k Pc) of Formula (1), ##STR1## wherein: M is selected from H, metal, halometal, oxymetal and hydroxymetal; and k is the inverse of 1/2 the valency of M; is linked via an oxygen atom to an aromatic radical and the remaining peripheral carbon atoms are unsubstituted or substituted by any combination of atoms or groups and sulphonated derivatives thereof provided that the phthalocyanine absorbs electromagnetic radiation at a wavelength from 650 nm to 800 nm.

    Abstract translation: 使用取代的酞菁素从织物中除去污渍，其中包括用包含酞菁的水性组合物处理染色的织物，其中式（1）的酞菁核的1-16位的至少一个外周碳原子（MkPc） ），m H，金属，卤素，氧化金属和羟基金属; 并且k是+ E的倒数，f 1/2 + EE是M的化合价; 通过氧原子连接到芳族基团，并且剩余的外围碳原子是未取代的或被原子或基团和磺化衍生物的任何组合取代，条件是酞菁吸收在650nm至800nm的波长的电磁辐射。

    Phthalocyanines
    7.
    发明授权
    Phthalocyanines 失效
    酞菁

    公开(公告)号：US5629417A

    公开(公告)日：1997-05-13

    申请号：US594412

    申请日：1996-01-31

    Applicant: James S. Campbell ,  Peter Gregory ,  Dean Thetford

    Inventor： James S. Campbell ,  Peter Gregory ,  Dean Thetford

    IPC: C07D487/22 ,  C09B47/20 ,  C09B47/22

    CPC classification number: C09B47/20 ,  C09B47/22

    Abstract: A phthalocyanine of Formula (1): ##STR1## wherein: M.sub.k PC is a phthalocyanine nucleus of Formula (2): ##STR2## M is a metal atom, a chloro-metal group, and oxy-metal group or hydrogen; k is inverse of 1/2 valency of M; R and R.sup.1 each independently is an organic radical;R.sup.2 is H or optionally substituted alkyl;a is an average value from 15 to 8;b is an average value from 1 to 8; anda+b is from 15 to 16; and sulphonated derivatives thereof and process for their preparation.The phthalocyanines of the present invention are useful for absorbing electro-magnetic radiation from for example a laser source and may be used in a coating for optical data storage disks, or in security applications such as printing banknotes or cheques, or in the preparation of lithographic printing plates or in washing powders to assist in bleaching.

    Abstract translation: 式（1）的酞菁：式（1）其中：MkPC是式（2）的酞菁核：式（2）M是金属原子，氯 - 金属基和氧 - 金属基团或氢; k为+ E的倒数，为M的1/2 + EE化合价; R和R 1各自独立地为有机基团; R2是H或任选取代的烷基; a是从15到8的平均值; b为1〜8的平均值; a + b为15〜16; 及其磺化衍生物及其制备方法。 本发明的酞菁可用于从例如激光源吸收电磁辐射，并且可用于光学数据存储盘的涂层中，或用于诸如印刷纸币或支票的安全应用中，或用于制备光刻 印刷板或洗涤粉以帮助漂白。

    Xanthene dyes for ink jet printing
    8.
    发明授权
    Xanthene dyes for ink jet printing 失效
    用于喷墨印花的呫吨染料

    公开(公告)号：US5279656A

    公开(公告)日：1994-01-18

    申请号：US973666

    申请日：1992-11-09

    Applicant: Ronald W. Kenyon ,  Peter Gregory

    Inventor： Ronald W. Kenyon ,  Peter Gregory

    IPC: C07D311/88 ,  C07D311/82 ,  C09B11/28 ,  C09B67/22 ,  C09D11/00 ,  C09D11/02

    CPC classification number: C07D311/82 ,  C09B11/28 ,  C09B67/0041

    Abstract: A compound of Formula (1): ##STR1## wherein: X.sup.1 is a sulpho or carboxy group;each X.sup.2 independently is a substituent;m has a value of from 0 to 2;Y.sup.1 and Y.sup.2 are each independently alkyl or halo; andZ is a carboxy group.The above compounds may be used as colorants for ink jet printing inks either alone or as a mixture with a second magenta compound.

    Abstract translation: 式（1）的化合物：（*化学结构*）（1）其中：X1是磺基或羧基; 每个X2独立地是取代基; m的值为0〜2; Y1和Y2各自独立地为烷基或卤素; Z为羧基。 上述化合物可以单独使用或作为与第二品红化合物的混合物用作喷墨印刷油墨的着色剂。

    Disazo dyes suitable for use in ink jet printing
    9.
    发明授权
    Disazo dyes suitable for use in ink jet printing 失效
    适用于喷墨印刷的双偶氮染料

    公开(公告)号：US5262527A

    公开(公告)日：1993-11-16

    申请号：US723324

    申请日：1991-06-28

    Applicant: Peter Gregory ,  Ronald W. Kenyon ,  Prahalad M. Mistry

    Inventor： Peter Gregory ,  Ronald W. Kenyon ,  Prahalad M. Mistry

    IPC: C09B33/10 ,  C09B43/00 ,  C09B43/16 ,  C09B62/03 ,  C09D11/00 ,  C09D11/02

    CPC classification number: C09D11/328 ,  C09B43/00 ,  C09B43/16 ,  C09B62/03

    Abstract: Anionic azo compounds which, in the free acid form, have the Formula (1): ##STR1## Ar.sup.1 and Ar.sup.2 are each independently aryl or substituted aryl providing at least one of Ar.sup.1 and Ar.sup.2 has at least one substituent selected from COOH and COSH;each R.sup.1 and R.sup.2 is independently H, alkyl, substituted alkyl, alkenyl or substituted alkenyl;L is a divalent organic linking group;n is 0 or 1;each X independently is carbonyl or a group of the formula (2), (3) or (4): ##STR2## each Z independently is NR.sup.3 R.sup.4, SR.sup.5 or OR.sup.5 ; each Y independently is H, Cl, Z, SR.sup.6 or OR.sup.6 ;each E independently is Cl or CN;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each independently H, alkyl, substituted alkyl, alkenyl, substituted alkenyl, aryl, substituted aryl, aralkyl, substituted aralkyl or R.sup.3 and R.sup.4 together with the nitrogen atom to which they are attached form a 5 or 6 membered ring;provided the compound of Formula (1) has at least as many groups selected from --COOH and --COSH as --SO.sub.3 H groups.The compounds are useful for the preparation of inks for use in ink-jet printing.

    Substituted phthalocyanines
    10.
    发明授权
    Substituted phthalocyanines 失效
    取代的羟基苯甲酸

    公开(公告)号：US5189153A

    公开(公告)日：1993-02-23

    申请号：US540172

    申请日：1990-06-19

    Applicant: Peter Gregory ,  Prakash Patel

    Inventor： Peter Gregory ,  Prakash Patel

    IPC: C07D487/22 ,  C09B47/18 ,  C09B47/20 ,  C09B47/22 ,  C09B47/24 ,  C09B47/30 ,  C09B69/04 ,  G11B7/248

    CPC classification number: C09B47/24 ,  C09B69/04 ,  G11B7/248

    Abstract: A phthalocyanine compound of the Formula (1): ##STR1## wherein: Pc is a phthalocyanine nucleus which is metal free or contains a metal or oxymetal;X is S; NT or O;Y is S; NT or O;Z is S or Se; in which T in the above is H; alkyl or aryl;.sup.+ HA is an aliphatic polyamino ammonium ion or a substituted diguanidinium ion;each R independently is an aromatic radical linked to a peripheral carbon atom of the Pc nucleus through an atom Z;each R.sup.1 independently is optionally substituted phenylene or naphthylene in which the atoms X and Y are attached to adjacent nuclear carbon atoms in R.sup.1 and to adjacent peripheral carbon atoms of the Pc nucleus;a is 0 to 16; provided thatb is 0 to 8; a+b>0; andc+d is 1 to 16.

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